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阿榮電纜中的銅都是一樣的嗎?什么樣的是好銅?一篇文章解釋清楚

來源:行業動(dong)態(tai) 閱讀:109574 發布時間:2019-07-05

導讀:由于生(sheng)產(chan)(chan)銅(tong)(tong)桿的(de)兩者(zhe)的(de)工藝不同,所生(sheng)產(chan)(chan)的(de)銅(tong)(tong)桿中的(de)含氧(yang)(yang)(yang)量(liang)(liang)及外(wai)觀就不同。上引生(sheng)產(chan)(chan)的(de)銅(tong)(tong)桿,工藝得當氧(yang)(yang)(yang)含量(liang)(liang)在10ppm以下,叫無氧(yang)(yang)(yang)銅(tong)(tong)桿;連鑄連鑄生(sheng)產(chan)(chan)的(de)銅(tong)(tong)桿 是在保護條件下的(de)熱軋(ya),氧(yang)(yang)(yang)含量(liang)(liang)在200-500ppm范(fan)圍內,但(dan)有時(shi)也(ye)(ye)高達700ppm以上,一般情況下,此種方法生(sheng)產(chan)(chan)的(de)銅(tong)(tong)外(wai)表光亮,低氧(yang)(yang)(yang)銅(tong)(tong)桿,有時(shi)也(ye)(ye)叫光桿。

銅桿(gan)(gan)是(shi)電纜行(xing)(xing)業的(de)(de)主要(yao)原料,生產(chan)的(de)(de)方(fang)式(shi)主要(yao)有兩(liang)種——連(lian)鑄(zhu)(zhu)(zhu)連(lian)軋(ya)法(fa)(fa)和上引連(lian)鑄(zhu)(zhu)(zhu)法(fa)(fa)。連(lian)鑄(zhu)(zhu)(zhu)連(lian)軋(ya)低氧(yang)(yang)銅桿(gan)(gan)的(de)(de)生產(chan)方(fang)法(fa)(fa)較(jiao)(jiao)多(duo)(duo),其(qi)特點是(shi)金屬(shu)(shu)在豎爐中融(rong)化后(hou),銅液通過保溫爐、溜槽、中間包,從澆管進入封閉的(de)(de)模腔內(nei)(nei),采(cai)用(yong)(yong)較(jiao)(jiao)大(da)的(de)(de)冷(leng)卻強度進行(xing)(xing)冷(leng)卻,形成鑄(zhu)(zhu)(zhu)坯,然后(hou)進行(xing)(xing)多(duo)(duo)道(dao)次(ci)軋(ya)制,生產(chan)的(de)(de)低氧(yang)(yang)銅桿(gan)(gan)為(wei)熱加工(gong)(gong)組織,原來的(de)(de)鑄(zhu)(zhu)(zhu)造組織已經破碎(sui),含(han)氧(yang)(yang)量一(yi)般為(wei)200~400ppm之(zhi)間。無(wu)氧(yang)(yang)銅桿(gan)(gan)國內(nei)(nei)基(ji)本全部采(cai)用(yong)(yong)上引連(lian)鑄(zhu)(zhu)(zhu)法(fa)(fa)生產(chan),金屬(shu)(shu)在感應(ying)電爐中融(rong)化后(hou)通過石墨模進行(xing)(xing)上引連(lian)續(xu)鑄(zhu)(zhu)(zhu)造,之(zhi)后(hou)進行(xing)(xing)冷(leng)軋(ya)或冷(leng)加工(gong)(gong),生產(chan)的(de)(de)無(wu)氧(yang)(yang)銅桿(gan)(gan)為(wei)鑄(zhu)(zhu)(zhu)造組織,含(han)氧(yang)(yang)量一(yi)般在20ppm以下。由于制造工(gong)(gong)藝的(de)(de)不同,所(suo)以在組織結構、氧(yang)(yang)含(han)量分(fen)布、雜質的(de)(de)形式(shi)及(ji)分(fen)布等諸多(duo)(duo)方(fang)面有較(jiao)(jiao)大(da)差別。

一、拉制性能

銅桿(gan)的拉制(zhi)(zhi)性(xing)能(neng)跟很多因素有關,如雜質(zhi)的含(han)量、氧含(han)量及分布(bu)、工(gong)藝控制(zhi)(zhi)等。下面分別從以(yi)上幾個方面對(dui)銅桿(gan)的拉制(zhi)(zhi)性(xing)能(neng)進行(xing)分析。

1、熔(rong)化(hua)方式對S等雜質的影響

連(lian)(lian)鑄連(lian)(lian)軋(ya)生產銅(tong)(tong)(tong)桿(gan)主要是通過氣體的(de)燃燒(shao)使銅(tong)(tong)(tong)桿(gan)熔化(hua),在燃燒(shao)的(de)過程中(zhong),通過氧化(hua)和揮發作(zuo)用,可一定(ding)程度減少部分雜(za)質進入銅(tong)(tong)(tong)液(ye),因此連(lian)(lian)鑄連(lian)(lian)軋(ya)法對原料要求相對低一些。上引連(lian)(lian)鑄生產無(wu)氧銅(tong)(tong)(tong)桿(gan),由于是用感應電(dian)爐熔化(hua),電(dian)解銅(tong)(tong)(tong)表面的(de)“銅(tong)(tong)(tong)綠”“銅(tong)(tong)(tong)豆”基本都熔入到(dao)銅(tong)(tong)(tong)液(ye)中(zhong)。其中(zhong)熔入的(de)S對無(wu)氧銅(tong)(tong)(tong)桿(gan)塑性影響(xiang)極大,會增加拉絲(si)斷線率。

2、鑄造過程(cheng)中(zhong)雜(za)質的進入

在(zai)生(sheng)產過程(cheng)(cheng)中(zhong),連鑄連軋工藝(yi)需通(tong)過保溫爐、溜(liu)槽、中(zhong)間(jian)包轉運(yun)銅液,相對(dui)容易(yi)造(zao)成耐火(huo)材料(liao)的(de)(de)(de)剝落,在(zai)軋制(zhi)過程(cheng)(cheng)中(zhong)需要通(tong)過軋輥,造(zao)成鐵質的(de)(de)(de)脫落,會(hui)給(gei)銅桿(gan)造(zao)成外部夾雜。而熱軋中(zhong)皮上和皮下氧化物的(de)(de)(de)軋入,會(hui)給(gei)低氧桿(gan)的(de)(de)(de)拉(la)絲造(zao)成不利的(de)(de)(de)影響。上引連鑄法生(sheng)產工藝(yi)流程(cheng)(cheng)較短,銅液是通(tong)過聯體爐內潛流式完成,對(dui)耐火(huo)材料(liao)的(de)(de)(de)沖擊不大,結(jie)晶(jing)是通(tong)過石墨模內進(jin)行,所以過程(cheng)(cheng)中(zhong)可能產生(sheng)的(de)(de)(de)污染源較少(shao)(shao),雜質進(jin)入的(de)(de)(de)機會(hui)較少(shao)(shao)。

O、S、P是(shi)與銅會(hui)生(sheng)產化合物的(de)元素。在熔(rong)態(tai)銅中(zhong),氧(yang)可以溶(rong)解一部分,但當銅冷(leng)凝時(shi),氧(yang)幾(ji)乎不溶(rong)解于銅中(zhong)。熔(rong)態(tai)時(shi)所溶(rong)解的(de)氧(yang),以銅=氧(yang)化亞銅共(gong)晶(jing)體析出,分布在晶(jing)粒晶(jing)界處。銅-氧(yang)化亞銅共(gong)晶(jing)體的(de)出現,顯著降低了銅的(de)塑性(xing)。

硫(liu)可以溶解在(zai)熔體的(de)銅(tong)(tong)中,但在(zai)室溫下,其(qi)溶解度幾(ji)乎降(jiang)低到(dao)零,它(ta)以硫(liu)化亞銅(tong)(tong)的(de)形式(shi)出現在(zai)晶粒晶界處,會顯著降(jiang)低銅(tong)(tong)的(de)塑性。

3、氧在低氧銅桿(gan)和無氧銅桿(gan)中分布(bu)形式及其影響

氧(yang)(yang)含量(liang)(liang)對低(di)氧(yang)(yang)銅(tong)桿的拉(la)線(xian)(xian)性能有(you)著明(ming)顯的影響。當氧(yang)(yang)含量(liang)(liang)增加到(dao)最(zui)佳(jia)(jia)值時,銅(tong)桿的斷線(xian)(xian)率(lv)最(zui)低(di)。這是因為氧(yang)(yang)在與(yu)大部分雜質反應的過程中(zhong)都起到(dao)了清除器的作用。適度的氧(yang)(yang)還有(you)利于去除銅(tong)液中(zhong)的氫,生成水蒸氣(qi)溢出,減少氣(qi)孔的形成。最(zui)佳(jia)(jia)的氧(yang)(yang)含量(liang)(liang)為拉(la)線(xian)(xian)工藝提供(gong)了最(zui)好的條件。

低氧銅(tong)(tong)桿(gan)氧化物(wu)(wu)(wu)的(de)(de)(de)分(fen)布:在連(lian)續(xu)澆(jiao)鑄中凝固(gu)的(de)(de)(de)最初階段,散熱速率和均(jun)(jun)勻冷卻(que)是決(jue)定銅(tong)(tong)桿(gan)氧化物(wu)(wu)(wu)分(fen)布的(de)(de)(de)主要因素。不(bu)均(jun)(jun)勻冷卻(que)會(hui)引起(qi)銅(tong)(tong)桿(gan)內部結構本質(zhi)上(shang)的(de)(de)(de)差異,但后續(xu)的(de)(de)(de)熱加工,柱狀(zhuang)晶通(tong)常會(hui)遭到破壞,使氧化亞銅(tong)(tong)顆粒細微化和均(jun)(jun)勻分(fen)布。氧化物(wu)(wu)(wu)顆粒聚集而產生的(de)(de)(de)典型情況是中心爆裂。除氧化物(wu)(wu)(wu)顆粒分(fen)布的(de)(de)(de)影響外,具有較小氧化物(wu)(wu)(wu)顆粒的(de)(de)(de)銅(tong)(tong)桿(gan)顯示出(chu)較好的(de)(de)(de)拉線特(te)性,較大的(de)(de)(de)Cu2O顆粒容易造成應力集中點(dian)而斷裂。

無氧(yang)銅(tong)(tong)含(han)氧(yang)量(liang)超標,銅(tong)(tong)桿變脆,延伸(shen)率下降,拉伸(shen)式(shi)樣端口顯暗紅色,結晶組(zu)織(zhi)疏松。當氧(yang)含(han)量(liang)超出8ppm時(shi),工藝(yi)性能(neng)變差,表現為鑄(zhu)造及(ji)拉伸(shen)過程中斷桿及(ji)斷線率極具(ju)增高。這(zhe)是由于氧(yang)能(neng)與(yu)銅(tong)(tong)生(sheng)成氧(yang)化亞銅(tong)(tong)脆性相(xiang),形成銅(tong)(tong)-氧(yang)化亞銅(tong)(tong)共晶體(ti),以網狀組(zu)織(zhi)分布在境界上。這(zhe)種脆性相(xiang)硬度高,在冷變形時(shi)將會與(yu)銅(tong)(tong)機體(ti)脫離,導致(zhi)銅(tong)(tong)桿的機械性能(neng)下降,在后續加工中容易造成斷裂(lie)現象(xiang)。氧(yang)含(han)量(liang)高還能(neng)導致(zhi)無氧(yang)銅(tong)(tong)桿導電率下降。因此,必須嚴格控制上引(yin)連鑄(zhu)工藝(yi)及(ji)產品質(zhi)量(liang)。

4、氫的影響

在上引連鑄中,氧(yang)含量(liang)控(kong)制較(jiao)低,氧(yang)化物的副作(zuo)用(yong)唄**降低,但氫的影響成為較(jiao)顯著(zhu)的問(wen)題。吸氣后(hou)熔體中存在平衡反應:H2O(g)=[O]+2[H];

氣(qi)體(ti)及疏松(song)是在結(jie)(jie)(jie)晶(jing)(jing)(jing)(jing)的(de)(de)(de)過(guo)程(cheng)中(zhong),氫從(cong)過(guo)飽和的(de)(de)(de)溶液(ye)中(zhong)析(xi)出(chu)(chu)并聚集而形(xing)(xing)(xing)(xing)(xing)成的(de)(de)(de)。在結(jie)(jie)(jie)晶(jing)(jing)(jing)(jing)前(qian)析(xi)出(chu)(chu)的(de)(de)(de)氫又可還原(yuan)氧化亞銅(tong)而生成水氣(qi)泡。由(you)于上(shang)引鑄(zhu)造的(de)(de)(de)特點(dian)是銅(tong)液(ye)自上(shang)而下的(de)(de)(de)結(jie)(jie)(jie)晶(jing)(jing)(jing)(jing),形(xing)(xing)(xing)(xing)(xing)成的(de)(de)(de)液(ye)**形(xing)(xing)(xing)(xing)(xing)狀近似錐型。銅(tong)液(ye)結(jie)(jie)(jie)晶(jing)(jing)(jing)(jing)前(qian)析(xi)出(chu)(chu)的(de)(de)(de)氣(qi)體(ti)在上(shang)浮(fu)過(guo)程(cheng)中(zhong)被堵在凝固(gu)組(zu)織內(nei),結(jie)(jie)(jie)晶(jing)(jing)(jing)(jing)時在鑄(zhu)桿內(nei)形(xing)(xing)(xing)(xing)(xing)成氣(qi)孔(kong)。上(shang)引的(de)(de)(de)含氣(qi)量(liang)少時,析(xi)出(chu)(chu)的(de)(de)(de)氫存在于晶(jing)(jing)(jing)(jing)界處(chu),形(xing)(xing)(xing)(xing)(xing)成疏松(song);含氣(qi)量(liang)多時,則聚集成氣(qi)孔(kong),因(yin)此,氣(qi)孔(kong)和疏松(song)是氫氣(qi)和水蒸(zheng)氣(qi)兩者(zhe)形(xing)(xing)(xing)(xing)(xing)成的(de)(de)(de)。

氫(qing)來(lai)源于(yu)上引(yin)生產過程中(zhong)的各(ge)個工藝(yi)環(huan)節(jie),如(ru)原(yuan)料電(dian)解(jie)(jie)銅(tong)(tong)的“銅(tong)(tong)綠”、輔料木炭**、氣候環(huan)境**、石(shi)墨(mo)結晶器未干燥等。因此,熔化爐中(zhong)的銅(tong)(tong)液表面(mian)應(ying)覆蓋經(jing)烘烤的木炭,電(dian)解(jie)(jie)銅(tong)(tong)應(ying)盡量去除“銅(tong)(tong)綠”、“銅(tong)(tong)豆(dou)”“耳朵”,對提(ti)高無氧(yang)銅(tong)(tong)桿(gan)質量非常重要(yao)。

在連鑄連軋工藝中,往往采用(yong)適度控制氧(yang)含量來控制氫。Cu2O+ H2= 2Cu+ H2O

由于銅液(ye)在(zai)鑄造過程中(zhong)是自下而(er)上結晶,銅液(ye)中(zhong)的氧和氫所產生的水蒸氣很容(rong)易上浮跑出,銅液(ye)中(zhong)的氫大(da)部分能被有效去除,因而(er)對銅桿(gan)的影響(xiang)較小。

二、表面質量

在生產電磁線(xian)等產品的(de)過程中,對銅桿(gan)(gan)的(de)表面(mian)質量(liang)也需(xu)提(ti)出要求(qiu)。需(xu)要拉制后的(de)銅絲表面(mian)無毛刺(ci)、銅粉(fen)少、無油污(wu)。并通過扭轉(zhuan)試驗測量(liang)表面(mian)銅粉(fen)的(de)質量(liang)和扭轉(zhuan)后觀察銅桿(gan)(gan)的(de)復原(yuan)情(qing)況(kuang)來(lai)判(pan)定其(qi)好壞。

在(zai)連(lian)鑄連(lian)軋過程(cheng)中(zhong),從鑄造到軋制(zhi)前(qian),溫度(du)高(gao),完(wan)全(quan)暴(bao)露于空氣(qi)中(zhong),使鑄坯表面(mian)形成較厚的(de)氧化(hua)層,在(zai)軋制(zhi)過程(cheng)中(zhong),隨(sui)著軋輥(gun)的(de)轉(zhuan)動,氧化(hua)物(wu)顆粒軋入銅線表面(mian)。由(you)于氧化(hua)亞(ya)銅是高(gao)熔點脆性化(hua)合(he)物(wu),對于軋入較深的(de)氧化(hua)亞(ya)銅,當成條狀的(de)聚(ju)集物(wu)遇(yu)模具拉伸(shen)時,就會(hui)是銅桿外表面(mian)產(chan)生毛刺,給后(hou)續的(de)涂漆造成麻煩。

而(er)上引連鑄(zhu)工藝制造(zao)(zao)的無(wu)氧銅(tong)桿(gan),由(you)于鑄(zhu)造(zao)(zao)和冷卻完全與氧隔絕,后(hou)續亦無(wu)熱軋過程,銅(tong)桿(gan)表(biao)面無(wu)軋入表(biao)面的氧化(hua)物,質(zhi)量較好,拉制后(hou)銅(tong)粉(fen)少(shao),上述問題較少(shao)存在。

無(wu)氧銅(tong)桿也分進(jin)口(kou)設(she)(she)備(bei)做的(de)(de)(de)和國(guo)產(chan)設(she)(she)備(bei)做的(de)(de)(de),但目前(qian)進(jin)口(kou)產(chan)品(pin)已無(wu)明顯(xian)優勢,銅(tong)桿產(chan)品(pin)出(chu)來后區別不是(shi)(shi)很大,只要銅(tong)板選(xuan)的(de)(de)(de)好(hao),生(sheng)產(chan)控(kong)制比較穩定,國(guo)產(chan)設(she)(she)備(bei)也能產(chan)出(chu)可拉伸(shen)0.05的(de)(de)(de)銅(tong)桿.進(jin)口(kou)設(she)(she)備(bei)一般是(shi)(shi)芬蘭奧托昆普(pu)的(de)(de)(de)設(she)(she)備(bei),國(guo)產(chan)設(she)(she)備(bei)最好(hao)的(de)(de)(de)應該是(shi)(shi)上海的(de)(de)(de)海軍(jun)廠的(de)(de)(de)了,生(sheng)產(chan)時間最長,軍(jun)工企業,質量可靠。

低(di)氧銅桿進口設(she)備國(guo)際主要有(you)兩種(zhong)(zhong),一種(zhong)(zhong)是(shi)(shi)美國(guo)南線(xian)設(she)備,英(ying)文是(shi)(shi)SOUTHWIRE,國(guo)內(nei)廠家(jia)是(shi)(shi)南京華新(xin),江西銅業(ye),另(ling)一種(zhong)(zhong)是(shi)(shi)德國(guo)CONTIROD設(she)備,國(guo)內(nei)廠家(jia)是(shi)(shi)常州金源,天津大無(wu)縫(feng)。

無(wu)氧(yang)(yang)及低(di)氧(yang)(yang)桿(gan)(gan)從含氧(yang)(yang)量上容(rong)易區別,無(wu)氧(yang)(yang)銅是含氧(yang)(yang)量在(zai)(zai)(zai)10-20個PPM以(yi)下(xia),但目前有(you)的(de)(de)(de)(de)(de)(de)廠家只(zhi)能(neng)做到(dao)(dao)50個PPM以(yi)下(xia).低(di)氧(yang)(yang)銅桿(gan)(gan)在(zai)(zai)(zai) 200-400個PPM,好的(de)(de)(de)(de)(de)(de)桿(gan)(gan)子(zi)(zi)一般(ban)含氧(yang)(yang)量控制在(zai)(zai)(zai)250個PPM左右,無(wu)氧(yang)(yang)桿(gan)(gan)一般(ban)采(cai)取的(de)(de)(de)(de)(de)(de)是上引法,低(di)氧(yang)(yang)桿(gan)(gan)是連(lian)鑄連(lian)軋,兩種產品相(xiang)對(dui)而(er)(er)言低(di)氧(yang)(yang)桿(gan)(gan)對(dui)漆(qi)包線(xian)性 能(neng)更適應些(xie),如(ru)柔軟性,回彈角,繞線(xian)性能(neng).但低(di)氧(yang)(yang)桿(gan)(gan)對(dui)拉絲條件相(xiang)對(dui)要苛刻些(xie),同樣拉伸(shen)(shen)(shen)0.2的(de)(de)(de)(de)(de)(de)細絲,如(ru)果伸(shen)(shen)(shen)線(xian)條件不好,普通的(de)(de)(de)(de)(de)(de)無(wu)氧(yang)(yang)桿(gan)(gan)可拉而(er)(er)好的(de)(de)(de)(de)(de)(de)低(di)氧(yang)(yang)桿(gan)(gan)就斷(duan) 線(xian),但如(ru)果放(fang)在(zai)(zai)(zai)好的(de)(de)(de)(de)(de)(de)伸(shen)(shen)(shen)線(xian)條件,同樣的(de)(de)(de)(de)(de)(de)桿(gan)(gan)子(zi)(zi),低(di)氧(yang)(yang)桿(gan)(gan)說不定就能(neng)拉到(dao)(dao)雙零(ling)五,而(er)(er)普通無(wu)氧(yang)(yang)桿(gan)(gan)最多只(zhi)能(neng)拉伸(shen)(shen)(shen)到(dao)(dao)0.1而(er)(er)已,當然做的(de)(de)(de)(de)(de)(de)最細的(de)(de)(de)(de)(de)(de)如(ru)雙零(ling)二卻非得依靠(kao)進(jin)口的(de)(de)(de)(de)(de)(de) 無(wu)氧(yang)(yang)銅桿(gan)(gan)了.目前有(you)企業嘗試用(yong)剝(bo)皮的(de)(de)(de)(de)(de)(de)方(fang)式來(lai)處(chu)理(li)低(di)氧(yang)(yang)桿(gan)(gan)來(lai)伸(shen)(shen)(shen)0.03線(xian).但有(you)關這方(fang)面的(de)(de)(de)(de)(de)(de)內容(rong)我(wo)還不是很清楚。

音響(xiang)線(xian)一般反而(er)喜歡用無(wu)氧(yang)桿,這(zhe)和無(wu)氧(yang)桿是(shi)單晶(jing)銅(tong),低氧(yang)桿是(shi)多晶(jing)銅(tong)有關。

氧銅(tong)桿和無(wu)氧銅(tong)桿由于制造方法的不同,致使存(cun)在差別(bie),具有各自的特點。

一、關于氧(yang)的吸入和脫去以及它的存在狀態

生(sheng)產銅(tong)(tong)(tong)(tong)桿的(de)(de)(de)(de)陰(yin)極銅(tong)(tong)(tong)(tong)的(de)(de)(de)(de)含(han)氧(yang)(yang)(yang)量一(yi)般在10—50ppm,在常(chang)溫下(xia)氧(yang)(yang)(yang)在銅(tong)(tong)(tong)(tong)中(zhong)(zhong)(zhong)的(de)(de)(de)(de)固(gu)溶度約2ppm。低氧(yang)(yang)(yang)銅(tong)(tong)(tong)(tong)桿的(de)(de)(de)(de)含(han)氧(yang)(yang)(yang)量一(yi)般在200(175)—400(450)ppm,因此氧(yang)(yang)(yang)的(de)(de)(de)(de)進入(ru)是(shi)在銅(tong)(tong)(tong)(tong)的(de)(de)(de)(de)液態(tai)(tai)下(xia)吸入(ru)的(de)(de)(de)(de),而(er)(er)上(shang)引法(fa)無(wu)氧(yang)(yang)(yang)銅(tong)(tong)(tong)(tong)桿則(ze)相(xiang)(xiang)反(fan),氧(yang)(yang)(yang)在液態(tai)(tai)銅(tong)(tong)(tong)(tong)下(xia)保持相(xiang)(xiang)當時間后,被(bei)還原(yuan)而(er)(er)脫去,通常(chang)這(zhe)種(zhong)桿的(de)(de)(de)(de)含(han)氧(yang)(yang)(yang)量都(dou)在10—50ppm以(yi)下(xia),最低可達(da)1-2ppm,從組(zu)織(zhi)上(shang)看,低氧(yang)(yang)(yang)銅(tong)(tong)(tong)(tong)中(zhong)(zhong)(zhong)的(de)(de)(de)(de)氧(yang)(yang)(yang),以(yi)氧(yang)(yang)(yang)化(hua)銅(tong)(tong)(tong)(tong)狀態(tai)(tai),存在于(yu)晶粒(li)邊界附近,這(zhe)對低氧(yang)(yang)(yang)銅(tong)(tong)(tong)(tong)桿而(er)(er)言可以(yi)說是(shi)常(chang)見的(de)(de)(de)(de)但對無(wu)氧(yang)(yang)(yang)銅(tong)(tong)(tong)(tong)桿則(ze)很少見。氧(yang)(yang)(yang)化(hua)銅(tong)(tong)(tong)(tong)以(yi)夾雜形式在晶界出現(xian)對材(cai)料(liao)的(de)(de)(de)(de)韌性(xing)產生(sheng)負(fu)面影響。而(er)(er)無(wu)氧(yang)(yang)(yang)銅(tong)(tong)(tong)(tong)中(zhong)(zhong)(zhong)的(de)(de)(de)(de)氧(yang)(yang)(yang)很低,所以(yi)這(zhe)種(zhong)銅(tong)(tong)(tong)(tong)的(de)(de)(de)(de)組(zu)織(zhi)是(shi)均(jun)勻的(de)(de)(de)(de)單相(xiang)(xiang)組(zu)織(zhi)對韌性(xing)有利。在無(wu)氧(yang)(yang)(yang)銅(tong)(tong)(tong)(tong)桿中(zhong)(zhong)(zhong)的(de)(de)(de)(de)多孔性(xing)是(shi)不常(chang)見的(de)(de)(de)(de),而(er)(er)在低氧(yang)(yang)(yang)銅(tong)(tong)(tong)(tong)桿中(zhong)(zhong)(zhong)則(ze)是(shi)常(chang)見的(de)(de)(de)(de)一(yi)種(zhong)缺陷。

二、熱軋組織和鑄(zhu)造組織的區別

低(di)氧(yang)(yang)銅(tong)桿由于經(jing)(jing)過(guo)熱(re)軋(ya),所(suo)以(yi)(yi)其組(zu)(zu)織(zhi)屬熱(re)加(jia)工(gong)組(zu)(zu)織(zhi),原(yuan)來的(de)鑄(zhu)造(zao)組(zu)(zu)織(zhi)已經(jing)(jing)破(po)碎,在8mm的(de)桿時已有(you)再結晶(jing)(jing)的(de)形式出現,而(er)無(wu)(wu)氧(yang)(yang)銅(tong)桿屬鑄(zhu)造(zao)組(zu)(zu)織(zhi),晶(jing)(jing)粒(li)粗(cu)大,這是(shi)為(wei)(wei)什么,無(wu)(wu)氧(yang)(yang)銅(tong)的(de)再結晶(jing)(jing)溫度(du)較高(gao),需(xu)要較高(gao)退(tui)火(huo)(huo)溫度(du)的(de)固有(you)原(yuan)因(yin)。這是(shi)因(yin)為(wei)(wei),再結晶(jing)(jing)發生在晶(jing)(jing)粒(li)邊界附(fu)近,無(wu)(wu)氧(yang)(yang)銅(tong)桿組(zu)(zu)織(zhi)晶(jing)(jing)粒(li)粗(cu)大,晶(jing)(jing)粒(li)尺寸甚(shen)至(zhi)能達(da)幾(ji)個毫米,因(yin)而(er)晶(jing)(jing)粒(li)邊界少,即(ji)使通(tong)過(guo)拉制變形,但晶(jing)(jing)粒(li)邊界相(xiang)對(dui)低(di)氧(yang)(yang)銅(tong)桿還是(shi)較少,所(suo)以(yi)(yi)需(xu)要較高(gao)的(de)退(tui)火(huo)(huo)功率。對(dui)無(wu)(wu)氧(yang)(yang)銅(tong)成(cheng)功的(de)退(tui)火(huo)(huo)要求(qiu)是(shi):由桿經(jing)(jing)拉制,但尚未鑄(zhu)造(zao)組(zu)(zu)織(zhi)的(de)線時的(de)第一次退(tui)火(huo)(huo),其退(tui)火(huo)(huo)功率應比(bi)同樣情況的(de)低(di)氧(yang)(yang)銅(tong)高(gao)10——15%。經(jing)(jing)繼續拉制,在以(yi)(yi)后階段(duan)的(de)退(tui)火(huo)(huo)功率應留有(you)足夠的(de)余量和(he)對(dui)低(di)氧(yang)(yang)銅(tong)和(he)無(wu)(wu)氧(yang)(yang)銅(tong)切(qie)實區別執行不同的(de)退(tui)火(huo)(huo)工(gong)藝,以(yi)(yi)保證在制品和(he)成(cheng)品導線的(de)柔(rou)軟性(xing)。

三(san)、夾雜,氧(yang)含量波(bo)動,表面(mian)氧(yang)化物和可能存(cun)在的熱軋缺(que)陷的差別

無(wu)(wu)氧(yang)(yang)(yang)銅桿(gan)的(de)(de)(de)可拉(la)性在(zai)(zai)所(suo)有線徑(jing)里(li)與低氧(yang)(yang)(yang)銅桿(gan)相(xiang)比(bi)都是(shi)優越的(de)(de)(de),除(chu)上述組(zu)織原因(yin)外,無(wu)(wu)氧(yang)(yang)(yang)銅桿(gan)夾(jia)雜(za)少,含氧(yang)(yang)(yang)量穩定(ding),無(wu)(wu)熱軋(ya)可能產生(sheng)的(de)(de)(de)缺陷,桿(gan)表(biao)氧(yang)(yang)(yang)化(hua)物厚度可達(da)≤15A。在(zai)(zai)連鑄(zhu)連軋(ya)生(sheng)產過(guo)程中(zhong)如果(guo)工(gong)藝不(bu)穩定(ding),對(dui)氧(yang)(yang)(yang)監控不(bu)嚴,含氧(yang)(yang)(yang)量不(bu)穩定(ding)將直(zhi)接(jie)影(ying)響桿(gan)的(de)(de)(de)性能。如果(guo)桿(gan)的(de)(de)(de)表(biao)面氧(yang)(yang)(yang)化(hua)物能在(zai)(zai)后工(gong)序的(de)(de)(de)連續清洗中(zhong)得(de)以(yi)彌補外,但比(bi)較麻煩的(de)(de)(de)是(shi)有相(xiang)當多(duo)的(de)(de)(de)氧(yang)(yang)(yang)化(hua)物存在(zai)(zai)于“皮(pi)下”,對(dui)拉(la)線斷線影(ying)響更直(zhi)接(jie),故而在(zai)(zai)拉(la)制微細(xi)線,超(chao)微細(xi)線時,為了減少斷線,有時要對(dui)銅桿(gan)采取不(bu)得(de)已(yi)的(de)(de)(de)辦法——剝(bo)皮(pi),甚至二次剝(bo)皮(pi)的(de)(de)(de)原因(yin)所(suo)在(zai)(zai),目的(de)(de)(de)要除(chu)去(qu)皮(pi)下氧(yang)(yang)(yang)化(hua)物。

四、低氧銅桿和無氧銅桿的韌性有差別

兩者都可(ke)以拉到0.015mm,但在低溫超導(dao)線(xian)中的低溫級(ji)無(wu)氧(yang)銅,其細(xi)絲(si)間的間距(ju)只有0.001mm.

五(wu)、從制(zhi)桿的原材(cai)料到制(zhi)線的經(jing)濟性有差(cha)別(bie)。

制(zhi)造無(wu)氧(yang)銅(tong)桿要(yao)求質量(liang)較(jiao)高(gao)的(de)原材(cai)料。一般,拉制(zhi)直徑(jing)(jing)>1mm的(de)銅(tong)線(xian)時,低氧(yang)銅(tong)桿的(de)優(you)點比較(jiao)明顯,而無(wu)氧(yang)銅(tong)桿顯得更為優(you)越的(de)是拉制(zhi)直徑(jing)(jing)<0.5mm的(de)銅(tong)線(xian)。

六、低(di)氧(yang)銅桿(gan)(gan)的(de)制(zhi)線(xian)工(gong)藝與無氧(yang)銅桿(gan)(gan)的(de)有所(suo)不(bu)同。

低(di)氧(yang)銅(tong)(tong)桿的制(zhi)線(xian)(xian)工藝不(bu)能照搬到(dao)無氧(yang)銅(tong)(tong)桿的制(zhi)線(xian)(xian)工藝上(shang)來,至少(shao)兩者(zhe)的退(tui)火(huo)工藝是(shi)不(bu)同的。因為線(xian)(xian)的柔軟性深(shen)受材料成份和(he)制(zhi)桿,制(zhi)線(xian)(xian)和(he)退(tui)火(huo)工藝的影(ying)響,不(bu)能簡單地說低(di)氧(yang)銅(tong)(tong)或無氧(yang)銅(tong)(tong)誰軟誰硬。