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蘿北電纜中的銅都是一樣的嗎?什么樣的是好銅?一篇文章解釋清楚

來源:行業動(dong)態(tai) 閱(yue)讀:109507 發(fa)布時間:2019-07-05

導讀:由于生(sheng)(sheng)產(chan)銅(tong)桿(gan)(gan)的(de)兩(liang)者的(de)工藝不(bu)同,所(suo)生(sheng)(sheng)產(chan)的(de)銅(tong)桿(gan)(gan)中的(de)含氧量(liang)及外(wai)(wai)觀就不(bu)同。上引生(sheng)(sheng)產(chan)的(de)銅(tong)桿(gan)(gan),工藝得當氧含量(liang)在(zai)10ppm以下(xia),叫無氧銅(tong)桿(gan)(gan);連(lian)鑄(zhu)連(lian)鑄(zhu)生(sheng)(sheng)產(chan)的(de)銅(tong)桿(gan)(gan) 是在(zai)保(bao)護條件下(xia)的(de)熱軋,氧含量(liang)在(zai)200-500ppm范圍內,但有(you)時(shi)(shi)也(ye)高達700ppm以上,一般情況下(xia),此種方法生(sheng)(sheng)產(chan)的(de)銅(tong)外(wai)(wai)表光亮,低氧銅(tong)桿(gan)(gan),有(you)時(shi)(shi)也(ye)叫光桿(gan)(gan)。

銅桿(gan)是(shi)(shi)電(dian)纜行(xing)(xing)業的(de)主(zhu)要(yao)原料,生(sheng)產(chan)的(de)方(fang)式(shi)主(zhu)要(yao)有兩種——連(lian)(lian)鑄(zhu)(zhu)(zhu)(zhu)連(lian)(lian)軋法(fa)和上引連(lian)(lian)鑄(zhu)(zhu)(zhu)(zhu)法(fa)。連(lian)(lian)鑄(zhu)(zhu)(zhu)(zhu)連(lian)(lian)軋低氧銅桿(gan)的(de)生(sheng)產(chan)方(fang)法(fa)較(jiao)多(duo),其特點是(shi)(shi)金(jin)屬在(zai)豎爐(lu)中(zhong)(zhong)融(rong)化后(hou),銅液通過保(bao)溫爐(lu)、溜(liu)槽、中(zhong)(zhong)間包,從澆管進(jin)入封閉(bi)的(de)模腔內,采用較(jiao)大的(de)冷卻(que)強度進(jin)行(xing)(xing)冷卻(que),形(xing)成(cheng)鑄(zhu)(zhu)(zhu)(zhu)坯,然后(hou)進(jin)行(xing)(xing)多(duo)道次軋制,生(sheng)產(chan)的(de)低氧銅桿(gan)為(wei)熱加工組(zu)織,原來的(de)鑄(zhu)(zhu)(zhu)(zhu)造(zao)組(zu)織已經破碎(sui),含(han)氧量一般為(wei)200~400ppm之間。無(wu)氧銅桿(gan)國內基本全(quan)部采用上引連(lian)(lian)鑄(zhu)(zhu)(zhu)(zhu)法(fa)生(sheng)產(chan),金(jin)屬在(zai)感(gan)應電(dian)爐(lu)中(zhong)(zhong)融(rong)化后(hou)通過石墨模進(jin)行(xing)(xing)上引連(lian)(lian)續(xu)鑄(zhu)(zhu)(zhu)(zhu)造(zao),之后(hou)進(jin)行(xing)(xing)冷軋或冷加工,生(sheng)產(chan)的(de)無(wu)氧銅桿(gan)為(wei)鑄(zhu)(zhu)(zhu)(zhu)造(zao)組(zu)織,含(han)氧量一般在(zai)20ppm以(yi)下(xia)。由(you)于制造(zao)工藝的(de)不同(tong),所以(yi)在(zai)組(zu)織結(jie)構、氧含(han)量分布、雜(za)質(zhi)的(de)形(xing)式(shi)及(ji)分布等諸(zhu)多(duo)方(fang)面有較(jiao)大差(cha)別。

一、拉制性能

銅桿的拉制(zhi)性(xing)能(neng)跟很(hen)多(duo)因素有關(guan),如雜質的含量、氧含量及分布、工藝(yi)控制(zhi)等。下(xia)面分別(bie)從以上幾個方(fang)面對(dui)銅桿的拉制(zhi)性(xing)能(neng)進行分析。

1、熔化方(fang)式對S等雜質的影(ying)響

連(lian)鑄連(lian)軋生(sheng)產銅(tong)(tong)桿(gan)主要是通過氣(qi)體的(de)燃燒(shao)使銅(tong)(tong)桿(gan)熔(rong)(rong)化(hua),在(zai)燃燒(shao)的(de)過程(cheng)中,通過氧化(hua)和揮發作用(yong),可一(yi)定程(cheng)度減(jian)少部分雜質進入銅(tong)(tong)液(ye),因此連(lian)鑄連(lian)軋法對(dui)原料要求相對(dui)低一(yi)些(xie)。上引(yin)連(lian)鑄生(sheng)產無氧銅(tong)(tong)桿(gan),由于是用(yong)感應(ying)電(dian)爐熔(rong)(rong)化(hua),電(dian)解銅(tong)(tong)表面(mian)的(de)“銅(tong)(tong)綠”“銅(tong)(tong)豆”基本(ben)都熔(rong)(rong)入到(dao)銅(tong)(tong)液(ye)中。其(qi)中熔(rong)(rong)入的(de)S對(dui)無氧銅(tong)(tong)桿(gan)塑(su)性影響(xiang)極(ji)大(da),會(hui)增加拉絲斷線率。

2、鑄(zhu)造過程中(zhong)雜質的進入

在(zai)生產(chan)(chan)過(guo)(guo)程中(zhong),連鑄連軋(ya)工(gong)藝(yi)需通(tong)過(guo)(guo)保(bao)溫爐(lu)、溜槽(cao)、中(zhong)間(jian)包轉運銅液,相對(dui)容(rong)易造成耐(nai)(nai)火材料的剝落,在(zai)軋(ya)制過(guo)(guo)程中(zhong)需要通(tong)過(guo)(guo)軋(ya)輥,造成鐵質(zhi)的脫落,會給銅桿造成外部夾雜。而熱軋(ya)中(zhong)皮上和皮下氧化(hua)物的軋(ya)入,會給低氧桿的拉絲造成不利的影(ying)響。上引連鑄法生產(chan)(chan)工(gong)藝(yi)流程較短,銅液是(shi)通(tong)過(guo)(guo)聯(lian)體爐(lu)內潛(qian)流式完成,對(dui)耐(nai)(nai)火材料的沖擊不大,結(jie)晶(jing)是(shi)通(tong)過(guo)(guo)石墨模內進(jin)行(xing),所以過(guo)(guo)程中(zhong)可能(neng)產(chan)(chan)生的污染源(yuan)較少(shao)(shao),雜質(zhi)進(jin)入的機會較少(shao)(shao)。

O、S、P是與銅(tong)(tong)(tong)會生產(chan)化合物的(de)元素。在(zai)熔(rong)態(tai)銅(tong)(tong)(tong)中(zhong),氧(yang)(yang)(yang)(yang)可(ke)以(yi)溶(rong)解一部分(fen),但(dan)當銅(tong)(tong)(tong)冷凝時,氧(yang)(yang)(yang)(yang)幾(ji)乎(hu)不(bu)溶(rong)解于銅(tong)(tong)(tong)中(zhong)。熔(rong)態(tai)時所溶(rong)解的(de)氧(yang)(yang)(yang)(yang),以(yi)銅(tong)(tong)(tong)=氧(yang)(yang)(yang)(yang)化亞(ya)銅(tong)(tong)(tong)共(gong)(gong)晶(jing)(jing)體析出,分(fen)布在(zai)晶(jing)(jing)粒晶(jing)(jing)界處。銅(tong)(tong)(tong)-氧(yang)(yang)(yang)(yang)化亞(ya)銅(tong)(tong)(tong)共(gong)(gong)晶(jing)(jing)體的(de)出現,顯著(zhu)降(jiang)低了銅(tong)(tong)(tong)的(de)塑性。

硫可以(yi)溶解在(zai)(zai)熔體的(de)銅中(zhong),但在(zai)(zai)室溫下,其溶解度幾乎降低到(dao)零(ling),它以(yi)硫化亞銅的(de)形(xing)式出(chu)現在(zai)(zai)晶粒晶界處(chu),會顯著降低銅的(de)塑性(xing)。

3、氧在低氧銅桿(gan)和無氧銅桿(gan)中分(fen)布形式及(ji)其影響(xiang)

氧(yang)含(han)(han)量(liang)對低氧(yang)銅桿的(de)(de)(de)拉線性能有著(zhu)明(ming)顯的(de)(de)(de)影響。當氧(yang)含(han)(han)量(liang)增加到最(zui)(zui)佳值時,銅桿的(de)(de)(de)斷線率(lv)最(zui)(zui)低。這(zhe)是因為氧(yang)在與大部分雜質(zhi)反應的(de)(de)(de)過程中(zhong)都起(qi)到了清除器的(de)(de)(de)作(zuo)用。適度的(de)(de)(de)氧(yang)還有利于去除銅液中(zhong)的(de)(de)(de)氫,生成水蒸氣溢出,減少氣孔的(de)(de)(de)形成。最(zui)(zui)佳的(de)(de)(de)氧(yang)含(han)(han)量(liang)為拉線工藝提供了最(zui)(zui)好的(de)(de)(de)條件。

低氧(yang)銅桿氧(yang)化(hua)(hua)物(wu)的(de)(de)分(fen)布(bu):在連(lian)續澆鑄中凝固的(de)(de)最初階段,散熱速率和均勻冷卻(que)是決定(ding)銅桿氧(yang)化(hua)(hua)物(wu)分(fen)布(bu)的(de)(de)主要(yao)因素。不均勻冷卻(que)會引起銅桿內(nei)部結構本質上的(de)(de)差異,但后續的(de)(de)熱加(jia)工,柱(zhu)狀晶(jing)通(tong)常會遭到破壞,使氧(yang)化(hua)(hua)亞銅顆(ke)粒細微(wei)化(hua)(hua)和均勻分(fen)布(bu)。氧(yang)化(hua)(hua)物(wu)顆(ke)粒聚集而產(chan)生的(de)(de)典型情況是中心爆裂(lie)。除氧(yang)化(hua)(hua)物(wu)顆(ke)粒分(fen)布(bu)的(de)(de)影響外,具(ju)有(you)較(jiao)(jiao)小氧(yang)化(hua)(hua)物(wu)顆(ke)粒的(de)(de)銅桿顯示出較(jiao)(jiao)好的(de)(de)拉線(xian)特性,較(jiao)(jiao)大的(de)(de)Cu2O顆(ke)粒容易造成應力集中點而斷裂(lie)。

無氧(yang)(yang)(yang)銅(tong)含(han)(han)氧(yang)(yang)(yang)量超標,銅(tong)桿變(bian)脆(cui),延伸(shen)率下降,拉伸(shen)式(shi)樣端(duan)口顯(xian)暗(an)紅色,結(jie)晶組織疏(shu)松。當氧(yang)(yang)(yang)含(han)(han)量超出8ppm時,工(gong)藝性(xing)能變(bian)差,表現為鑄(zhu)(zhu)造及拉伸(shen)過(guo)程中(zhong)(zhong)斷桿及斷線率極具(ju)增高。這是由于氧(yang)(yang)(yang)能與(yu)銅(tong)生成氧(yang)(yang)(yang)化亞銅(tong)脆(cui)性(xing)相,形成銅(tong)-氧(yang)(yang)(yang)化亞銅(tong)共晶體,以網狀組織分布(bu)在境界上(shang)(shang)。這種(zhong)脆(cui)性(xing)相硬度高,在冷變(bian)形時將(jiang)會與(yu)銅(tong)機(ji)體脫離(li),導(dao)致銅(tong)桿的機(ji)械性(xing)能下降,在后續加工(gong)中(zhong)(zhong)容易(yi)造成斷裂(lie)現象。氧(yang)(yang)(yang)含(han)(han)量高還(huan)能導(dao)致無氧(yang)(yang)(yang)銅(tong)桿導(dao)電率下降。因(yin)此,必須嚴格控制上(shang)(shang)引連鑄(zhu)(zhu)工(gong)藝及產品質量。

4、氫的影響

在上(shang)引連鑄中(zhong)(zhong),氧含量控制較低,氧化(hua)物的(de)副(fu)作用唄**降低,但氫的(de)影響成為較顯著的(de)問(wen)題。吸氣后熔體中(zhong)(zhong)存在平(ping)衡反(fan)應:H2O(g)=[O]+2[H];

氣(qi)(qi)體及疏松(song)是(shi)在(zai)結晶(jing)(jing)的(de)(de)(de)過(guo)程(cheng)中(zhong)(zhong),氫(qing)從過(guo)飽和(he)的(de)(de)(de)溶液(ye)(ye)中(zhong)(zhong)析出(chu)(chu)并聚(ju)集而(er)形(xing)成的(de)(de)(de)。在(zai)結晶(jing)(jing)前(qian)析出(chu)(chu)的(de)(de)(de)氫(qing)又可還原氧化亞銅而(er)生成水氣(qi)(qi)泡。由于(yu)上引(yin)鑄造的(de)(de)(de)特點是(shi)銅液(ye)(ye)自上而(er)下的(de)(de)(de)結晶(jing)(jing),形(xing)成的(de)(de)(de)液(ye)(ye)**形(xing)狀近似錐型。銅液(ye)(ye)結晶(jing)(jing)前(qian)析出(chu)(chu)的(de)(de)(de)氣(qi)(qi)體在(zai)上浮過(guo)程(cheng)中(zhong)(zhong)被堵在(zai)凝(ning)固組織內,結晶(jing)(jing)時在(zai)鑄桿內形(xing)成氣(qi)(qi)孔。上引(yin)的(de)(de)(de)含(han)氣(qi)(qi)量少時,析出(chu)(chu)的(de)(de)(de)氫(qing)存在(zai)于(yu)晶(jing)(jing)界處,形(xing)成疏松(song);含(han)氣(qi)(qi)量多時,則(ze)聚(ju)集成氣(qi)(qi)孔,因(yin)此,氣(qi)(qi)孔和(he)疏松(song)是(shi)氫(qing)氣(qi)(qi)和(he)水蒸氣(qi)(qi)兩(liang)者(zhe)形(xing)成的(de)(de)(de)。

氫(qing)來(lai)源于(yu)上(shang)引生(sheng)產過程中的各個(ge)工藝環(huan)節,如原(yuan)料(liao)電解銅(tong)(tong)的“銅(tong)(tong)綠”、輔料(liao)木炭(tan)**、氣候環(huan)境**、石墨結晶器未(wei)干燥等(deng)。因此,熔化爐中的銅(tong)(tong)液表面應覆蓋經烘烤的木炭(tan),電解銅(tong)(tong)應盡量(liang)去(qu)除(chu)“銅(tong)(tong)綠”、“銅(tong)(tong)豆”“耳朵(duo)”,對提高無(wu)氧銅(tong)(tong)桿質量(liang)非常(chang)重(zhong)要。

在連鑄(zhu)連軋工藝(yi)中,往往采用適度(du)控制氧含量來控制氫。Cu2O+ H2= 2Cu+ H2O

由于(yu)銅液在鑄(zhu)造(zao)過(guo)程中(zhong)是自下(xia)而上(shang)結晶,銅液中(zhong)的(de)氧和氫(qing)所產生的(de)水蒸(zheng)氣很容易上(shang)浮跑出,銅液中(zhong)的(de)氫(qing)大部(bu)分能(neng)被(bei)有效去除,因而對銅桿的(de)影響較小。

二、表面質量

在生(sheng)產(chan)電(dian)磁線等產(chan)品(pin)的(de)(de)過程中(zhong),對銅桿的(de)(de)表(biao)面(mian)質量(liang)也需(xu)提出要(yao)求。需(xu)要(yao)拉(la)制后(hou)的(de)(de)銅絲表(biao)面(mian)無(wu)毛刺(ci)、銅粉少、無(wu)油污。并通過扭轉(zhuan)試驗測量(liang)表(biao)面(mian)銅粉的(de)(de)質量(liang)和(he)扭轉(zhuan)后(hou)觀察銅桿的(de)(de)復原(yuan)情(qing)況來判定其好(hao)壞。

在(zai)(zai)連(lian)鑄(zhu)連(lian)軋過程中,從(cong)鑄(zhu)造到軋制前(qian),溫度高,完(wan)全暴露于(yu)空氣中,使鑄(zhu)坯(pi)表面(mian)形成較(jiao)厚的氧(yang)(yang)化(hua)(hua)層,在(zai)(zai)軋制過程中,隨著軋輥的轉動,氧(yang)(yang)化(hua)(hua)物(wu)(wu)顆粒(li)軋入(ru)銅(tong)線表面(mian)。由于(yu)氧(yang)(yang)化(hua)(hua)亞銅(tong)是高熔(rong)點脆性化(hua)(hua)合物(wu)(wu),對于(yu)軋入(ru)較(jiao)深的氧(yang)(yang)化(hua)(hua)亞銅(tong),當成條(tiao)狀(zhuang)的聚集物(wu)(wu)遇模具拉伸時,就(jiu)會是銅(tong)桿外(wai)表面(mian)產生(sheng)毛刺,給(gei)后續(xu)的涂漆造成麻煩。

而(er)上(shang)(shang)引連(lian)鑄(zhu)工藝(yi)制造(zao)的(de)無氧(yang)銅桿,由(you)于鑄(zhu)造(zao)和冷(leng)卻完全與氧(yang)隔絕,后續亦無熱軋(ya)過程,銅桿表面無軋(ya)入(ru)表面的(de)氧(yang)化(hua)物,質量較(jiao)(jiao)好,拉制后銅粉(fen)少,上(shang)(shang)述問題較(jiao)(jiao)少存在。

無氧銅桿也分進(jin)口(kou)設(she)備做(zuo)的(de)(de)(de)(de)(de)(de)和國(guo)(guo)產(chan)(chan)設(she)備做(zuo)的(de)(de)(de)(de)(de)(de),但目前(qian)進(jin)口(kou)產(chan)(chan)品已無明(ming)顯(xian)優勢,銅桿產(chan)(chan)品出(chu)來后(hou)區(qu)別不是(shi)很大,只要銅板選的(de)(de)(de)(de)(de)(de)好(hao),生產(chan)(chan)控制比較穩(wen)定,國(guo)(guo)產(chan)(chan)設(she)備也能產(chan)(chan)出(chu)可拉伸0.05的(de)(de)(de)(de)(de)(de)銅桿.進(jin)口(kou)設(she)備一(yi)般是(shi)芬蘭奧托昆普的(de)(de)(de)(de)(de)(de)設(she)備,國(guo)(guo)產(chan)(chan)設(she)備最好(hao)的(de)(de)(de)(de)(de)(de)應(ying)該是(shi)上(shang)海的(de)(de)(de)(de)(de)(de)海軍(jun)廠的(de)(de)(de)(de)(de)(de)了(le),生產(chan)(chan)時間最長,軍(jun)工企(qi)業(ye),質量可靠(kao)。

低氧銅桿進口設備(bei)國(guo)際主要有兩種,一(yi)種是(shi)(shi)美國(guo)南(nan)線設備(bei),英文是(shi)(shi)SOUTHWIRE,國(guo)內廠家是(shi)(shi)南(nan)京華新,江(jiang)西銅業,另一(yi)種是(shi)(shi)德國(guo)CONTIROD設備(bei),國(guo)內廠家是(shi)(shi)常州金(jin)源,天津大無縫。

無氧(yang)(yang)(yang)(yang)及(ji)低氧(yang)(yang)(yang)(yang)桿(gan)(gan)(gan)(gan)從含(han)氧(yang)(yang)(yang)(yang)量(liang)(liang)上(shang)容(rong)易(yi)區別,無氧(yang)(yang)(yang)(yang)銅(tong)(tong)是含(han)氧(yang)(yang)(yang)(yang)量(liang)(liang)在10-20個(ge)PPM以(yi)下(xia)(xia),但目前有(you)的廠家只能(neng)做到(dao)(dao)50個(ge)PPM以(yi)下(xia)(xia).低氧(yang)(yang)(yang)(yang)銅(tong)(tong)桿(gan)(gan)(gan)(gan)在 200-400個(ge)PPM,好(hao)的桿(gan)(gan)(gan)(gan)子一般(ban)含(han)氧(yang)(yang)(yang)(yang)量(liang)(liang)控制在250個(ge)PPM左(zuo)右,無氧(yang)(yang)(yang)(yang)桿(gan)(gan)(gan)(gan)一般(ban)采取(qu)的是上(shang)引法,低氧(yang)(yang)(yang)(yang)桿(gan)(gan)(gan)(gan)是連鑄連軋(ya),兩種(zhong)產品(pin)相(xiang)對而言低氧(yang)(yang)(yang)(yang)桿(gan)(gan)(gan)(gan)對漆包(bao)線性(xing) 能(neng)更(geng)適應些,如(ru)(ru)柔軟性(xing),回彈角,繞線性(xing)能(neng).但低氧(yang)(yang)(yang)(yang)桿(gan)(gan)(gan)(gan)對拉(la)絲條(tiao)件(jian)相(xiang)對要苛刻些,同(tong)(tong)樣拉(la)伸0.2的細(xi)絲,如(ru)(ru)果伸線條(tiao)件(jian)不(bu)好(hao),普通的無氧(yang)(yang)(yang)(yang)桿(gan)(gan)(gan)(gan)可拉(la)而好(hao)的低氧(yang)(yang)(yang)(yang)桿(gan)(gan)(gan)(gan)就(jiu)(jiu)斷 線,但如(ru)(ru)果放在好(hao)的伸線條(tiao)件(jian),同(tong)(tong)樣的桿(gan)(gan)(gan)(gan)子,低氧(yang)(yang)(yang)(yang)桿(gan)(gan)(gan)(gan)說不(bu)定就(jiu)(jiu)能(neng)拉(la)到(dao)(dao)雙零(ling)五,而普通無氧(yang)(yang)(yang)(yang)桿(gan)(gan)(gan)(gan)最(zui)多只能(neng)拉(la)伸到(dao)(dao)0.1而已,當(dang)然(ran)做的最(zui)細(xi)的如(ru)(ru)雙零(ling)二卻非得依靠(kao)進(jin)口的 無氧(yang)(yang)(yang)(yang)銅(tong)(tong)桿(gan)(gan)(gan)(gan)了.目前有(you)企業嘗試(shi)用剝皮的方(fang)式來處理低氧(yang)(yang)(yang)(yang)桿(gan)(gan)(gan)(gan)來伸0.03線.但有(you)關(guan)這方(fang)面的內容(rong)我還(huan)不(bu)是很清楚。

音響線一(yi)般反而(er)喜歡用無氧(yang)桿,這(zhe)和無氧(yang)桿是(shi)單(dan)晶(jing)銅,低氧(yang)桿是(shi)多晶(jing)銅有(you)關。

氧銅桿和(he)無氧銅桿由于制造(zao)方法(fa)的不同(tong),致使存在差別,具有各(ge)自(zi)的特(te)點(dian)。

一、關(guan)于氧(yang)的(de)吸入和脫(tuo)去以(yi)及它的(de)存在(zai)狀(zhuang)態

生(sheng)產銅(tong)(tong)(tong)桿(gan)的(de)(de)(de)(de)(de)陰(yin)極銅(tong)(tong)(tong)的(de)(de)(de)(de)(de)含(han)氧(yang)(yang)(yang)量一般(ban)在(zai)(zai)(zai)(zai)10—50ppm,在(zai)(zai)(zai)(zai)常(chang)溫下(xia)(xia)氧(yang)(yang)(yang)在(zai)(zai)(zai)(zai)銅(tong)(tong)(tong)中的(de)(de)(de)(de)(de)固溶度約2ppm。低(di)(di)氧(yang)(yang)(yang)銅(tong)(tong)(tong)桿(gan)的(de)(de)(de)(de)(de)含(han)氧(yang)(yang)(yang)量一般(ban)在(zai)(zai)(zai)(zai)200(175)—400(450)ppm,因此氧(yang)(yang)(yang)的(de)(de)(de)(de)(de)進入是(shi)在(zai)(zai)(zai)(zai)銅(tong)(tong)(tong)的(de)(de)(de)(de)(de)液態下(xia)(xia)吸入的(de)(de)(de)(de)(de),而(er)上引法無氧(yang)(yang)(yang)銅(tong)(tong)(tong)桿(gan)則(ze)(ze)相反,氧(yang)(yang)(yang)在(zai)(zai)(zai)(zai)液態銅(tong)(tong)(tong)下(xia)(xia)保持相當時間后,被還原而(er)脫去,通(tong)常(chang)這(zhe)種桿(gan)的(de)(de)(de)(de)(de)含(han)氧(yang)(yang)(yang)量都在(zai)(zai)(zai)(zai)10—50ppm以(yi)下(xia)(xia),最低(di)(di)可達1-2ppm,從組(zu)(zu)織上看,低(di)(di)氧(yang)(yang)(yang)銅(tong)(tong)(tong)中的(de)(de)(de)(de)(de)氧(yang)(yang)(yang),以(yi)氧(yang)(yang)(yang)化(hua)銅(tong)(tong)(tong)狀態,存在(zai)(zai)(zai)(zai)于晶粒邊(bian)界(jie)附近(jin),這(zhe)對(dui)(dui)低(di)(di)氧(yang)(yang)(yang)銅(tong)(tong)(tong)桿(gan)而(er)言可以(yi)說是(shi)常(chang)見(jian)的(de)(de)(de)(de)(de)但(dan)對(dui)(dui)無氧(yang)(yang)(yang)銅(tong)(tong)(tong)桿(gan)則(ze)(ze)很少見(jian)。氧(yang)(yang)(yang)化(hua)銅(tong)(tong)(tong)以(yi)夾雜形式在(zai)(zai)(zai)(zai)晶界(jie)出現對(dui)(dui)材料的(de)(de)(de)(de)(de)韌(ren)(ren)性(xing)產生(sheng)負面影(ying)響。而(er)無氧(yang)(yang)(yang)銅(tong)(tong)(tong)中的(de)(de)(de)(de)(de)氧(yang)(yang)(yang)很低(di)(di),所以(yi)這(zhe)種銅(tong)(tong)(tong)的(de)(de)(de)(de)(de)組(zu)(zu)織是(shi)均勻的(de)(de)(de)(de)(de)單(dan)相組(zu)(zu)織對(dui)(dui)韌(ren)(ren)性(xing)有利(li)。在(zai)(zai)(zai)(zai)無氧(yang)(yang)(yang)銅(tong)(tong)(tong)桿(gan)中的(de)(de)(de)(de)(de)多孔(kong)性(xing)是(shi)不常(chang)見(jian)的(de)(de)(de)(de)(de),而(er)在(zai)(zai)(zai)(zai)低(di)(di)氧(yang)(yang)(yang)銅(tong)(tong)(tong)桿(gan)中則(ze)(ze)是(shi)常(chang)見(jian)的(de)(de)(de)(de)(de)一種缺陷。

二、熱軋組織和鑄造組織的區別(bie)

低(di)(di)氧(yang)銅(tong)(tong)桿由于經(jing)過熱軋,所以其組(zu)(zu)織(zhi)屬(shu)熱加工(gong)組(zu)(zu)織(zhi),原來的(de)(de)鑄(zhu)造組(zu)(zu)織(zhi)已經(jing)破碎,在(zai)(zai)(zai)8mm的(de)(de)桿時已有(you)再結(jie)晶(jing)的(de)(de)形式出現(xian),而(er)無氧(yang)銅(tong)(tong)桿屬(shu)鑄(zhu)造組(zu)(zu)織(zhi),晶(jing)粒(li)粗大,這(zhe)是為什么,無氧(yang)銅(tong)(tong)的(de)(de)再結(jie)晶(jing)溫度較(jiao)(jiao)高(gao)(gao)(gao),需(xu)要較(jiao)(jiao)高(gao)(gao)(gao)退(tui)火(huo)溫度的(de)(de)固有(you)原因。這(zhe)是因為,再結(jie)晶(jing)發生在(zai)(zai)(zai)晶(jing)粒(li)邊(bian)(bian)界附近,無氧(yang)銅(tong)(tong)桿組(zu)(zu)織(zhi)晶(jing)粒(li)粗大,晶(jing)粒(li)尺寸(cun)甚至能達幾個毫米(mi),因而(er)晶(jing)粒(li)邊(bian)(bian)界少,即使通過拉(la)制(zhi)變(bian)形,但晶(jing)粒(li)邊(bian)(bian)界相(xiang)對(dui)低(di)(di)氧(yang)銅(tong)(tong)桿還是較(jiao)(jiao)少,所以需(xu)要較(jiao)(jiao)高(gao)(gao)(gao)的(de)(de)退(tui)火(huo)功(gong)率(lv)(lv)(lv)。對(dui)無氧(yang)銅(tong)(tong)成(cheng)功(gong)的(de)(de)退(tui)火(huo)要求是:由桿經(jing)拉(la)制(zhi),但尚未鑄(zhu)造組(zu)(zu)織(zhi)的(de)(de)線(xian)時的(de)(de)第(di)一次退(tui)火(huo),其退(tui)火(huo)功(gong)率(lv)(lv)(lv)應比同樣情況(kuang)的(de)(de)低(di)(di)氧(yang)銅(tong)(tong)高(gao)(gao)(gao)10——15%。經(jing)繼續拉(la)制(zhi),在(zai)(zai)(zai)以后(hou)階段的(de)(de)退(tui)火(huo)功(gong)率(lv)(lv)(lv)應留有(you)足夠的(de)(de)余量和對(dui)低(di)(di)氧(yang)銅(tong)(tong)和無氧(yang)銅(tong)(tong)切實(shi)區別執(zhi)行不同的(de)(de)退(tui)火(huo)工(gong)藝,以保證在(zai)(zai)(zai)制(zhi)品和成(cheng)品導線(xian)的(de)(de)柔軟性。

三(san)、夾(jia)雜,氧含量波動,表面(mian)氧化物和可(ke)能存在的熱軋缺陷的差別

無氧(yang)銅(tong)桿的(de)可拉性在(zai)所(suo)有(you)線(xian)徑(jing)里與低氧(yang)銅(tong)桿相(xiang)比都是優越的(de),除上述組織(zhi)原因外(wai),無氧(yang)銅(tong)桿夾雜少,含氧(yang)量穩定,無熱軋可能產生的(de)缺陷,桿表(biao)氧(yang)化物厚(hou)度可達≤15A。在(zai)連(lian)鑄連(lian)軋生產過程中(zhong)如果工(gong)藝不(bu)穩定,對(dui)氧(yang)監控(kong)不(bu)嚴,含氧(yang)量不(bu)穩定將直接(jie)(jie)影響(xiang)桿的(de)性能。如果桿的(de)表(biao)面氧(yang)化物能在(zai)后工(gong)序的(de)連(lian)續清(qing)洗中(zhong)得(de)以彌補(bu)外(wai),但比較麻煩的(de)是有(you)相(xiang)當(dang)多的(de)氧(yang)化物存在(zai)于(yu)“皮(pi)下”,對(dui)拉線(xian)斷線(xian)影響(xiang)更直接(jie)(jie),故而(er)在(zai)拉制微(wei)細線(xian),超微(wei)細線(xian)時,為了減少斷線(xian),有(you)時要對(dui)銅(tong)桿采取不(bu)得(de)已的(de)辦法——剝皮(pi),甚至(zhi)二次(ci)剝皮(pi)的(de)原因所(suo)在(zai),目的(de)要除去皮(pi)下氧(yang)化物。

四、低氧(yang)銅(tong)桿(gan)和無氧(yang)銅(tong)桿(gan)的韌性有差別

兩(liang)者(zhe)都可以拉到0.015mm,但在低(di)溫超導(dao)線中(zhong)的低(di)溫級無(wu)氧銅(tong),其細絲間(jian)(jian)的間(jian)(jian)距只有(you)0.001mm.

五、從制(zhi)桿的(de)原材料(liao)到制(zhi)線的(de)經(jing)濟性有差別。

制造無氧銅(tong)(tong)桿要求(qiu)質量(liang)較高的(de)(de)原材(cai)料(liao)。一般,拉制直徑>1mm的(de)(de)銅(tong)(tong)線時,低(di)氧銅(tong)(tong)桿的(de)(de)優點比(bi)較明顯,而(er)無氧銅(tong)(tong)桿顯得更為優越的(de)(de)是拉制直徑<0.5mm的(de)(de)銅(tong)(tong)線。

六(liu)、低氧銅桿(gan)的制線工(gong)藝與無氧銅桿(gan)的有所不同。

低氧銅桿(gan)(gan)的制線(xian)工藝(yi)不(bu)能照搬到無氧銅桿(gan)(gan)的制線(xian)工藝(yi)上來,至少兩者的退(tui)火(huo)工藝(yi)是(shi)不(bu)同的。因(yin)為(wei)線(xian)的柔軟性(xing)深受材料成份和制桿(gan)(gan),制線(xian)和退(tui)火(huo)工藝(yi)的影響(xiang),不(bu)能簡單(dan)地(di)說低氧銅或無氧銅誰軟誰硬。