熱門關鍵詞:
來源:行業動態 閱讀:109616 發布時間:2019-07-05
導讀:由于(yu)生(sheng)(sheng)產(chan)銅(tong)(tong)桿(gan)(gan)的兩者的工藝不(bu)(bu)同(tong),所生(sheng)(sheng)產(chan)的銅(tong)(tong)桿(gan)(gan)中(zhong)的含氧(yang)量及外觀(guan)就不(bu)(bu)同(tong)。上引生(sheng)(sheng)產(chan)的銅(tong)(tong)桿(gan)(gan),工藝得當氧(yang)含量在10ppm以下(xia),叫無(wu)氧(yang)銅(tong)(tong)桿(gan)(gan);連鑄連鑄生(sheng)(sheng)產(chan)的銅(tong)(tong)桿(gan)(gan) 是在保護條件下(xia)的熱軋,氧(yang)含量在200-500ppm范(fan)圍內,但(dan)有時(shi)也(ye)(ye)高達(da)700ppm以上,一般情(qing)況下(xia),此種方法(fa)生(sheng)(sheng)產(chan)的銅(tong)(tong)外表光亮,低(di)氧(yang)銅(tong)(tong)桿(gan)(gan),有時(shi)也(ye)(ye)叫光桿(gan)(gan)。
銅(tong)(tong)桿(gan)是電纜行(xing)(xing)業的(de)(de)主要(yao)原(yuan)料,生(sheng)產(chan)的(de)(de)方(fang)式(shi)主要(yao)有(you)兩(liang)種(zhong)——連(lian)鑄(zhu)(zhu)連(lian)軋(ya)(ya)(ya)法和上引連(lian)鑄(zhu)(zhu)法。連(lian)鑄(zhu)(zhu)連(lian)軋(ya)(ya)(ya)低氧(yang)銅(tong)(tong)桿(gan)的(de)(de)生(sheng)產(chan)方(fang)法較(jiao)多,其(qi)特點是金(jin)屬(shu)在(zai)豎爐(lu)中(zhong)融(rong)化后(hou),銅(tong)(tong)液通(tong)(tong)過保溫爐(lu)、溜槽、中(zhong)間包,從澆(jiao)管(guan)進(jin)入封閉的(de)(de)模腔內(nei)(nei),采用(yong)較(jiao)大的(de)(de)冷(leng)卻強度進(jin)行(xing)(xing)冷(leng)卻,形成鑄(zhu)(zhu)坯,然后(hou)進(jin)行(xing)(xing)多道次軋(ya)(ya)(ya)制(zhi),生(sheng)產(chan)的(de)(de)低氧(yang)銅(tong)(tong)桿(gan)為熱加工(gong)(gong)(gong)組(zu)織,原(yuan)來的(de)(de)鑄(zhu)(zhu)造(zao)組(zu)織已(yi)經(jing)破碎,含(han)(han)氧(yang)量(liang)一般為200~400ppm之間。無氧(yang)銅(tong)(tong)桿(gan)國內(nei)(nei)基本全部采用(yong)上引連(lian)鑄(zhu)(zhu)法生(sheng)產(chan),金(jin)屬(shu)在(zai)感應電爐(lu)中(zhong)融(rong)化后(hou)通(tong)(tong)過石墨模進(jin)行(xing)(xing)上引連(lian)續鑄(zhu)(zhu)造(zao),之后(hou)進(jin)行(xing)(xing)冷(leng)軋(ya)(ya)(ya)或冷(leng)加工(gong)(gong)(gong),生(sheng)產(chan)的(de)(de)無氧(yang)銅(tong)(tong)桿(gan)為鑄(zhu)(zhu)造(zao)組(zu)織,含(han)(han)氧(yang)量(liang)一般在(zai)20ppm以下。由(you)于制(zhi)造(zao)工(gong)(gong)(gong)藝的(de)(de)不同,所(suo)以在(zai)組(zu)織結構、氧(yang)含(han)(han)量(liang)分(fen)布、雜質的(de)(de)形式(shi)及(ji)分(fen)布等諸多方(fang)面有(you)較(jiao)大差別。
一、拉制性能
銅桿(gan)的拉制(zhi)性能(neng)跟很多因素有關,如雜質的含量(liang)、氧(yang)含量(liang)及分(fen)布、工藝控制(zhi)等(deng)。下面分(fen)別(bie)從以上幾個(ge)方面對銅桿(gan)的拉制(zhi)性能(neng)進行分(fen)析。
1、熔化(hua)方(fang)式對S等雜質(zhi)的影響
連(lian)鑄連(lian)軋(ya)生(sheng)產銅(tong)桿主(zhu)要(yao)是(shi)通過氣體的燃(ran)燒使銅(tong)桿熔(rong)(rong)化(hua),在(zai)燃(ran)燒的過程中(zhong),通過氧(yang)化(hua)和揮發作用,可一定(ding)程度減(jian)少部(bu)分雜質進入銅(tong)液,因此(ci)連(lian)鑄連(lian)軋(ya)法對(dui)原料要(yao)求(qiu)相對(dui)低一些(xie)。上引連(lian)鑄生(sheng)產無氧(yang)銅(tong)桿,由(you)于是(shi)用感(gan)應電爐熔(rong)(rong)化(hua),電解(jie)銅(tong)表面的“銅(tong)綠”“銅(tong)豆”基本(ben)都熔(rong)(rong)入到(dao)銅(tong)液中(zhong)。其中(zhong)熔(rong)(rong)入的S對(dui)無氧(yang)銅(tong)桿塑(su)性(xing)影響極(ji)大,會(hui)增加(jia)拉絲斷線(xian)率。
2、鑄(zhu)造過程中雜質的進入
在生產過(guo)(guo)程(cheng)中,連鑄(zhu)連軋工藝(yi)(yi)需通過(guo)(guo)保溫爐、溜槽、中間包轉(zhuan)運銅(tong)液(ye),相對(dui)(dui)容(rong)易造成耐火(huo)材料的剝落,在軋制(zhi)過(guo)(guo)程(cheng)中需要通過(guo)(guo)軋輥,造成鐵質(zhi)的脫落,會給銅(tong)桿造成外部夾(jia)雜(za)。而(er)熱軋中皮上和皮下氧化物(wu)的軋入(ru),會給低氧桿的拉絲造成不利的影響。上引(yin)連鑄(zhu)法生產工藝(yi)(yi)流(liu)程(cheng)較短,銅(tong)液(ye)是(shi)通過(guo)(guo)聯體爐內潛流(liu)式(shi)完(wan)成,對(dui)(dui)耐火(huo)材料的沖擊不大,結晶是(shi)通過(guo)(guo)石墨模(mo)內進(jin)行,所以過(guo)(guo)程(cheng)中可能產生的污染源較少,雜(za)質(zhi)進(jin)入(ru)的機(ji)會較少。
O、S、P是與銅(tong)(tong)會(hui)生產化(hua)(hua)合物的元素。在熔(rong)態銅(tong)(tong)中,氧(yang)(yang)可以溶解一部分,但當(dang)銅(tong)(tong)冷凝時,氧(yang)(yang)幾乎不溶解于銅(tong)(tong)中。熔(rong)態時所(suo)溶解的氧(yang)(yang),以銅(tong)(tong)=氧(yang)(yang)化(hua)(hua)亞銅(tong)(tong)共晶(jing)體析出,分布(bu)在晶(jing)粒晶(jing)界處。銅(tong)(tong)-氧(yang)(yang)化(hua)(hua)亞銅(tong)(tong)共晶(jing)體的出現,顯(xian)著降低了銅(tong)(tong)的塑性(xing)。
硫可(ke)以溶解在(zai)熔體的(de)銅中,但在(zai)室溫(wen)下,其(qi)溶解度幾乎降低到(dao)零,它以硫化亞銅的(de)形式出現(xian)在(zai)晶粒晶界處,會顯著降低銅的(de)塑性。
3、氧(yang)在低(di)氧(yang)銅桿(gan)(gan)和無氧(yang)銅桿(gan)(gan)中分布形式及其影響(xiang)
氧(yang)含量(liang)對低氧(yang)銅桿的(de)(de)(de)(de)拉線(xian)性(xing)能有著明顯的(de)(de)(de)(de)影響。當氧(yang)含量(liang)增加到最(zui)佳值時,銅桿的(de)(de)(de)(de)斷(duan)線(xian)率(lv)最(zui)低。這是因為氧(yang)在與大(da)部分(fen)雜質(zhi)反應的(de)(de)(de)(de)過程中都起(qi)到了清除器(qi)的(de)(de)(de)(de)作用。適(shi)度的(de)(de)(de)(de)氧(yang)還有利于去(qu)除銅液中的(de)(de)(de)(de)氫,生成水蒸氣溢出,減少氣孔的(de)(de)(de)(de)形成。最(zui)佳的(de)(de)(de)(de)氧(yang)含量(liang)為拉線(xian)工(gong)藝提供了最(zui)好(hao)的(de)(de)(de)(de)條件。
低(di)氧(yang)銅桿氧(yang)化物(wu)的(de)(de)(de)分(fen)布(bu):在連續(xu)澆鑄中凝固的(de)(de)(de)最初階段,散熱速率和均勻(yun)冷卻是(shi)決定銅桿氧(yang)化物(wu)分(fen)布(bu)的(de)(de)(de)主要因素。不均勻(yun)冷卻會引(yin)起銅桿內部(bu)結構本質上的(de)(de)(de)差異,但后續(xu)的(de)(de)(de)熱加工,柱狀晶通(tong)常會遭到(dao)破壞(huai),使氧(yang)化亞銅顆(ke)(ke)粒(li)細微化和均勻(yun)分(fen)布(bu)。氧(yang)化物(wu)顆(ke)(ke)粒(li)聚集而(er)產生的(de)(de)(de)典型情況是(shi)中心(xin)爆裂。除氧(yang)化物(wu)顆(ke)(ke)粒(li)分(fen)布(bu)的(de)(de)(de)影(ying)響外,具有較小氧(yang)化物(wu)顆(ke)(ke)粒(li)的(de)(de)(de)銅桿顯示出(chu)較好的(de)(de)(de)拉(la)線特性(xing),較大的(de)(de)(de)Cu2O顆(ke)(ke)粒(li)容易造成應力集中點(dian)而(er)斷裂。
無(wu)氧(yang)銅(tong)含(han)氧(yang)量(liang)超標,銅(tong)桿(gan)變脆(cui),延伸(shen)(shen)率下(xia)降,拉伸(shen)(shen)式樣端(duan)口顯(xian)暗(an)紅色(se),結晶組(zu)織疏松。當氧(yang)含(han)量(liang)超出8ppm時,工(gong)藝性(xing)(xing)能(neng)(neng)變差,表(biao)現為鑄造(zao)及(ji)拉伸(shen)(shen)過程中斷桿(gan)及(ji)斷線率極具增高。這(zhe)(zhe)是由于(yu)氧(yang)能(neng)(neng)與(yu)(yu)銅(tong)生成(cheng)氧(yang)化亞銅(tong)脆(cui)性(xing)(xing)相,形(xing)成(cheng)銅(tong)-氧(yang)化亞銅(tong)共(gong)晶體,以網(wang)狀組(zu)織分布在境界上(shang)。這(zhe)(zhe)種脆(cui)性(xing)(xing)相硬度高,在冷變形(xing)時將(jiang)會與(yu)(yu)銅(tong)機體脫離,導(dao)致(zhi)銅(tong)桿(gan)的機械性(xing)(xing)能(neng)(neng)下(xia)降,在后(hou)續(xu)加(jia)工(gong)中容易造(zao)成(cheng)斷裂(lie)現象。氧(yang)含(han)量(liang)高還能(neng)(neng)導(dao)致(zhi)無(wu)氧(yang)銅(tong)桿(gan)導(dao)電率下(xia)降。因此(ci),必須(xu)嚴(yan)格(ge)控制上(shang)引連鑄工(gong)藝及(ji)產品質(zhi)量(liang)。
4、氫的影響
在(zai)上引連鑄中,氧(yang)含(han)量(liang)控制較低,氧(yang)化物的(de)副(fu)作用唄**降低,但氫的(de)影響成為較顯(xian)著的(de)問題。吸氣后熔體中存在(zai)平衡(heng)反應(ying):H2O(g)=[O]+2[H];
氣(qi)(qi)(qi)體(ti)及疏松是在結(jie)晶的(de)(de)(de)(de)過(guo)程(cheng)中,氫(qing)(qing)從過(guo)飽和(he)(he)的(de)(de)(de)(de)溶液中析(xi)出(chu)(chu)并(bing)聚集而(er)形(xing)(xing)成(cheng)(cheng)(cheng)(cheng)的(de)(de)(de)(de)。在結(jie)晶前(qian)析(xi)出(chu)(chu)的(de)(de)(de)(de)氫(qing)(qing)又可(ke)還原氧(yang)化亞銅(tong)而(er)生成(cheng)(cheng)(cheng)(cheng)水(shui)氣(qi)(qi)(qi)泡。由(you)于(yu)(yu)上引鑄造的(de)(de)(de)(de)特點是銅(tong)液自上而(er)下(xia)的(de)(de)(de)(de)結(jie)晶,形(xing)(xing)成(cheng)(cheng)(cheng)(cheng)的(de)(de)(de)(de)液**形(xing)(xing)狀近似錐(zhui)型。銅(tong)液結(jie)晶前(qian)析(xi)出(chu)(chu)的(de)(de)(de)(de)氣(qi)(qi)(qi)體(ti)在上浮過(guo)程(cheng)中被堵(du)在凝固組織內,結(jie)晶時在鑄桿內形(xing)(xing)成(cheng)(cheng)(cheng)(cheng)氣(qi)(qi)(qi)孔。上引的(de)(de)(de)(de)含氣(qi)(qi)(qi)量少時,析(xi)出(chu)(chu)的(de)(de)(de)(de)氫(qing)(qing)存在于(yu)(yu)晶界處,形(xing)(xing)成(cheng)(cheng)(cheng)(cheng)疏松;含氣(qi)(qi)(qi)量多(duo)時,則聚集成(cheng)(cheng)(cheng)(cheng)氣(qi)(qi)(qi)孔,因此,氣(qi)(qi)(qi)孔和(he)(he)疏松是氫(qing)(qing)氣(qi)(qi)(qi)和(he)(he)水(shui)蒸(zheng)氣(qi)(qi)(qi)兩者(zhe)形(xing)(xing)成(cheng)(cheng)(cheng)(cheng)的(de)(de)(de)(de)。
氫來源(yuan)于上引(yin)生產過(guo)程中的各個工藝環節,如(ru)原料電解銅(tong)的“銅(tong)綠(lv)”、輔(fu)料木(mu)炭(tan)**、氣候環境**、石墨結晶器(qi)未(wei)干燥等。因此(ci),熔化爐中的銅(tong)液表面應(ying)覆蓋經烘(hong)烤的木(mu)炭(tan),電解銅(tong)應(ying)盡量去除“銅(tong)綠(lv)”、“銅(tong)豆”“耳(er)朵”,對(dui)提高無氧銅(tong)桿質量非常重要(yao)。
在連(lian)(lian)鑄連(lian)(lian)軋工藝(yi)中(zhong),往往采用適度控制(zhi)氧含量來控制(zhi)氫(qing)。Cu2O+ H2= 2Cu+ H2O
由于(yu)銅(tong)液在(zai)鑄造(zao)過程(cheng)中是自下而上結晶,銅(tong)液中的氧和氫所產(chan)生的水蒸氣很容易上浮跑出,銅(tong)液中的氫大(da)部分能被有效去(qu)除,因(yin)而對銅(tong)桿的影響較小。
二、表面質量
在生產電磁線等(deng)產品的(de)過(guo)(guo)程中,對銅(tong)桿的(de)表面(mian)質量(liang)也需(xu)提出要求。需(xu)要拉制后(hou)的(de)銅(tong)絲(si)表面(mian)無毛刺(ci)、銅(tong)粉少、無油污。并(bing)通過(guo)(guo)扭轉(zhuan)試驗(yan)測量(liang)表面(mian)銅(tong)粉的(de)質量(liang)和扭轉(zhuan)后(hou)觀察銅(tong)桿的(de)復原情況來判定(ding)其好壞。
在連(lian)鑄(zhu)連(lian)軋(ya)(ya)(ya)過程中,從鑄(zhu)造到軋(ya)(ya)(ya)制前,溫度高(gao),完全暴露(lu)于(yu)空氣中,使鑄(zhu)坯表(biao)面(mian)形(xing)成較厚的(de)氧化層,在軋(ya)(ya)(ya)制過程中,隨著軋(ya)(ya)(ya)輥的(de)轉動,氧化物(wu)顆粒軋(ya)(ya)(ya)入銅線(xian)表(biao)面(mian)。由于(yu)氧化亞(ya)(ya)銅是(shi)高(gao)熔點脆性化合物(wu),對于(yu)軋(ya)(ya)(ya)入較深的(de)氧化亞(ya)(ya)銅,當成條(tiao)狀的(de)聚集(ji)物(wu)遇模(mo)具拉伸時,就會是(shi)銅桿外表(biao)面(mian)產生毛(mao)刺(ci),給后續(xu)的(de)涂漆造成麻煩。
而上(shang)引連鑄(zhu)工藝制造(zao)的無氧銅桿,由于(yu)鑄(zhu)造(zao)和冷卻完全與氧隔絕,后續亦無熱軋過程,銅桿表面無軋入表面的氧化物,質量較(jiao)好,拉制后銅粉少,上(shang)述問題較(jiao)少存在。
無(wu)氧銅桿也(ye)分(fen)進(jin)口(kou)設(she)備(bei)做的(de)(de)和國(guo)產(chan)(chan)設(she)備(bei)做的(de)(de),但(dan)目前(qian)進(jin)口(kou)產(chan)(chan)品已無(wu)明顯優勢,銅桿產(chan)(chan)品出來后區別不是(shi)很大(da),只要銅板選(xuan)的(de)(de)好,生產(chan)(chan)控制比較(jiao)穩定,國(guo)產(chan)(chan)設(she)備(bei)也(ye)能產(chan)(chan)出可拉伸0.05的(de)(de)銅桿.進(jin)口(kou)設(she)備(bei)一般是(shi)芬蘭奧托昆普的(de)(de)設(she)備(bei),國(guo)產(chan)(chan)設(she)備(bei)最好的(de)(de)應該(gai)是(shi)上海的(de)(de)海軍廠的(de)(de)了,生產(chan)(chan)時間最長,軍工企(qi)業,質量可靠。
低氧(yang)銅(tong)桿進口設備國(guo)際主(zhu)要(yao)有(you)兩種,一種是(shi)美國(guo)南線設備,英文是(shi)SOUTHWIRE,國(guo)內廠家是(shi)南京華新,江西銅(tong)業,另一種是(shi)德國(guo)CONTIROD設備,國(guo)內廠家是(shi)常州金源(yuan),天津大(da)無縫。
無(wu)(wu)氧(yang)(yang)及低氧(yang)(yang)桿(gan)(gan)(gan)(gan)(gan)從(cong)含(han)氧(yang)(yang)量上容(rong)易區別(bie),無(wu)(wu)氧(yang)(yang)銅(tong)(tong)是(shi)(shi)(shi)含(han)氧(yang)(yang)量在10-20個(ge)PPM以下,但(dan)目前有的(de)(de)(de)廠家只能(neng)(neng)做到50個(ge)PPM以下.低氧(yang)(yang)銅(tong)(tong)桿(gan)(gan)(gan)(gan)(gan)在 200-400個(ge)PPM,好(hao)的(de)(de)(de)桿(gan)(gan)(gan)(gan)(gan)子一般含(han)氧(yang)(yang)量控(kong)制在250個(ge)PPM左右,無(wu)(wu)氧(yang)(yang)桿(gan)(gan)(gan)(gan)(gan)一般采取的(de)(de)(de)是(shi)(shi)(shi)上引法,低氧(yang)(yang)桿(gan)(gan)(gan)(gan)(gan)是(shi)(shi)(shi)連鑄連軋,兩種(zhong)產(chan)品相對而言低氧(yang)(yang)桿(gan)(gan)(gan)(gan)(gan)對漆包線性 能(neng)(neng)更(geng)適應些(xie)(xie),如柔軟性,回彈角(jiao),繞線性能(neng)(neng).但(dan)低氧(yang)(yang)桿(gan)(gan)(gan)(gan)(gan)對拉(la)絲條(tiao)件(jian)相對要苛(ke)刻些(xie)(xie),同樣拉(la)伸(shen)0.2的(de)(de)(de)細(xi)絲,如果伸(shen)線條(tiao)件(jian)不好(hao),普(pu)(pu)通的(de)(de)(de)無(wu)(wu)氧(yang)(yang)桿(gan)(gan)(gan)(gan)(gan)可拉(la)而好(hao)的(de)(de)(de)低氧(yang)(yang)桿(gan)(gan)(gan)(gan)(gan)就(jiu)斷 線,但(dan)如果放在好(hao)的(de)(de)(de)伸(shen)線條(tiao)件(jian),同樣的(de)(de)(de)桿(gan)(gan)(gan)(gan)(gan)子,低氧(yang)(yang)桿(gan)(gan)(gan)(gan)(gan)說不定就(jiu)能(neng)(neng)拉(la)到雙零(ling)五(wu),而普(pu)(pu)通無(wu)(wu)氧(yang)(yang)桿(gan)(gan)(gan)(gan)(gan)最(zui)多只能(neng)(neng)拉(la)伸(shen)到0.1而已,當然(ran)做的(de)(de)(de)最(zui)細(xi)的(de)(de)(de)如雙零(ling)二卻(que)非得依(yi)靠進口的(de)(de)(de) 無(wu)(wu)氧(yang)(yang)銅(tong)(tong)桿(gan)(gan)(gan)(gan)(gan)了.目前有企(qi)業嘗試用(yong)剝皮的(de)(de)(de)方式(shi)來處理低氧(yang)(yang)桿(gan)(gan)(gan)(gan)(gan)來伸(shen)0.03線.但(dan)有關這方面的(de)(de)(de)內容(rong)我(wo)還(huan)不是(shi)(shi)(shi)很清楚。
音響線一(yi)般(ban)反而喜歡用無氧(yang)桿,這和無氧(yang)桿是單(dan)晶(jing)(jing)銅(tong),低氧(yang)桿是多晶(jing)(jing)銅(tong)有關。
氧銅(tong)桿和無氧銅(tong)桿由于制造方法(fa)的不(bu)同,致使存(cun)在差別,具有(you)各自的特點。
一(yi)、關于氧的吸入(ru)和脫去(qu)以及它的存在狀態
生(sheng)產(chan)銅(tong)(tong)(tong)(tong)桿(gan)的(de)(de)(de)(de)(de)(de)陰極銅(tong)(tong)(tong)(tong)的(de)(de)(de)(de)(de)(de)含氧(yang)(yang)(yang)量一般(ban)在(zai)10—50ppm,在(zai)常(chang)(chang)溫下氧(yang)(yang)(yang)在(zai)銅(tong)(tong)(tong)(tong)中(zhong)的(de)(de)(de)(de)(de)(de)固溶度(du)約2ppm。低(di)氧(yang)(yang)(yang)銅(tong)(tong)(tong)(tong)桿(gan)的(de)(de)(de)(de)(de)(de)含氧(yang)(yang)(yang)量一般(ban)在(zai)200(175)—400(450)ppm,因此氧(yang)(yang)(yang)的(de)(de)(de)(de)(de)(de)進入是(shi)(shi)在(zai)銅(tong)(tong)(tong)(tong)的(de)(de)(de)(de)(de)(de)液態下吸入的(de)(de)(de)(de)(de)(de),而上引法(fa)無(wu)氧(yang)(yang)(yang)銅(tong)(tong)(tong)(tong)桿(gan)則相(xiang)反,氧(yang)(yang)(yang)在(zai)液態銅(tong)(tong)(tong)(tong)下保持相(xiang)當時間后(hou),被還原而脫去,通(tong)常(chang)(chang)這種(zhong)桿(gan)的(de)(de)(de)(de)(de)(de)含氧(yang)(yang)(yang)量都(dou)在(zai)10—50ppm以(yi)下,最低(di)可達1-2ppm,從(cong)組(zu)織上看,低(di)氧(yang)(yang)(yang)銅(tong)(tong)(tong)(tong)中(zhong)的(de)(de)(de)(de)(de)(de)氧(yang)(yang)(yang),以(yi)氧(yang)(yang)(yang)化銅(tong)(tong)(tong)(tong)狀態,存在(zai)于晶(jing)粒(li)邊界附近,這對低(di)氧(yang)(yang)(yang)銅(tong)(tong)(tong)(tong)桿(gan)而言可以(yi)說是(shi)(shi)常(chang)(chang)見的(de)(de)(de)(de)(de)(de)但對無(wu)氧(yang)(yang)(yang)銅(tong)(tong)(tong)(tong)桿(gan)則很少見。氧(yang)(yang)(yang)化銅(tong)(tong)(tong)(tong)以(yi)夾雜形(xing)式在(zai)晶(jing)界出現對材料(liao)的(de)(de)(de)(de)(de)(de)韌性(xing)產(chan)生(sheng)負面影響。而無(wu)氧(yang)(yang)(yang)銅(tong)(tong)(tong)(tong)中(zhong)的(de)(de)(de)(de)(de)(de)氧(yang)(yang)(yang)很低(di),所以(yi)這種(zhong)銅(tong)(tong)(tong)(tong)的(de)(de)(de)(de)(de)(de)組(zu)織是(shi)(shi)均(jun)勻(yun)的(de)(de)(de)(de)(de)(de)單相(xiang)組(zu)織對韌性(xing)有利。在(zai)無(wu)氧(yang)(yang)(yang)銅(tong)(tong)(tong)(tong)桿(gan)中(zhong)的(de)(de)(de)(de)(de)(de)多孔性(xing)是(shi)(shi)不常(chang)(chang)見的(de)(de)(de)(de)(de)(de),而在(zai)低(di)氧(yang)(yang)(yang)銅(tong)(tong)(tong)(tong)桿(gan)中(zhong)則是(shi)(shi)常(chang)(chang)見的(de)(de)(de)(de)(de)(de)一種(zhong)缺陷。
二、熱軋組織和(he)鑄造(zao)組織的區別
低氧(yang)(yang)(yang)銅(tong)(tong)(tong)桿(gan)由于經(jing)過熱軋,所以其組(zu)織屬熱加工(gong)組(zu)織,原來的(de)(de)(de)鑄造(zao)組(zu)織已經(jing)破(po)碎(sui),在(zai)8mm的(de)(de)(de)桿(gan)時(shi)已有再結晶(jing)的(de)(de)(de)形式出(chu)現,而無氧(yang)(yang)(yang)銅(tong)(tong)(tong)桿(gan)屬鑄造(zao)組(zu)織,晶(jing)粒(li)(li)粗(cu)大,這是為什么(me),無氧(yang)(yang)(yang)銅(tong)(tong)(tong)的(de)(de)(de)再結晶(jing)溫(wen)度較高(gao),需(xu)要較高(gao)退火(huo)溫(wen)度的(de)(de)(de)固有原因(yin)(yin)。這是因(yin)(yin)為,再結晶(jing)發生在(zai)晶(jing)粒(li)(li)邊(bian)界附近,無氧(yang)(yang)(yang)銅(tong)(tong)(tong)桿(gan)組(zu)織晶(jing)粒(li)(li)粗(cu)大,晶(jing)粒(li)(li)尺(chi)寸甚至能(neng)達(da)幾個毫米,因(yin)(yin)而晶(jing)粒(li)(li)邊(bian)界少(shao),即(ji)使通(tong)過拉制(zhi)(zhi)變形,但(dan)晶(jing)粒(li)(li)邊(bian)界相對(dui)(dui)低氧(yang)(yang)(yang)銅(tong)(tong)(tong)桿(gan)還是較少(shao),所以需(xu)要較高(gao)的(de)(de)(de)退火(huo)功(gong)率。對(dui)(dui)無氧(yang)(yang)(yang)銅(tong)(tong)(tong)成(cheng)功(gong)的(de)(de)(de)退火(huo)要求是:由桿(gan)經(jing)拉制(zhi)(zhi),但(dan)尚未(wei)鑄造(zao)組(zu)織的(de)(de)(de)線時(shi)的(de)(de)(de)第一(yi)次退火(huo),其退火(huo)功(gong)率應(ying)比同(tong)(tong)樣情況(kuang)的(de)(de)(de)低氧(yang)(yang)(yang)銅(tong)(tong)(tong)高(gao)10——15%。經(jing)繼(ji)續拉制(zhi)(zhi),在(zai)以后階段的(de)(de)(de)退火(huo)功(gong)率應(ying)留有足夠的(de)(de)(de)余量(liang)和(he)(he)對(dui)(dui)低氧(yang)(yang)(yang)銅(tong)(tong)(tong)和(he)(he)無氧(yang)(yang)(yang)銅(tong)(tong)(tong)切實區別執行不(bu)同(tong)(tong)的(de)(de)(de)退火(huo)工(gong)藝,以保證在(zai)制(zhi)(zhi)品(pin)和(he)(he)成(cheng)品(pin)導線的(de)(de)(de)柔軟性。
三、夾雜,氧含量波動(dong),表面氧化(hua)物(wu)和(he)可能存在的熱軋缺陷的差(cha)別(bie)
無(wu)氧銅(tong)桿(gan)(gan)的(de)可(ke)拉(la)(la)性(xing)在所有(you)線(xian)(xian)徑里與低(di)氧銅(tong)桿(gan)(gan)相(xiang)比(bi)都(dou)是(shi)(shi)優越(yue)的(de),除(chu)上述(shu)組織(zhi)原(yuan)因外,無(wu)氧銅(tong)桿(gan)(gan)夾雜(za)少(shao),含(han)氧量(liang)穩(wen)定(ding)(ding),無(wu)熱軋(ya)可(ke)能(neng)產生的(de)缺(que)陷(xian),桿(gan)(gan)表氧化(hua)(hua)(hua)物(wu)厚度可(ke)達≤15A。在連鑄連軋(ya)生產過程中如(ru)果(guo)工(gong)藝不(bu)穩(wen)定(ding)(ding),對氧監(jian)控(kong)不(bu)嚴,含(han)氧量(liang)不(bu)穩(wen)定(ding)(ding)將直(zhi)接(jie)影響桿(gan)(gan)的(de)性(xing)能(neng)。如(ru)果(guo)桿(gan)(gan)的(de)表面氧化(hua)(hua)(hua)物(wu)能(neng)在后工(gong)序(xu)的(de)連續清洗中得以彌補外,但比(bi)較麻煩的(de)是(shi)(shi)有(you)相(xiang)當多的(de)氧化(hua)(hua)(hua)物(wu)存(cun)在于“皮下”,對拉(la)(la)線(xian)(xian)斷線(xian)(xian)影響更直(zhi)接(jie),故而在拉(la)(la)制微(wei)細線(xian)(xian),超微(wei)細線(xian)(xian)時,為了減(jian)少(shao)斷線(xian)(xian),有(you)時要對銅(tong)桿(gan)(gan)采取不(bu)得已(yi)的(de)辦法——剝皮,甚至二次(ci)剝皮的(de)原(yuan)因所在,目的(de)要除(chu)去皮下氧化(hua)(hua)(hua)物(wu)。
四、低氧銅(tong)桿和無氧銅(tong)桿的(de)韌性有差(cha)別
兩者都可以(yi)拉到0.015mm,但在低溫超導線中(zhong)的(de)低溫級無氧銅,其細絲間的(de)間距只有0.001mm.
五、從制桿的(de)原材料(liao)到制線的(de)經濟性(xing)有差(cha)別。
制造無氧(yang)銅桿(gan)要求質量較高的(de)原材料(liao)。一(yi)般,拉制直(zhi)徑(jing)(jing)>1mm的(de)銅線(xian)時,低氧(yang)銅桿(gan)的(de)優點比較明顯,而無氧(yang)銅桿(gan)顯得(de)更(geng)為優越的(de)是拉制直(zhi)徑(jing)(jing)<0.5mm的(de)銅線(xian)。
六、低(di)氧銅桿的制(zhi)線(xian)工藝(yi)與(yu)無氧銅桿的有所不同。
低氧銅(tong)桿的制(zhi)線工(gong)藝(yi)不(bu)能(neng)照(zhao)搬到無氧銅(tong)桿的制(zhi)線工(gong)藝(yi)上來(lai),至少兩者的退(tui)火(huo)工(gong)藝(yi)是(shi)不(bu)同的。因(yin)為線的柔軟(ruan)性深受材料(liao)成份(fen)和(he)制(zhi)桿,制(zhi)線和(he)退(tui)火(huo)工(gong)藝(yi)的影響,不(bu)能(neng)簡單地說(shuo)低氧銅(tong)或無氧銅(tong)誰(shui)軟(ruan)誰(shui)硬。
上(shang)一條梨樹絕緣層厚度不合格對電線電纜有何影響
下(xia)一(yi)條梨樹如何分辨劣質線纜(電纜人必備)