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弓長嶺電纜中的銅都是一樣的嗎?什么樣的是好銅?一篇文章解釋清楚

來源:行(xing)業(ye)動(dong)態 閱讀(du):109528 發布時間(jian):2019-07-05

導讀:由于生產(chan)(chan)銅(tong)桿(gan)(gan)(gan)的(de)(de)兩者的(de)(de)工藝不(bu)同(tong),所生產(chan)(chan)的(de)(de)銅(tong)桿(gan)(gan)(gan)中的(de)(de)含氧(yang)量(liang)(liang)及外觀(guan)就不(bu)同(tong)。上(shang)引生產(chan)(chan)的(de)(de)銅(tong)桿(gan)(gan)(gan),工藝得當氧(yang)含量(liang)(liang)在(zai)(zai)10ppm以下(xia),叫無氧(yang)銅(tong)桿(gan)(gan)(gan);連鑄連鑄生產(chan)(chan)的(de)(de)銅(tong)桿(gan)(gan)(gan) 是在(zai)(zai)保護條(tiao)件下(xia)的(de)(de)熱軋(ya),氧(yang)含量(liang)(liang)在(zai)(zai)200-500ppm范(fan)圍內,但有時(shi)也高(gao)達700ppm以上(shang),一般情況下(xia),此種方法(fa)生產(chan)(chan)的(de)(de)銅(tong)外表光(guang)亮,低氧(yang)銅(tong)桿(gan)(gan)(gan),有時(shi)也叫光(guang)桿(gan)(gan)(gan)。

銅(tong)(tong)桿(gan)(gan)是電纜行(xing)業的(de)主(zhu)要(yao)原(yuan)料,生(sheng)產(chan)的(de)方式(shi)主(zhu)要(yao)有兩種——連(lian)鑄(zhu)連(lian)軋(ya)(ya)法(fa)和上引連(lian)鑄(zhu)法(fa)。連(lian)鑄(zhu)連(lian)軋(ya)(ya)低氧(yang)銅(tong)(tong)桿(gan)(gan)的(de)生(sheng)產(chan)方法(fa)較(jiao)多,其特點(dian)是金(jin)屬在(zai)豎爐(lu)中融化后,銅(tong)(tong)液通過保溫爐(lu)、溜槽、中間包,從澆管進(jin)入封(feng)閉的(de)模腔(qiang)內,采(cai)用(yong)(yong)較(jiao)大(da)的(de)冷卻強度(du)進(jin)行(xing)冷卻,形(xing)成鑄(zhu)坯,然后進(jin)行(xing)多道次(ci)軋(ya)(ya)制,生(sheng)產(chan)的(de)低氧(yang)銅(tong)(tong)桿(gan)(gan)為(wei)熱(re)加工(gong)組(zu)織(zhi)(zhi),原(yuan)來的(de)鑄(zhu)造(zao)(zao)(zao)組(zu)織(zhi)(zhi)已經破碎(sui),含氧(yang)量一(yi)般為(wei)200~400ppm之間。無氧(yang)銅(tong)(tong)桿(gan)(gan)國內基(ji)本全(quan)部采(cai)用(yong)(yong)上引連(lian)鑄(zhu)法(fa)生(sheng)產(chan),金(jin)屬在(zai)感應電爐(lu)中融化后通過石墨模進(jin)行(xing)上引連(lian)續鑄(zhu)造(zao)(zao)(zao),之后進(jin)行(xing)冷軋(ya)(ya)或冷加工(gong),生(sheng)產(chan)的(de)無氧(yang)銅(tong)(tong)桿(gan)(gan)為(wei)鑄(zhu)造(zao)(zao)(zao)組(zu)織(zhi)(zhi),含氧(yang)量一(yi)般在(zai)20ppm以下(xia)。由于制造(zao)(zao)(zao)工(gong)藝的(de)不同,所以在(zai)組(zu)織(zhi)(zhi)結構、氧(yang)含量分(fen)布、雜質(zhi)的(de)形(xing)式(shi)及分(fen)布等諸多方面(mian)有較(jiao)大(da)差別。

一、拉制性能

銅桿的拉制性能跟(gen)很多因素有關,如雜質的含(han)量(liang)、氧含(han)量(liang)及分布、工藝控制等(deng)。下面分別從以上幾個方面對銅桿的拉制性能進行分析。

1、熔化方式對S等雜(za)質的影響

連(lian)(lian)鑄連(lian)(lian)軋(ya)生(sheng)產銅(tong)(tong)(tong)(tong)桿主要(yao)是通過(guo)(guo)氣體(ti)的(de)燃燒(shao)使銅(tong)(tong)(tong)(tong)桿熔化,在燃燒(shao)的(de)過(guo)(guo)程中(zhong),通過(guo)(guo)氧(yang)(yang)化和揮發作用,可一(yi)定(ding)程度減少部(bu)分雜質進(jin)入銅(tong)(tong)(tong)(tong)液,因此連(lian)(lian)鑄連(lian)(lian)軋(ya)法對(dui)(dui)原料(liao)要(yao)求(qiu)相對(dui)(dui)低一(yi)些。上引連(lian)(lian)鑄生(sheng)產無氧(yang)(yang)銅(tong)(tong)(tong)(tong)桿,由(you)于是用感應電爐(lu)熔化,電解銅(tong)(tong)(tong)(tong)表面的(de)“銅(tong)(tong)(tong)(tong)綠”“銅(tong)(tong)(tong)(tong)豆(dou)”基(ji)本都熔入到銅(tong)(tong)(tong)(tong)液中(zhong)。其中(zhong)熔入的(de)S對(dui)(dui)無氧(yang)(yang)銅(tong)(tong)(tong)(tong)桿塑性影響極大,會增加(jia)拉絲斷線率(lv)。

2、鑄(zhu)造過程中雜質的(de)進(jin)入(ru)

在生產(chan)過(guo)(guo)程中(zhong),連鑄(zhu)(zhu)連軋工藝需(xu)(xu)通(tong)(tong)過(guo)(guo)保溫爐、溜槽(cao)、中(zhong)間(jian)包轉運(yun)銅(tong)液,相對(dui)容(rong)易(yi)造(zao)(zao)成(cheng)耐火材(cai)料的剝落,在軋制過(guo)(guo)程中(zhong)需(xu)(xu)要通(tong)(tong)過(guo)(guo)軋輥,造(zao)(zao)成(cheng)鐵質的脫落,會給銅(tong)桿(gan)造(zao)(zao)成(cheng)外部夾(jia)雜(za)。而熱軋中(zhong)皮上和皮下氧化物的軋入,會給低氧桿(gan)的拉絲造(zao)(zao)成(cheng)不(bu)利(li)的影響。上引(yin)連鑄(zhu)(zhu)法生產(chan)工藝流(liu)程較(jiao)短,銅(tong)液是通(tong)(tong)過(guo)(guo)聯體爐內(nei)潛(qian)流(liu)式完成(cheng),對(dui)耐火材(cai)料的沖擊(ji)不(bu)大(da),結晶是通(tong)(tong)過(guo)(guo)石(shi)墨模內(nei)進(jin)行,所以過(guo)(guo)程中(zhong)可能產(chan)生的污染源較(jiao)少(shao),雜(za)質進(jin)入的機會較(jiao)少(shao)。

O、S、P是與銅會生產化(hua)合物的(de)(de)元素。在熔態銅中(zhong),氧可以溶解(jie)一(yi)部分(fen),但當銅冷凝時(shi),氧幾乎不溶解(jie)于銅中(zhong)。熔態時(shi)所溶解(jie)的(de)(de)氧,以銅=氧化(hua)亞銅共晶體析(xi)出,分(fen)布在晶粒(li)晶界(jie)處(chu)。銅-氧化(hua)亞銅共晶體的(de)(de)出現,顯著(zhu)降低了銅的(de)(de)塑性(xing)。

硫(liu)可(ke)以(yi)溶解在(zai)熔體(ti)的(de)銅中,但在(zai)室溫下(xia),其溶解度幾乎(hu)降低到零,它以(yi)硫(liu)化亞銅的(de)形式出現在(zai)晶(jing)粒晶(jing)界處,會顯著降低銅的(de)塑性。

3、氧在低氧銅桿和無氧銅桿中分布形(xing)式及其影響(xiang)

氧(yang)含量(liang)對低氧(yang)銅桿(gan)的(de)拉線性能有著明顯的(de)影響(xiang)。當(dang)氧(yang)含量(liang)增加到最(zui)佳(jia)值時(shi),銅桿(gan)的(de)斷線率最(zui)低。這(zhe)是因為氧(yang)在(zai)與(yu)大部(bu)分(fen)雜(za)質反(fan)應的(de)過程中都(dou)起到了清除器的(de)作用。適度的(de)氧(yang)還有利于(yu)去除銅液中的(de)氫,生(sheng)成水蒸(zheng)氣(qi)溢出,減少氣(qi)孔的(de)形(xing)成。最(zui)佳(jia)的(de)氧(yang)含量(liang)為拉線工藝提(ti)供(gong)了最(zui)好的(de)條件。

低(di)氧(yang)(yang)(yang)銅(tong)(tong)(tong)桿氧(yang)(yang)(yang)化(hua)(hua)物的(de)(de)(de)(de)分布(bu):在連續(xu)澆鑄中凝固的(de)(de)(de)(de)最初階段(duan),散熱速(su)率和(he)均勻(yun)冷(leng)卻(que)(que)是決(jue)定銅(tong)(tong)(tong)桿氧(yang)(yang)(yang)化(hua)(hua)物分布(bu)的(de)(de)(de)(de)主要因素(su)。不均勻(yun)冷(leng)卻(que)(que)會(hui)引起銅(tong)(tong)(tong)桿內(nei)部(bu)結(jie)構本質上(shang)的(de)(de)(de)(de)差異,但(dan)后續(xu)的(de)(de)(de)(de)熱加工(gong),柱狀(zhuang)晶通常(chang)會(hui)遭到破壞(huai),使氧(yang)(yang)(yang)化(hua)(hua)亞銅(tong)(tong)(tong)顆(ke)(ke)粒(li)(li)細(xi)微化(hua)(hua)和(he)均勻(yun)分布(bu)。氧(yang)(yang)(yang)化(hua)(hua)物顆(ke)(ke)粒(li)(li)聚集而產生的(de)(de)(de)(de)典型(xing)情(qing)況是中心爆裂。除(chu)氧(yang)(yang)(yang)化(hua)(hua)物顆(ke)(ke)粒(li)(li)分布(bu)的(de)(de)(de)(de)影響外,具有較小氧(yang)(yang)(yang)化(hua)(hua)物顆(ke)(ke)粒(li)(li)的(de)(de)(de)(de)銅(tong)(tong)(tong)桿顯示出較好(hao)的(de)(de)(de)(de)拉線特性,較大的(de)(de)(de)(de)Cu2O顆(ke)(ke)粒(li)(li)容易(yi)造(zao)成應(ying)力集中點而斷裂。

無(wu)氧(yang)(yang)(yang)銅(tong)(tong)含氧(yang)(yang)(yang)量(liang)(liang)超(chao)標,銅(tong)(tong)桿變脆(cui),延伸(shen)率(lv)下降(jiang),拉伸(shen)式樣端口顯暗紅色,結晶(jing)組織疏松。當氧(yang)(yang)(yang)含量(liang)(liang)超(chao)出8ppm時,工(gong)(gong)藝(yi)性(xing)能(neng)(neng)變差,表現為鑄造及拉伸(shen)過程中斷桿及斷線率(lv)極具(ju)增(zeng)高。這是由于(yu)氧(yang)(yang)(yang)能(neng)(neng)與銅(tong)(tong)生成(cheng)(cheng)氧(yang)(yang)(yang)化(hua)亞銅(tong)(tong)脆(cui)性(xing)相(xiang),形成(cheng)(cheng)銅(tong)(tong)-氧(yang)(yang)(yang)化(hua)亞銅(tong)(tong)共晶(jing)體(ti),以網狀組織分布在境界上(shang)。這種脆(cui)性(xing)相(xiang)硬(ying)度高,在冷變形時將會與銅(tong)(tong)機(ji)體(ti)脫離,導(dao)(dao)致(zhi)(zhi)銅(tong)(tong)桿的機(ji)械性(xing)能(neng)(neng)下降(jiang),在后續加工(gong)(gong)中容易造成(cheng)(cheng)斷裂(lie)現象(xiang)。氧(yang)(yang)(yang)含量(liang)(liang)高還能(neng)(neng)導(dao)(dao)致(zhi)(zhi)無(wu)氧(yang)(yang)(yang)銅(tong)(tong)桿導(dao)(dao)電率(lv)下降(jiang)。因此,必須嚴格控制上(shang)引連鑄工(gong)(gong)藝(yi)及產品質量(liang)(liang)。

4、氫的影響

在上引連(lian)鑄中(zhong),氧含量(liang)控制較低,氧化物(wu)的(de)(de)副(fu)作用唄**降低,但氫(qing)的(de)(de)影響成(cheng)為較顯著的(de)(de)問題。吸(xi)氣后熔(rong)體中(zhong)存在平(ping)衡反應:H2O(g)=[O]+2[H];

氣(qi)(qi)(qi)(qi)體及疏松是在(zai)(zai)結(jie)晶(jing)(jing)的(de)(de)(de)(de)過(guo)程中,氫(qing)從過(guo)飽(bao)和(he)的(de)(de)(de)(de)溶液(ye)中析(xi)(xi)出(chu)并聚(ju)集而(er)形(xing)(xing)成的(de)(de)(de)(de)。在(zai)(zai)結(jie)晶(jing)(jing)前(qian)析(xi)(xi)出(chu)的(de)(de)(de)(de)氫(qing)又可還原氧(yang)化亞銅(tong)而(er)生成水氣(qi)(qi)(qi)(qi)泡。由于上(shang)引鑄(zhu)造的(de)(de)(de)(de)特點是銅(tong)液(ye)自上(shang)而(er)下(xia)的(de)(de)(de)(de)結(jie)晶(jing)(jing),形(xing)(xing)成的(de)(de)(de)(de)液(ye)**形(xing)(xing)狀近似錐型。銅(tong)液(ye)結(jie)晶(jing)(jing)前(qian)析(xi)(xi)出(chu)的(de)(de)(de)(de)氣(qi)(qi)(qi)(qi)體在(zai)(zai)上(shang)浮過(guo)程中被(bei)堵在(zai)(zai)凝(ning)固組織內(nei),結(jie)晶(jing)(jing)時(shi)在(zai)(zai)鑄(zhu)桿內(nei)形(xing)(xing)成氣(qi)(qi)(qi)(qi)孔。上(shang)引的(de)(de)(de)(de)含氣(qi)(qi)(qi)(qi)量(liang)少時(shi),析(xi)(xi)出(chu)的(de)(de)(de)(de)氫(qing)存在(zai)(zai)于晶(jing)(jing)界處,形(xing)(xing)成疏松;含氣(qi)(qi)(qi)(qi)量(liang)多時(shi),則聚(ju)集成氣(qi)(qi)(qi)(qi)孔,因此,氣(qi)(qi)(qi)(qi)孔和(he)疏松是氫(qing)氣(qi)(qi)(qi)(qi)和(he)水蒸氣(qi)(qi)(qi)(qi)兩者形(xing)(xing)成的(de)(de)(de)(de)。

氫來源于(yu)上引生產(chan)過程中的(de)各個工藝環節(jie),如原料電(dian)(dian)解銅(tong)(tong)的(de)“銅(tong)(tong)綠”、輔料木(mu)炭**、氣候環境**、石墨結(jie)晶器未干燥等。因此,熔化(hua)爐中的(de)銅(tong)(tong)液表面(mian)應(ying)覆蓋經烘烤的(de)木(mu)炭,電(dian)(dian)解銅(tong)(tong)應(ying)盡量去(qu)除(chu)“銅(tong)(tong)綠”、“銅(tong)(tong)豆”“耳(er)朵”,對提高(gao)無氧銅(tong)(tong)桿質量非常重(zhong)要(yao)。

在連(lian)鑄連(lian)軋(ya)工(gong)藝中(zhong),往往采用適度控制氧(yang)含量來控制氫。Cu2O+ H2= 2Cu+ H2O

由(you)于(yu)銅(tong)液在鑄造過程中是(shi)自下而上結晶,銅(tong)液中的氧和氫(qing)(qing)所產(chan)生(sheng)的水蒸氣很容易上浮跑出,銅(tong)液中的氫(qing)(qing)大部分能被有效去除(chu),因而對銅(tong)桿的影響(xiang)較小。

二、表面質量

在生產電磁線等產品(pin)的過程中(zhong),對銅(tong)桿(gan)(gan)的表面(mian)質(zhi)量也需(xu)提出要求(qiu)。需(xu)要拉制(zhi)后(hou)的銅(tong)絲表面(mian)無(wu)毛刺、銅(tong)粉少、無(wu)油污(wu)。并(bing)通過扭轉(zhuan)試驗測量表面(mian)銅(tong)粉的質(zhi)量和扭轉(zhuan)后(hou)觀察銅(tong)桿(gan)(gan)的復(fu)原情況來判定其(qi)好(hao)壞。

在連(lian)鑄(zhu)連(lian)軋(ya)(ya)過程中(zhong),從鑄(zhu)造(zao)到軋(ya)(ya)制前,溫度高(gao),完全暴露于(yu)空氣(qi)中(zhong),使鑄(zhu)坯表面形成較(jiao)厚的(de)氧(yang)化(hua)層,在軋(ya)(ya)制過程中(zhong),隨著(zhu)軋(ya)(ya)輥的(de)轉動,氧(yang)化(hua)物(wu)顆粒軋(ya)(ya)入銅(tong)(tong)線(xian)表面。由(you)于(yu)氧(yang)化(hua)亞(ya)銅(tong)(tong)是(shi)高(gao)熔點脆性化(hua)合物(wu),對于(yu)軋(ya)(ya)入較(jiao)深的(de)氧(yang)化(hua)亞(ya)銅(tong)(tong),當成條狀(zhuang)的(de)聚集(ji)物(wu)遇模具拉(la)伸時,就(jiu)會(hui)是(shi)銅(tong)(tong)桿外表面產生毛刺,給后續的(de)涂漆造(zao)成麻煩(fan)。

而上引連鑄工藝(yi)制(zhi)造的(de)無氧銅(tong)桿,由于鑄造和冷卻完全與氧隔絕(jue),后(hou)續亦無熱軋過程(cheng),銅(tong)桿表面無軋入表面的(de)氧化物,質量較(jiao)好,拉制(zhi)后(hou)銅(tong)粉少(shao),上述(shu)問題較(jiao)少(shao)存在(zai)。

無氧銅(tong)(tong)桿(gan)也分進口(kou)設(she)備(bei)做的和國(guo)產(chan)(chan)(chan)設(she)備(bei)做的,但目前(qian)進口(kou)產(chan)(chan)(chan)品已無明顯優(you)勢,銅(tong)(tong)桿(gan)產(chan)(chan)(chan)品出來后區別不是(shi)很大,只要銅(tong)(tong)板選的好,生產(chan)(chan)(chan)控制比較穩(wen)定,國(guo)產(chan)(chan)(chan)設(she)備(bei)也能產(chan)(chan)(chan)出可(ke)拉(la)伸0.05的銅(tong)(tong)桿(gan).進口(kou)設(she)備(bei)一般是(shi)芬蘭奧托(tuo)昆普的設(she)備(bei),國(guo)產(chan)(chan)(chan)設(she)備(bei)最好的應該是(shi)上(shang)海的海軍廠的了,生產(chan)(chan)(chan)時間最長,軍工企業,質量可(ke)靠。

低氧銅(tong)桿(gan)進口(kou)設(she)備國際主要(yao)有兩種,一種是美國南線(xian)設(she)備,英(ying)文是SOUTHWIRE,國內廠家是南京華(hua)新,江西(xi)銅(tong)業,另一種是德(de)國CONTIROD設(she)備,國內廠家是常(chang)州金源,天津大(da)無縫(feng)。

無(wu)(wu)(wu)氧(yang)(yang)(yang)(yang)(yang)及低氧(yang)(yang)(yang)(yang)(yang)桿(gan)(gan)(gan)(gan)(gan)(gan)(gan)從含氧(yang)(yang)(yang)(yang)(yang)量(liang)上容易區別(bie),無(wu)(wu)(wu)氧(yang)(yang)(yang)(yang)(yang)銅(tong)是(shi)含氧(yang)(yang)(yang)(yang)(yang)量(liang)在(zai)(zai)10-20個PPM以(yi)下,但(dan)(dan)目(mu)前(qian)有的(de)(de)廠(chang)家只(zhi)能(neng)(neng)做到50個PPM以(yi)下.低氧(yang)(yang)(yang)(yang)(yang)銅(tong)桿(gan)(gan)(gan)(gan)(gan)(gan)(gan)在(zai)(zai) 200-400個PPM,好(hao)的(de)(de)桿(gan)(gan)(gan)(gan)(gan)(gan)(gan)子(zi)一般(ban)含氧(yang)(yang)(yang)(yang)(yang)量(liang)控制在(zai)(zai)250個PPM左右,無(wu)(wu)(wu)氧(yang)(yang)(yang)(yang)(yang)桿(gan)(gan)(gan)(gan)(gan)(gan)(gan)一般(ban)采取的(de)(de)是(shi)上引法(fa),低氧(yang)(yang)(yang)(yang)(yang)桿(gan)(gan)(gan)(gan)(gan)(gan)(gan)是(shi)連鑄連軋,兩種產品相對(dui)而(er)言低氧(yang)(yang)(yang)(yang)(yang)桿(gan)(gan)(gan)(gan)(gan)(gan)(gan)對(dui)漆包線(xian)性(xing) 能(neng)(neng)更適應些,如(ru)(ru)柔軟性(xing),回彈角,繞線(xian)性(xing)能(neng)(neng).但(dan)(dan)低氧(yang)(yang)(yang)(yang)(yang)桿(gan)(gan)(gan)(gan)(gan)(gan)(gan)對(dui)拉(la)絲條件(jian)相對(dui)要苛刻些,同(tong)樣(yang)拉(la)伸(shen)(shen)0.2的(de)(de)細絲,如(ru)(ru)果伸(shen)(shen)線(xian)條件(jian)不(bu)好(hao),普通的(de)(de)無(wu)(wu)(wu)氧(yang)(yang)(yang)(yang)(yang)桿(gan)(gan)(gan)(gan)(gan)(gan)(gan)可拉(la)而(er)好(hao)的(de)(de)低氧(yang)(yang)(yang)(yang)(yang)桿(gan)(gan)(gan)(gan)(gan)(gan)(gan)就斷 線(xian),但(dan)(dan)如(ru)(ru)果放在(zai)(zai)好(hao)的(de)(de)伸(shen)(shen)線(xian)條件(jian),同(tong)樣(yang)的(de)(de)桿(gan)(gan)(gan)(gan)(gan)(gan)(gan)子(zi),低氧(yang)(yang)(yang)(yang)(yang)桿(gan)(gan)(gan)(gan)(gan)(gan)(gan)說(shuo)不(bu)定就能(neng)(neng)拉(la)到雙(shuang)零五,而(er)普通無(wu)(wu)(wu)氧(yang)(yang)(yang)(yang)(yang)桿(gan)(gan)(gan)(gan)(gan)(gan)(gan)最(zui)多只(zhi)能(neng)(neng)拉(la)伸(shen)(shen)到0.1而(er)已,當然(ran)做的(de)(de)最(zui)細的(de)(de)如(ru)(ru)雙(shuang)零二卻非得依靠進(jin)口的(de)(de) 無(wu)(wu)(wu)氧(yang)(yang)(yang)(yang)(yang)銅(tong)桿(gan)(gan)(gan)(gan)(gan)(gan)(gan)了.目(mu)前(qian)有企業(ye)嘗試用剝皮的(de)(de)方式(shi)來(lai)處(chu)理(li)低氧(yang)(yang)(yang)(yang)(yang)桿(gan)(gan)(gan)(gan)(gan)(gan)(gan)來(lai)伸(shen)(shen)0.03線(xian).但(dan)(dan)有關這方面的(de)(de)內容我還不(bu)是(shi)很(hen)清楚(chu)。

音響線一般反而喜歡用無(wu)氧桿(gan),這和無(wu)氧桿(gan)是單(dan)晶銅,低氧桿(gan)是多晶銅有關。

氧(yang)銅(tong)桿和無氧(yang)銅(tong)桿由于制(zhi)造方法的不同,致使存在差(cha)別(bie),具有各自的特點。

一、關于氧的(de)(de)吸入和脫去(qu)以及它的(de)(de)存在狀態

生產銅(tong)(tong)(tong)(tong)(tong)桿(gan)的(de)(de)陰極銅(tong)(tong)(tong)(tong)(tong)的(de)(de)含(han)氧(yang)(yang)量(liang)一(yi)般在(zai)(zai)10—50ppm,在(zai)(zai)常(chang)溫下(xia)(xia)(xia)氧(yang)(yang)在(zai)(zai)銅(tong)(tong)(tong)(tong)(tong)中的(de)(de)固溶度約(yue)2ppm。低(di)氧(yang)(yang)銅(tong)(tong)(tong)(tong)(tong)桿(gan)的(de)(de)含(han)氧(yang)(yang)量(liang)一(yi)般在(zai)(zai)200(175)—400(450)ppm,因此氧(yang)(yang)的(de)(de)進入是(shi)在(zai)(zai)銅(tong)(tong)(tong)(tong)(tong)的(de)(de)液態下(xia)(xia)(xia)吸入的(de)(de),而(er)(er)上(shang)引法無(wu)氧(yang)(yang)銅(tong)(tong)(tong)(tong)(tong)桿(gan)則相反(fan),氧(yang)(yang)在(zai)(zai)液態銅(tong)(tong)(tong)(tong)(tong)下(xia)(xia)(xia)保(bao)持相當時間后,被還(huan)原而(er)(er)脫去(qu),通(tong)常(chang)這(zhe)種(zhong)桿(gan)的(de)(de)含(han)氧(yang)(yang)量(liang)都在(zai)(zai)10—50ppm以(yi)(yi)下(xia)(xia)(xia),最低(di)可(ke)達(da)1-2ppm,從組織上(shang)看,低(di)氧(yang)(yang)銅(tong)(tong)(tong)(tong)(tong)中的(de)(de)氧(yang)(yang),以(yi)(yi)氧(yang)(yang)化銅(tong)(tong)(tong)(tong)(tong)狀態,存在(zai)(zai)于晶(jing)粒(li)邊(bian)界(jie)附近(jin),這(zhe)對(dui)(dui)低(di)氧(yang)(yang)銅(tong)(tong)(tong)(tong)(tong)桿(gan)而(er)(er)言可(ke)以(yi)(yi)說是(shi)常(chang)見(jian)(jian)的(de)(de)但對(dui)(dui)無(wu)氧(yang)(yang)銅(tong)(tong)(tong)(tong)(tong)桿(gan)則很少見(jian)(jian)。氧(yang)(yang)化銅(tong)(tong)(tong)(tong)(tong)以(yi)(yi)夾雜形式在(zai)(zai)晶(jing)界(jie)出現(xian)對(dui)(dui)材料(liao)的(de)(de)韌性(xing)(xing)產生負面(mian)影響。而(er)(er)無(wu)氧(yang)(yang)銅(tong)(tong)(tong)(tong)(tong)中的(de)(de)氧(yang)(yang)很低(di),所以(yi)(yi)這(zhe)種(zhong)銅(tong)(tong)(tong)(tong)(tong)的(de)(de)組織是(shi)均勻(yun)的(de)(de)單相組織對(dui)(dui)韌性(xing)(xing)有利(li)。在(zai)(zai)無(wu)氧(yang)(yang)銅(tong)(tong)(tong)(tong)(tong)桿(gan)中的(de)(de)多孔(kong)性(xing)(xing)是(shi)不常(chang)見(jian)(jian)的(de)(de),而(er)(er)在(zai)(zai)低(di)氧(yang)(yang)銅(tong)(tong)(tong)(tong)(tong)桿(gan)中則是(shi)常(chang)見(jian)(jian)的(de)(de)一(yi)種(zhong)缺陷(xian)。

二、熱軋組(zu)織和鑄造組(zu)織的區別

低(di)氧(yang)銅(tong)(tong)(tong)桿(gan)由(you)于經(jing)過熱軋,所(suo)以其組(zu)(zu)織(zhi)屬熱加(jia)工組(zu)(zu)織(zhi),原來(lai)的(de)(de)(de)(de)(de)(de)鑄(zhu)造組(zu)(zu)織(zhi)已經(jing)破(po)碎,在(zai)(zai)(zai)8mm的(de)(de)(de)(de)(de)(de)桿(gan)時已有(you)再(zai)結晶的(de)(de)(de)(de)(de)(de)形式出(chu)現,而無(wu)氧(yang)銅(tong)(tong)(tong)桿(gan)屬鑄(zhu)造組(zu)(zu)織(zhi),晶粒(li)(li)粗大,這是(shi)為(wei)什么,無(wu)氧(yang)銅(tong)(tong)(tong)的(de)(de)(de)(de)(de)(de)再(zai)結晶溫度較(jiao)(jiao)(jiao)高(gao)(gao),需要(yao)較(jiao)(jiao)(jiao)高(gao)(gao)退(tui)火(huo)(huo)(huo)溫度的(de)(de)(de)(de)(de)(de)固有(you)原因。這是(shi)因為(wei),再(zai)結晶發生在(zai)(zai)(zai)晶粒(li)(li)邊界(jie)附近,無(wu)氧(yang)銅(tong)(tong)(tong)桿(gan)組(zu)(zu)織(zhi)晶粒(li)(li)粗大,晶粒(li)(li)尺寸甚至能(neng)達幾個(ge)毫米,因而晶粒(li)(li)邊界(jie)少,即使通過拉(la)制(zhi)變形,但(dan)晶粒(li)(li)邊界(jie)相對低(di)氧(yang)銅(tong)(tong)(tong)桿(gan)還(huan)是(shi)較(jiao)(jiao)(jiao)少,所(suo)以需要(yao)較(jiao)(jiao)(jiao)高(gao)(gao)的(de)(de)(de)(de)(de)(de)退(tui)火(huo)(huo)(huo)功率。對無(wu)氧(yang)銅(tong)(tong)(tong)成功的(de)(de)(de)(de)(de)(de)退(tui)火(huo)(huo)(huo)要(yao)求是(shi):由(you)桿(gan)經(jing)拉(la)制(zhi),但(dan)尚未鑄(zhu)造組(zu)(zu)織(zhi)的(de)(de)(de)(de)(de)(de)線時的(de)(de)(de)(de)(de)(de)第一次退(tui)火(huo)(huo)(huo),其退(tui)火(huo)(huo)(huo)功率應(ying)比同樣情況的(de)(de)(de)(de)(de)(de)低(di)氧(yang)銅(tong)(tong)(tong)高(gao)(gao)10——15%。經(jing)繼續(xu)拉(la)制(zhi),在(zai)(zai)(zai)以后階段的(de)(de)(de)(de)(de)(de)退(tui)火(huo)(huo)(huo)功率應(ying)留有(you)足夠(gou)的(de)(de)(de)(de)(de)(de)余(yu)量和(he)對低(di)氧(yang)銅(tong)(tong)(tong)和(he)無(wu)氧(yang)銅(tong)(tong)(tong)切(qie)實區別執行不同的(de)(de)(de)(de)(de)(de)退(tui)火(huo)(huo)(huo)工藝,以保證(zheng)在(zai)(zai)(zai)制(zhi)品(pin)和(he)成品(pin)導(dao)線的(de)(de)(de)(de)(de)(de)柔軟性。

三、夾(jia)雜,氧含量波(bo)動,表(biao)面氧化物和可能存在的(de)熱軋缺陷的(de)差別

無(wu)氧(yang)銅(tong)(tong)桿的(de)(de)可(ke)拉(la)性在所有(you)(you)線徑里與低氧(yang)銅(tong)(tong)桿相(xiang)比都(dou)是優越(yue)的(de)(de),除(chu)上述組(zu)織原因外(wai),無(wu)氧(yang)銅(tong)(tong)桿夾雜少(shao),含氧(yang)量穩(wen)定,無(wu)熱(re)軋可(ke)能產(chan)生的(de)(de)缺(que)陷,桿表氧(yang)化(hua)(hua)物(wu)厚(hou)度可(ke)達(da)≤15A。在連(lian)鑄(zhu)連(lian)軋生產(chan)過程(cheng)中如(ru)果(guo)工藝不穩(wen)定,對(dui)氧(yang)監(jian)控不嚴,含氧(yang)量不穩(wen)定將直(zhi)接影(ying)響桿的(de)(de)性能。如(ru)果(guo)桿的(de)(de)表面氧(yang)化(hua)(hua)物(wu)能在后工序的(de)(de)連(lian)續清洗中得以(yi)彌補外(wai),但比較麻(ma)煩的(de)(de)是有(you)(you)相(xiang)當多的(de)(de)氧(yang)化(hua)(hua)物(wu)存在于“皮下(xia)”,對(dui)拉(la)線斷線影(ying)響更直(zhi)接,故而在拉(la)制微細(xi)線,超微細(xi)線時,為了減少(shao)斷線,有(you)(you)時要對(dui)銅(tong)(tong)桿采取(qu)不得已(yi)的(de)(de)辦法——剝皮,甚至二次剝皮的(de)(de)原因所在,目的(de)(de)要除(chu)去(qu)皮下(xia)氧(yang)化(hua)(hua)物(wu)。

四、低氧(yang)銅(tong)(tong)桿和無(wu)氧(yang)銅(tong)(tong)桿的韌性有差別

兩者都(dou)可以拉到(dao)0.015mm,但在低(di)溫(wen)超(chao)導線(xian)中的低(di)溫(wen)級無氧(yang)銅,其(qi)細絲(si)間的間距只有0.001mm.

五、從制(zhi)桿(gan)的原材料到制(zhi)線(xian)的經濟性(xing)有差別(bie)。

制造無(wu)氧(yang)銅(tong)桿要(yao)求(qiu)質(zhi)量較高的(de)原材料。一般,拉制直徑>1mm的(de)銅(tong)線時(shi),低氧(yang)銅(tong)桿的(de)優點比(bi)較明顯,而無(wu)氧(yang)銅(tong)桿顯得更為(wei)優越的(de)是拉制直徑<0.5mm的(de)銅(tong)線。

六、低氧銅桿的(de)制線工藝與無氧銅桿的(de)有(you)所不同。

低(di)氧銅(tong)桿(gan)的(de)(de)制線工藝(yi)不(bu)(bu)能(neng)照搬到無氧銅(tong)桿(gan)的(de)(de)制線工藝(yi)上來,至少兩(liang)者的(de)(de)退火(huo)工藝(yi)是(shi)不(bu)(bu)同的(de)(de)。因為線的(de)(de)柔軟性(xing)深受材料成份(fen)和(he)制桿(gan),制線和(he)退火(huo)工藝(yi)的(de)(de)影(ying)響,不(bu)(bu)能(neng)簡單地說低(di)氧銅(tong)或無氧銅(tong)誰(shui)軟誰(shui)硬。