国产精品成人网站/两攻一受3p双龙h调教/玩弄人妻少妇500系列/人妻换人妻仑乱/国产成人一区二区三区别

中文

全國熱線:138-9810-2027

推薦資訊

全國服務熱線

138-9810-2027

阿拉善左電纜中的銅都是一樣的嗎?什么樣的是好銅?一篇文章解釋清楚

來源(yuan):行業(ye)動(dong)態 閱讀(du):109371 發布時(shi)間:2019-07-05

導讀:由于生產銅(tong)(tong)桿(gan)(gan)的兩者的工(gong)藝(yi)不(bu)同(tong),所(suo)生產的銅(tong)(tong)桿(gan)(gan)中的含氧量及外觀(guan)就不(bu)同(tong)。上引(yin)生產的銅(tong)(tong)桿(gan)(gan),工(gong)藝(yi)得當(dang)氧含量在(zai)10ppm以下,叫無(wu)氧銅(tong)(tong)桿(gan)(gan);連鑄連鑄生產的銅(tong)(tong)桿(gan)(gan) 是(shi)在(zai)保護(hu)條件下的熱軋,氧含量在(zai)200-500ppm范圍內,但有時也高(gao)達700ppm以上,一般(ban)情況(kuang)下,此種方法生產的銅(tong)(tong)外表(biao)光亮(liang),低氧銅(tong)(tong)桿(gan)(gan),有時也叫光桿(gan)(gan)。

銅(tong)(tong)(tong)桿(gan)是電纜行(xing)(xing)業(ye)的(de)(de)主要(yao)原(yuan)料,生(sheng)(sheng)(sheng)產(chan)的(de)(de)方式(shi)主要(yao)有兩種——連鑄(zhu)(zhu)連軋(ya)(ya)(ya)法(fa)和上引連鑄(zhu)(zhu)法(fa)。連鑄(zhu)(zhu)連軋(ya)(ya)(ya)低(di)氧(yang)(yang)(yang)銅(tong)(tong)(tong)桿(gan)的(de)(de)生(sheng)(sheng)(sheng)產(chan)方法(fa)較多,其特點(dian)是金(jin)屬在豎爐(lu)中(zhong)融化后(hou),銅(tong)(tong)(tong)液通過保溫爐(lu)、溜槽、中(zhong)間包(bao),從澆管(guan)進(jin)入封閉的(de)(de)模(mo)腔內,采用較大的(de)(de)冷卻(que)(que)強度進(jin)行(xing)(xing)冷卻(que)(que),形成鑄(zhu)(zhu)坯,然后(hou)進(jin)行(xing)(xing)多道次軋(ya)(ya)(ya)制,生(sheng)(sheng)(sheng)產(chan)的(de)(de)低(di)氧(yang)(yang)(yang)銅(tong)(tong)(tong)桿(gan)為(wei)熱(re)加(jia)(jia)工(gong)組(zu)(zu)織(zhi),原(yuan)來的(de)(de)鑄(zhu)(zhu)造組(zu)(zu)織(zhi)已經(jing)破(po)碎,含(han)(han)(han)氧(yang)(yang)(yang)量(liang)(liang)一般為(wei)200~400ppm之間。無氧(yang)(yang)(yang)銅(tong)(tong)(tong)桿(gan)國(guo)內基本(ben)全部(bu)采用上引連鑄(zhu)(zhu)法(fa)生(sheng)(sheng)(sheng)產(chan),金(jin)屬在感(gan)應電爐(lu)中(zhong)融化后(hou)通過石(shi)墨(mo)模(mo)進(jin)行(xing)(xing)上引連續鑄(zhu)(zhu)造,之后(hou)進(jin)行(xing)(xing)冷軋(ya)(ya)(ya)或冷加(jia)(jia)工(gong),生(sheng)(sheng)(sheng)產(chan)的(de)(de)無氧(yang)(yang)(yang)銅(tong)(tong)(tong)桿(gan)為(wei)鑄(zhu)(zhu)造組(zu)(zu)織(zhi),含(han)(han)(han)氧(yang)(yang)(yang)量(liang)(liang)一般在20ppm以下。由于制造工(gong)藝的(de)(de)不(bu)同(tong),所以在組(zu)(zu)織(zhi)結構、氧(yang)(yang)(yang)含(han)(han)(han)量(liang)(liang)分布(bu)、雜質的(de)(de)形式(shi)及分布(bu)等(deng)諸(zhu)多方面有較大差別。

一、拉制性能

銅桿(gan)的拉制性能跟(gen)很多因(yin)素(su)有關,如雜質的含(han)量、氧含(han)量及分(fen)布、工藝控(kong)制等。下(xia)面分(fen)別從(cong)以上幾個方面對銅桿(gan)的拉制性能進行分(fen)析。

1、熔化方式對S等雜質的影響

連(lian)鑄連(lian)軋生產銅(tong)(tong)桿(gan)主要(yao)是通過(guo)氣(qi)體的燃燒使銅(tong)(tong)桿(gan)熔化,在燃燒的過(guo)程中(zhong)(zhong),通過(guo)氧(yang)化和揮(hui)發作用,可一(yi)定程度減少部分雜質進入銅(tong)(tong)液,因此連(lian)鑄連(lian)軋法對原料要(yao)求(qiu)相(xiang)對低一(yi)些。上引(yin)連(lian)鑄生產無(wu)(wu)氧(yang)銅(tong)(tong)桿(gan),由于是用感(gan)應電(dian)爐熔化,電(dian)解銅(tong)(tong)表面的“銅(tong)(tong)綠”“銅(tong)(tong)豆”基本(ben)都熔入到銅(tong)(tong)液中(zhong)(zhong)。其中(zhong)(zhong)熔入的S對無(wu)(wu)氧(yang)銅(tong)(tong)桿(gan)塑性影響極大,會增(zeng)加拉絲(si)斷線率。

2、鑄(zhu)造過程中(zhong)雜質(zhi)的(de)進(jin)入

在生(sheng)產過程(cheng)中,連(lian)(lian)鑄連(lian)(lian)軋(ya)工藝需通(tong)過保溫爐(lu)、溜槽(cao)、中間包轉運銅液,相對(dui)容易造成(cheng)耐火(huo)材料(liao)的剝落(luo),在軋(ya)制過程(cheng)中需要通(tong)過軋(ya)輥(gun),造成(cheng)鐵質的脫落(luo),會給銅桿造成(cheng)外部夾雜(za)。而熱軋(ya)中皮上和皮下氧(yang)化物的軋(ya)入(ru)(ru),會給低氧(yang)桿的拉絲造成(cheng)不(bu)利的影響。上引(yin)連(lian)(lian)鑄法生(sheng)產工藝流(liu)程(cheng)較(jiao)(jiao)短,銅液是(shi)通(tong)過聯體(ti)爐(lu)內潛流(liu)式完成(cheng),對(dui)耐火(huo)材料(liao)的沖擊不(bu)大(da),結晶是(shi)通(tong)過石墨模內進行(xing),所以過程(cheng)中可能(neng)產生(sheng)的污染(ran)源較(jiao)(jiao)少,雜(za)質進入(ru)(ru)的機(ji)會較(jiao)(jiao)少。

O、S、P是與銅(tong)會生產化(hua)合物的(de)元(yuan)素。在(zai)(zai)熔態銅(tong)中,氧(yang)可以(yi)(yi)溶解一部分,但當銅(tong)冷凝時,氧(yang)幾(ji)乎不溶解于銅(tong)中。熔態時所溶解的(de)氧(yang),以(yi)(yi)銅(tong)=氧(yang)化(hua)亞銅(tong)共(gong)晶(jing)體(ti)(ti)析出(chu),分布在(zai)(zai)晶(jing)粒晶(jing)界處。銅(tong)-氧(yang)化(hua)亞銅(tong)共(gong)晶(jing)體(ti)(ti)的(de)出(chu)現,顯著降(jiang)低了銅(tong)的(de)塑性。

硫可以溶解在(zai)熔(rong)體的(de)銅中,但在(zai)室溫下,其溶解度幾乎降低到(dao)零(ling),它(ta)以硫化亞銅的(de)形式出現在(zai)晶粒晶界處,會顯著(zhu)降低銅的(de)塑性。

3、氧(yang)在低氧(yang)銅(tong)桿和無氧(yang)銅(tong)桿中分(fen)布形式及(ji)其(qi)影響

氧(yang)含(han)(han)量(liang)對低氧(yang)銅(tong)(tong)(tong)桿的(de)(de)(de)拉線(xian)(xian)性能有著明顯的(de)(de)(de)影響。當氧(yang)含(han)(han)量(liang)增加到(dao)最(zui)佳值(zhi)時,銅(tong)(tong)(tong)桿的(de)(de)(de)斷線(xian)(xian)率最(zui)低。這是因為氧(yang)在(zai)與大(da)部(bu)分(fen)雜質(zhi)反(fan)應的(de)(de)(de)過程中都起到(dao)了清除器的(de)(de)(de)作用。適度的(de)(de)(de)氧(yang)還有利于去除銅(tong)(tong)(tong)液中的(de)(de)(de)氫,生成水蒸氣溢出(chu),減少(shao)氣孔(kong)的(de)(de)(de)形成。最(zui)佳的(de)(de)(de)氧(yang)含(han)(han)量(liang)為拉線(xian)(xian)工藝提供了最(zui)好的(de)(de)(de)條件。

低(di)氧(yang)銅(tong)桿(gan)氧(yang)化(hua)(hua)物的(de)分(fen)布(bu):在(zai)連續澆鑄(zhu)中(zhong)凝固的(de)最初階段,散熱速率和均(jun)勻(yun)冷(leng)(leng)卻是決定(ding)銅(tong)桿(gan)氧(yang)化(hua)(hua)物分(fen)布(bu)的(de)主(zhu)要因(yin)素。不均(jun)勻(yun)冷(leng)(leng)卻會引起銅(tong)桿(gan)內部(bu)結構本(ben)質上的(de)差異,但后續的(de)熱加(jia)工,柱狀晶通常會遭到(dao)破(po)壞(huai),使(shi)氧(yang)化(hua)(hua)亞(ya)銅(tong)顆(ke)(ke)粒(li)細(xi)微化(hua)(hua)和均(jun)勻(yun)分(fen)布(bu)。氧(yang)化(hua)(hua)物顆(ke)(ke)粒(li)聚集(ji)而產生(sheng)的(de)典(dian)型(xing)情(qing)況是中(zhong)心(xin)爆裂。除氧(yang)化(hua)(hua)物顆(ke)(ke)粒(li)分(fen)布(bu)的(de)影響外,具(ju)有較小(xiao)氧(yang)化(hua)(hua)物顆(ke)(ke)粒(li)的(de)銅(tong)桿(gan)顯示(shi)出較好的(de)拉(la)線特性(xing),較大的(de)Cu2O顆(ke)(ke)粒(li)容易造成(cheng)應力集(ji)中(zhong)點而斷裂。

無氧(yang)(yang)(yang)銅(tong)(tong)含(han)氧(yang)(yang)(yang)量(liang)超標,銅(tong)(tong)桿(gan)變脆,延伸(shen)率下(xia)降,拉伸(shen)式樣端口顯暗(an)紅色(se),結晶組織(zhi)疏松。當氧(yang)(yang)(yang)含(han)量(liang)超出8ppm時,工(gong)藝性(xing)能變差(cha),表現為(wei)鑄造(zao)及(ji)(ji)拉伸(shen)過程中斷桿(gan)及(ji)(ji)斷線率極具增高。這是(shi)由于氧(yang)(yang)(yang)能與(yu)銅(tong)(tong)生成氧(yang)(yang)(yang)化亞銅(tong)(tong)脆性(xing)相,形成銅(tong)(tong)-氧(yang)(yang)(yang)化亞銅(tong)(tong)共(gong)晶體,以網狀(zhuang)組織(zhi)分布在(zai)境界上。這種脆性(xing)相硬度高,在(zai)冷(leng)變形時將(jiang)會與(yu)銅(tong)(tong)機體脫(tuo)離,導致(zhi)銅(tong)(tong)桿(gan)的機械性(xing)能下(xia)降,在(zai)后續加工(gong)中容易造(zao)成斷裂現象(xiang)。氧(yang)(yang)(yang)含(han)量(liang)高還能導致(zhi)無氧(yang)(yang)(yang)銅(tong)(tong)桿(gan)導電率下(xia)降。因(yin)此,必須嚴格控制上引連鑄工(gong)藝及(ji)(ji)產品質量(liang)。

4、氫的影響

在(zai)上引連鑄(zhu)中,氧含量控制較低(di),氧化物(wu)的(de)(de)副作用唄**降低(di),但(dan)氫的(de)(de)影(ying)響(xiang)成(cheng)為較顯著的(de)(de)問(wen)題。吸(xi)氣(qi)后熔(rong)體中存(cun)在(zai)平衡反應:H2O(g)=[O]+2[H];

氣(qi)體及疏(shu)(shu)松是在結晶的(de)(de)(de)過(guo)程中,氫(qing)從過(guo)飽(bao)和的(de)(de)(de)溶液(ye)(ye)中析(xi)出(chu)并聚集(ji)而(er)形(xing)成(cheng)(cheng)(cheng)(cheng)的(de)(de)(de)。在結晶前析(xi)出(chu)的(de)(de)(de)氫(qing)又可還原氧化(hua)亞銅而(er)生(sheng)成(cheng)(cheng)(cheng)(cheng)水(shui)氣(qi)泡。由于(yu)上(shang)引(yin)鑄造的(de)(de)(de)特點是銅液(ye)(ye)自上(shang)而(er)下的(de)(de)(de)結晶,形(xing)成(cheng)(cheng)(cheng)(cheng)的(de)(de)(de)液(ye)(ye)**形(xing)狀近似錐型。銅液(ye)(ye)結晶前析(xi)出(chu)的(de)(de)(de)氣(qi)體在上(shang)浮過(guo)程中被堵在凝(ning)固組織內(nei),結晶時在鑄桿內(nei)形(xing)成(cheng)(cheng)(cheng)(cheng)氣(qi)孔(kong)。上(shang)引(yin)的(de)(de)(de)含氣(qi)量(liang)少時,析(xi)出(chu)的(de)(de)(de)氫(qing)存在于(yu)晶界處,形(xing)成(cheng)(cheng)(cheng)(cheng)疏(shu)(shu)松;含氣(qi)量(liang)多(duo)時,則聚集(ji)成(cheng)(cheng)(cheng)(cheng)氣(qi)孔(kong),因此,氣(qi)孔(kong)和疏(shu)(shu)松是氫(qing)氣(qi)和水(shui)蒸氣(qi)兩者形(xing)成(cheng)(cheng)(cheng)(cheng)的(de)(de)(de)。

氫來源于上引生產過(guo)程中的(de)各個工藝環(huan)節,如原料電解銅(tong)的(de)“銅(tong)綠(lv)”、輔料木炭**、氣(qi)候環(huan)境**、石墨(mo)結晶器未(wei)干(gan)燥等。因此,熔化爐(lu)中的(de)銅(tong)液表面應(ying)覆蓋經烘烤的(de)木炭,電解銅(tong)應(ying)盡(jin)量去除“銅(tong)綠(lv)”、“銅(tong)豆”“耳(er)朵”,對提(ti)高無氧銅(tong)桿質(zhi)量非(fei)常重(zhong)要。

在連鑄連軋(ya)工藝中,往(wang)往(wang)采用(yong)適(shi)度(du)控(kong)制氧含量來(lai)控(kong)制氫。Cu2O+ H2= 2Cu+ H2O

由(you)于銅液(ye)在鑄造過程(cheng)中(zhong)(zhong)是自(zi)下而上結晶,銅液(ye)中(zhong)(zhong)的氧(yang)和氫(qing)所(suo)產生的水蒸氣很容(rong)易上浮跑出(chu),銅液(ye)中(zhong)(zhong)的氫(qing)大部分能被(bei)有效(xiao)去(qu)除,因(yin)而對銅桿的影響較小。

二、表面質量

在生產電磁線等產品的(de)過程中,對銅桿(gan)的(de)表面(mian)質量(liang)也需(xu)提(ti)出要(yao)求。需(xu)要(yao)拉制后的(de)銅絲表面(mian)無毛刺、銅粉(fen)少、無油污。并通過扭轉試驗測(ce)量(liang)表面(mian)銅粉(fen)的(de)質量(liang)和扭轉后觀(guan)察銅桿(gan)的(de)復原情(qing)況來判(pan)定其好壞。

在連(lian)鑄(zhu)連(lian)軋(ya)過程中(zhong),從鑄(zhu)造(zao)到軋(ya)制(zhi)前,溫(wen)度高,完全暴露于(yu)空氣中(zhong),使鑄(zhu)坯表(biao)面形成較(jiao)厚(hou)的(de)(de)氧化(hua)層(ceng),在軋(ya)制(zhi)過程中(zhong),隨著(zhu)軋(ya)輥(gun)的(de)(de)轉動,氧化(hua)物顆粒軋(ya)入銅線表(biao)面。由于(yu)氧化(hua)亞(ya)銅是(shi)高熔(rong)點脆(cui)性(xing)化(hua)合物,對于(yu)軋(ya)入較(jiao)深的(de)(de)氧化(hua)亞(ya)銅,當(dang)成條狀的(de)(de)聚集(ji)物遇模具拉伸時,就會是(shi)銅桿外表(biao)面產(chan)生毛刺,給后續的(de)(de)涂漆造(zao)成麻煩。

而上引連鑄工藝制造(zao)的無氧銅桿,由于鑄造(zao)和冷(leng)卻(que)完全與(yu)氧隔絕,后續亦無熱(re)軋過程,銅桿表面(mian)(mian)無軋入表面(mian)(mian)的氧化物(wu),質量(liang)較好,拉制后銅粉少,上述問題較少存在。

無氧銅桿(gan)也(ye)(ye)分進口(kou)設(she)(she)備(bei)做的(de)(de)(de)和國(guo)產設(she)(she)備(bei)做的(de)(de)(de),但目(mu)前進口(kou)產品(pin)已無明(ming)顯優勢,銅桿(gan)產品(pin)出(chu)來后區別不是(shi)(shi)很大,只(zhi)要銅板選的(de)(de)(de)好(hao),生產控制比(bi)較穩定,國(guo)產設(she)(she)備(bei)也(ye)(ye)能產出(chu)可(ke)拉伸0.05的(de)(de)(de)銅桿(gan).進口(kou)設(she)(she)備(bei)一般是(shi)(shi)芬蘭(lan)奧托昆普的(de)(de)(de)設(she)(she)備(bei),國(guo)產設(she)(she)備(bei)最好(hao)的(de)(de)(de)應該是(shi)(shi)上海的(de)(de)(de)海軍廠的(de)(de)(de)了,生產時間最長,軍工企業,質量可(ke)靠(kao)。

低氧銅(tong)桿進口設(she)備(bei)國際主要(yao)有兩種,一(yi)種是美國南線設(she)備(bei),英文是SOUTHWIRE,國內廠(chang)家(jia)是南京華新(xin),江西銅(tong)業,另一(yi)種是德國CONTIROD設(she)備(bei),國內廠(chang)家(jia)是常州金(jin)源,天津大(da)無縫。

無(wu)(wu)氧(yang)(yang)(yang)(yang)及低氧(yang)(yang)(yang)(yang)桿(gan)(gan)(gan)(gan)(gan)(gan)從含(han)氧(yang)(yang)(yang)(yang)量(liang)上(shang)容(rong)易區別,無(wu)(wu)氧(yang)(yang)(yang)(yang)銅(tong)是(shi)含(han)氧(yang)(yang)(yang)(yang)量(liang)在(zai)(zai)10-20個(ge)PPM以(yi)下(xia),但(dan)目(mu)前有(you)的(de)(de)(de)廠(chang)家(jia)只能(neng)(neng)做(zuo)到50個(ge)PPM以(yi)下(xia).低氧(yang)(yang)(yang)(yang)銅(tong)桿(gan)(gan)(gan)(gan)(gan)(gan)在(zai)(zai) 200-400個(ge)PPM,好的(de)(de)(de)桿(gan)(gan)(gan)(gan)(gan)(gan)子(zi)一般(ban)含(han)氧(yang)(yang)(yang)(yang)量(liang)控制在(zai)(zai)250個(ge)PPM左右,無(wu)(wu)氧(yang)(yang)(yang)(yang)桿(gan)(gan)(gan)(gan)(gan)(gan)一般(ban)采(cai)取的(de)(de)(de)是(shi)上(shang)引法,低氧(yang)(yang)(yang)(yang)桿(gan)(gan)(gan)(gan)(gan)(gan)是(shi)連鑄連軋,兩種產品(pin)相(xiang)對而(er)言(yan)低氧(yang)(yang)(yang)(yang)桿(gan)(gan)(gan)(gan)(gan)(gan)對漆包線(xian)(xian)(xian)性(xing) 能(neng)(neng)更(geng)適(shi)應(ying)些(xie),如(ru)柔(rou)軟性(xing),回彈角,繞線(xian)(xian)(xian)性(xing)能(neng)(neng).但(dan)低氧(yang)(yang)(yang)(yang)桿(gan)(gan)(gan)(gan)(gan)(gan)對拉絲(si)條(tiao)件(jian)相(xiang)對要(yao)苛刻(ke)些(xie),同(tong)樣拉伸0.2的(de)(de)(de)細(xi)(xi)絲(si),如(ru)果伸線(xian)(xian)(xian)條(tiao)件(jian)不好,普通(tong)的(de)(de)(de)無(wu)(wu)氧(yang)(yang)(yang)(yang)桿(gan)(gan)(gan)(gan)(gan)(gan)可拉而(er)好的(de)(de)(de)低氧(yang)(yang)(yang)(yang)桿(gan)(gan)(gan)(gan)(gan)(gan)就斷(duan) 線(xian)(xian)(xian),但(dan)如(ru)果放在(zai)(zai)好的(de)(de)(de)伸線(xian)(xian)(xian)條(tiao)件(jian),同(tong)樣的(de)(de)(de)桿(gan)(gan)(gan)(gan)(gan)(gan)子(zi),低氧(yang)(yang)(yang)(yang)桿(gan)(gan)(gan)(gan)(gan)(gan)說不定就能(neng)(neng)拉到雙(shuang)零五,而(er)普通(tong)無(wu)(wu)氧(yang)(yang)(yang)(yang)桿(gan)(gan)(gan)(gan)(gan)(gan)最(zui)多只能(neng)(neng)拉伸到0.1而(er)已,當然做(zuo)的(de)(de)(de)最(zui)細(xi)(xi)的(de)(de)(de)如(ru)雙(shuang)零二卻(que)非得依靠進口的(de)(de)(de) 無(wu)(wu)氧(yang)(yang)(yang)(yang)銅(tong)桿(gan)(gan)(gan)(gan)(gan)(gan)了(le).目(mu)前有(you)企業嘗試用剝皮的(de)(de)(de)方(fang)式來(lai)處理低氧(yang)(yang)(yang)(yang)桿(gan)(gan)(gan)(gan)(gan)(gan)來(lai)伸0.03線(xian)(xian)(xian).但(dan)有(you)關這方(fang)面的(de)(de)(de)內容(rong)我還不是(shi)很(hen)清楚。

音響線一般反而喜歡用無氧(yang)(yang)桿,這和(he)無氧(yang)(yang)桿是(shi)單晶(jing)銅,低(di)氧(yang)(yang)桿是(shi)多晶(jing)銅有關。

氧(yang)銅桿和無氧(yang)銅桿由于制造方法的不同,致使存在差(cha)別(bie),具有各自的特點。

一、關于氧的吸入和脫去以及它(ta)的存在(zai)狀態

生產(chan)銅(tong)(tong)(tong)(tong)(tong)(tong)桿(gan)(gan)的(de)(de)(de)陰(yin)極(ji)銅(tong)(tong)(tong)(tong)(tong)(tong)的(de)(de)(de)含(han)(han)氧(yang)(yang)(yang)量(liang)一(yi)般(ban)在(zai)(zai)10—50ppm,在(zai)(zai)常(chang)溫下氧(yang)(yang)(yang)在(zai)(zai)銅(tong)(tong)(tong)(tong)(tong)(tong)中(zhong)(zhong)(zhong)的(de)(de)(de)固(gu)溶(rong)度約2ppm。低氧(yang)(yang)(yang)銅(tong)(tong)(tong)(tong)(tong)(tong)桿(gan)(gan)的(de)(de)(de)含(han)(han)氧(yang)(yang)(yang)量(liang)一(yi)般(ban)在(zai)(zai)200(175)—400(450)ppm,因(yin)此(ci)氧(yang)(yang)(yang)的(de)(de)(de)進(jin)入是(shi)(shi)在(zai)(zai)銅(tong)(tong)(tong)(tong)(tong)(tong)的(de)(de)(de)液態(tai)下吸入的(de)(de)(de),而上引法無(wu)氧(yang)(yang)(yang)銅(tong)(tong)(tong)(tong)(tong)(tong)桿(gan)(gan)則相(xiang)反,氧(yang)(yang)(yang)在(zai)(zai)液態(tai)銅(tong)(tong)(tong)(tong)(tong)(tong)下保持相(xiang)當時間后,被還原而脫去,通常(chang)這(zhe)種桿(gan)(gan)的(de)(de)(de)含(han)(han)氧(yang)(yang)(yang)量(liang)都在(zai)(zai)10—50ppm以(yi)(yi)下,最低可達(da)1-2ppm,從(cong)組織上看,低氧(yang)(yang)(yang)銅(tong)(tong)(tong)(tong)(tong)(tong)中(zhong)(zhong)(zhong)的(de)(de)(de)氧(yang)(yang)(yang),以(yi)(yi)氧(yang)(yang)(yang)化(hua)(hua)銅(tong)(tong)(tong)(tong)(tong)(tong)狀(zhuang)態(tai),存(cun)在(zai)(zai)于晶粒邊界附近,這(zhe)對(dui)低氧(yang)(yang)(yang)銅(tong)(tong)(tong)(tong)(tong)(tong)桿(gan)(gan)而言可以(yi)(yi)說(shuo)是(shi)(shi)常(chang)見的(de)(de)(de)但對(dui)無(wu)氧(yang)(yang)(yang)銅(tong)(tong)(tong)(tong)(tong)(tong)桿(gan)(gan)則很少(shao)見。氧(yang)(yang)(yang)化(hua)(hua)銅(tong)(tong)(tong)(tong)(tong)(tong)以(yi)(yi)夾雜形(xing)式在(zai)(zai)晶界出現對(dui)材料的(de)(de)(de)韌性(xing)(xing)產(chan)生負面影響。而無(wu)氧(yang)(yang)(yang)銅(tong)(tong)(tong)(tong)(tong)(tong)中(zhong)(zhong)(zhong)的(de)(de)(de)氧(yang)(yang)(yang)很低,所以(yi)(yi)這(zhe)種銅(tong)(tong)(tong)(tong)(tong)(tong)的(de)(de)(de)組織是(shi)(shi)均勻的(de)(de)(de)單(dan)相(xiang)組織對(dui)韌性(xing)(xing)有利。在(zai)(zai)無(wu)氧(yang)(yang)(yang)銅(tong)(tong)(tong)(tong)(tong)(tong)桿(gan)(gan)中(zhong)(zhong)(zhong)的(de)(de)(de)多孔性(xing)(xing)是(shi)(shi)不常(chang)見的(de)(de)(de),而在(zai)(zai)低氧(yang)(yang)(yang)銅(tong)(tong)(tong)(tong)(tong)(tong)桿(gan)(gan)中(zhong)(zhong)(zhong)則是(shi)(shi)常(chang)見的(de)(de)(de)一(yi)種缺陷。

二、熱軋組(zu)(zu)織(zhi)和鑄造組(zu)(zu)織(zhi)的區別

低氧銅(tong)(tong)桿由于經過熱軋,所(suo)以(yi)(yi)(yi)其組(zu)織(zhi)屬熱加工組(zu)織(zhi),原(yuan)來(lai)的(de)(de)(de)鑄造組(zu)織(zhi)已(yi)經破碎,在(zai)8mm的(de)(de)(de)桿時已(yi)有(you)再結晶(jing)的(de)(de)(de)形式(shi)出現(xian),而(er)無(wu)氧銅(tong)(tong)桿屬鑄造組(zu)織(zhi),晶(jing)粒(li)(li)(li)粗大,這(zhe)是為什么(me),無(wu)氧銅(tong)(tong)的(de)(de)(de)再結晶(jing)溫(wen)(wen)度較高,需要較高退(tui)火(huo)溫(wen)(wen)度的(de)(de)(de)固有(you)原(yuan)因(yin)。這(zhe)是因(yin)為,再結晶(jing)發生在(zai)晶(jing)粒(li)(li)(li)邊界(jie)附近,無(wu)氧銅(tong)(tong)桿組(zu)織(zhi)晶(jing)粒(li)(li)(li)粗大,晶(jing)粒(li)(li)(li)尺寸甚至能達幾個(ge)毫(hao)米,因(yin)而(er)晶(jing)粒(li)(li)(li)邊界(jie)少(shao),即使通(tong)過拉制(zhi)變形,但晶(jing)粒(li)(li)(li)邊界(jie)相(xiang)對低氧銅(tong)(tong)桿還是較少(shao),所(suo)以(yi)(yi)(yi)需要較高的(de)(de)(de)退(tui)火(huo)功(gong)率(lv)。對無(wu)氧銅(tong)(tong)成功(gong)的(de)(de)(de)退(tui)火(huo)要求是:由桿經拉制(zhi),但尚未鑄造組(zu)織(zhi)的(de)(de)(de)線時的(de)(de)(de)第(di)一次退(tui)火(huo),其退(tui)火(huo)功(gong)率(lv)應比同樣情況的(de)(de)(de)低氧銅(tong)(tong)高10——15%。經繼(ji)續拉制(zhi),在(zai)以(yi)(yi)(yi)后階段的(de)(de)(de)退(tui)火(huo)功(gong)率(lv)應留有(you)足夠的(de)(de)(de)余量和(he)對低氧銅(tong)(tong)和(he)無(wu)氧銅(tong)(tong)切實區別執行不(bu)同的(de)(de)(de)退(tui)火(huo)工藝,以(yi)(yi)(yi)保證在(zai)制(zhi)品和(he)成品導線的(de)(de)(de)柔軟性。

三、夾雜,氧含量波動(dong),表面氧化物(wu)和(he)可能存在的(de)熱軋缺陷的(de)差別

無(wu)氧(yang)(yang)(yang)銅桿(gan)的(de)(de)(de)可(ke)拉(la)性(xing)在(zai)(zai)(zai)所(suo)有線(xian)(xian)徑里(li)與低氧(yang)(yang)(yang)銅桿(gan)相比都是優越的(de)(de)(de),除(chu)上(shang)述組(zu)織原(yuan)(yuan)因外(wai),無(wu)氧(yang)(yang)(yang)銅桿(gan)夾雜少,含氧(yang)(yang)(yang)量(liang)穩(wen)定(ding)(ding),無(wu)熱軋可(ke)能(neng)(neng)(neng)產生的(de)(de)(de)缺陷,桿(gan)表氧(yang)(yang)(yang)化物(wu)厚度可(ke)達≤15A。在(zai)(zai)(zai)連鑄連軋生產過(guo)程中如(ru)果工藝不(bu)穩(wen)定(ding)(ding),對(dui)(dui)氧(yang)(yang)(yang)監控(kong)不(bu)嚴,含氧(yang)(yang)(yang)量(liang)不(bu)穩(wen)定(ding)(ding)將(jiang)直(zhi)接影(ying)響桿(gan)的(de)(de)(de)性(xing)能(neng)(neng)(neng)。如(ru)果桿(gan)的(de)(de)(de)表面(mian)氧(yang)(yang)(yang)化物(wu)能(neng)(neng)(neng)在(zai)(zai)(zai)后工序的(de)(de)(de)連續(xu)清洗(xi)中得以(yi)彌(mi)補外(wai),但比較麻煩的(de)(de)(de)是有相當多的(de)(de)(de)氧(yang)(yang)(yang)化物(wu)存在(zai)(zai)(zai)于(yu)“皮(pi)下”,對(dui)(dui)拉(la)線(xian)(xian)斷(duan)線(xian)(xian)影(ying)響更直(zhi)接,故而在(zai)(zai)(zai)拉(la)制微細(xi)線(xian)(xian),超微細(xi)線(xian)(xian)時,為了(le)減少斷(duan)線(xian)(xian),有時要對(dui)(dui)銅桿(gan)采取(qu)不(bu)得已(yi)的(de)(de)(de)辦(ban)法——剝皮(pi),甚至二次剝皮(pi)的(de)(de)(de)原(yuan)(yuan)因所(suo)在(zai)(zai)(zai),目的(de)(de)(de)要除(chu)去(qu)皮(pi)下氧(yang)(yang)(yang)化物(wu)。

四(si)、低氧銅桿(gan)和(he)無氧銅桿(gan)的(de)韌(ren)性(xing)有差別

兩者都可(ke)以(yi)拉(la)到0.015mm,但在低溫(wen)超(chao)導線中的低溫(wen)級無(wu)氧銅,其細絲間的間距(ju)只有0.001mm.

五、從制桿的原材(cai)料到制線的經濟性(xing)有差(cha)別。

制(zhi)(zhi)造無氧銅桿要求質量較高(gao)的原材料。一般,拉制(zhi)(zhi)直徑>1mm的銅線(xian)時,低氧銅桿的優(you)點(dian)比(bi)較明(ming)顯,而無氧銅桿顯得更為優(you)越的是(shi)拉制(zhi)(zhi)直徑<0.5mm的銅線(xian)。

六、低氧銅桿的制線(xian)工藝與無氧銅桿的有所(suo)不同。

低(di)氧銅桿的(de)(de)制線(xian)工藝(yi)(yi)不能(neng)照搬(ban)到(dao)無氧銅桿的(de)(de)制線(xian)工藝(yi)(yi)上來(lai),至(zhi)少兩者(zhe)的(de)(de)退(tui)火工藝(yi)(yi)是不同的(de)(de)。因為線(xian)的(de)(de)柔軟(ruan)性深受材料(liao)成份和制桿,制線(xian)和退(tui)火工藝(yi)(yi)的(de)(de)影響(xiang),不能(neng)簡(jian)單地說(shuo)低(di)氧銅或(huo)無氧銅誰(shui)軟(ruan)誰(shui)硬。