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來源:行業動態 閱讀(du):109597 發(fa)布(bu)時間:2019-07-05
導讀:由于(yu)生(sheng)(sheng)(sheng)產銅桿(gan)(gan)的(de)(de)(de)(de)兩者的(de)(de)(de)(de)工(gong)藝不同,所生(sheng)(sheng)(sheng)產的(de)(de)(de)(de)銅桿(gan)(gan)中的(de)(de)(de)(de)含氧(yang)量(liang)及外觀就(jiu)不同。上引生(sheng)(sheng)(sheng)產的(de)(de)(de)(de)銅桿(gan)(gan),工(gong)藝得當氧(yang)含量(liang)在(zai)10ppm以(yi)下(xia),叫(jiao)無氧(yang)銅桿(gan)(gan);連鑄連鑄生(sheng)(sheng)(sheng)產的(de)(de)(de)(de)銅桿(gan)(gan) 是在(zai)保護條件下(xia)的(de)(de)(de)(de)熱軋,氧(yang)含量(liang)在(zai)200-500ppm范圍內,但有(you)時也高達700ppm以(yi)上,一般情況下(xia),此種方法生(sheng)(sheng)(sheng)產的(de)(de)(de)(de)銅外表光(guang)亮(liang),低氧(yang)銅桿(gan)(gan),有(you)時也叫(jiao)光(guang)桿(gan)(gan)。
銅(tong)(tong)桿(gan)(gan)是電(dian)纜行(xing)(xing)業(ye)的(de)主要原料,生產的(de)方(fang)(fang)式主要有兩種——連(lian)(lian)(lian)(lian)鑄(zhu)(zhu)(zhu)(zhu)連(lian)(lian)(lian)(lian)軋法(fa)和上引(yin)連(lian)(lian)(lian)(lian)鑄(zhu)(zhu)(zhu)(zhu)法(fa)。連(lian)(lian)(lian)(lian)鑄(zhu)(zhu)(zhu)(zhu)連(lian)(lian)(lian)(lian)軋低(di)氧(yang)銅(tong)(tong)桿(gan)(gan)的(de)生產方(fang)(fang)法(fa)較多(duo),其(qi)特(te)點是金(jin)屬在豎爐中(zhong)融化(hua)后,銅(tong)(tong)液(ye)通(tong)過保溫爐、溜槽(cao)、中(zhong)間(jian)包,從(cong)澆管進(jin)入封(feng)閉的(de)模(mo)腔內,采用(yong)較大的(de)冷卻強度進(jin)行(xing)(xing)冷卻,形成鑄(zhu)(zhu)(zhu)(zhu)坯(pi),然(ran)后進(jin)行(xing)(xing)多(duo)道次軋制(zhi),生產的(de)低(di)氧(yang)銅(tong)(tong)桿(gan)(gan)為(wei)熱加(jia)工(gong)組(zu)(zu)織,原來(lai)的(de)鑄(zhu)(zhu)(zhu)(zhu)造(zao)組(zu)(zu)織已經破碎,含(han)氧(yang)量一(yi)般為(wei)200~400ppm之(zhi)間(jian)。無氧(yang)銅(tong)(tong)桿(gan)(gan)國內基本全部采用(yong)上引(yin)連(lian)(lian)(lian)(lian)鑄(zhu)(zhu)(zhu)(zhu)法(fa)生產,金(jin)屬在感應電(dian)爐中(zhong)融化(hua)后通(tong)過石墨模(mo)進(jin)行(xing)(xing)上引(yin)連(lian)(lian)(lian)(lian)續鑄(zhu)(zhu)(zhu)(zhu)造(zao),之(zhi)后進(jin)行(xing)(xing)冷軋或冷加(jia)工(gong),生產的(de)無氧(yang)銅(tong)(tong)桿(gan)(gan)為(wei)鑄(zhu)(zhu)(zhu)(zhu)造(zao)組(zu)(zu)織,含(han)氧(yang)量一(yi)般在20ppm以下。由于制(zhi)造(zao)工(gong)藝的(de)不同(tong),所(suo)以在組(zu)(zu)織結構、氧(yang)含(han)量分布、雜(za)質(zhi)的(de)形式及分布等諸多(duo)方(fang)(fang)面有較大差別。
一、拉制性能
銅桿的(de)拉制性能(neng)跟很多因素(su)有關,如雜質的(de)含量、氧含量及(ji)分布、工藝控制等。下面分別從(cong)以上幾個方面對銅桿的(de)拉制性能(neng)進(jin)行分析。
1、熔化方式(shi)對S等雜質(zhi)的影響
連鑄(zhu)連軋生產銅(tong)(tong)(tong)桿主要(yao)是通(tong)過氣體(ti)的(de)燃燒(shao)使銅(tong)(tong)(tong)桿熔(rong)化,在燃燒(shao)的(de)過程(cheng)中(zhong)(zhong),通(tong)過氧(yang)化和揮發作(zuo)用(yong),可一定程(cheng)度減少部分雜質進(jin)入銅(tong)(tong)(tong)液(ye),因(yin)此連鑄(zhu)連軋法對(dui)原(yuan)料要(yao)求相對(dui)低一些(xie)。上引連鑄(zhu)生產無(wu)氧(yang)銅(tong)(tong)(tong)桿,由于是用(yong)感應電(dian)爐熔(rong)化,電(dian)解銅(tong)(tong)(tong)表面的(de)“銅(tong)(tong)(tong)綠(lv)”“銅(tong)(tong)(tong)豆”基本(ben)都熔(rong)入到銅(tong)(tong)(tong)液(ye)中(zhong)(zhong)。其中(zhong)(zhong)熔(rong)入的(de)S對(dui)無(wu)氧(yang)銅(tong)(tong)(tong)桿塑性影響極大,會增加拉絲斷線(xian)率。
2、鑄造(zao)過程中雜質的進入
在生(sheng)(sheng)產過(guo)程中,連(lian)(lian)鑄連(lian)(lian)軋(ya)工(gong)(gong)藝(yi)(yi)需通過(guo)保(bao)溫爐、溜槽、中間包轉(zhuan)運銅(tong)(tong)(tong)液(ye),相對容易造成(cheng)(cheng)耐(nai)火材(cai)料的(de)(de)(de)剝落(luo),在軋(ya)制過(guo)程中需要通過(guo)軋(ya)輥,造成(cheng)(cheng)鐵質的(de)(de)(de)脫落(luo),會(hui)給銅(tong)(tong)(tong)桿(gan)造成(cheng)(cheng)外部(bu)夾雜(za)。而熱(re)軋(ya)中皮上和皮下氧化物的(de)(de)(de)軋(ya)入(ru),會(hui)給低氧桿(gan)的(de)(de)(de)拉絲造成(cheng)(cheng)不利的(de)(de)(de)影響。上引連(lian)(lian)鑄法生(sheng)(sheng)產工(gong)(gong)藝(yi)(yi)流(liu)程較(jiao)短(duan),銅(tong)(tong)(tong)液(ye)是通過(guo)聯體爐內(nei)潛(qian)流(liu)式(shi)完成(cheng)(cheng),對耐(nai)火材(cai)料的(de)(de)(de)沖擊不大,結晶是通過(guo)石墨模內(nei)進行,所以過(guo)程中可能產生(sheng)(sheng)的(de)(de)(de)污染源較(jiao)少,雜(za)質進入(ru)的(de)(de)(de)機會(hui)較(jiao)少。
O、S、P是與(yu)銅(tong)(tong)(tong)(tong)會生產化合物的元(yuan)素。在熔態(tai)銅(tong)(tong)(tong)(tong)中,氧(yang)可以溶解一部分(fen),但(dan)當銅(tong)(tong)(tong)(tong)冷(leng)凝時,氧(yang)幾乎不溶解于(yu)銅(tong)(tong)(tong)(tong)中。熔態(tai)時所溶解的氧(yang),以銅(tong)(tong)(tong)(tong)=氧(yang)化亞銅(tong)(tong)(tong)(tong)共晶(jing)體(ti)析出,分(fen)布在晶(jing)粒(li)晶(jing)界處。銅(tong)(tong)(tong)(tong)-氧(yang)化亞銅(tong)(tong)(tong)(tong)共晶(jing)體(ti)的出現,顯著降(jiang)低了銅(tong)(tong)(tong)(tong)的塑性。
硫(liu)可以溶解在熔(rong)體的(de)(de)銅(tong)中,但在室溫下,其溶解度(du)幾乎降(jiang)低到(dao)零,它(ta)以硫(liu)化亞銅(tong)的(de)(de)形式出現在晶粒晶界處,會顯著降(jiang)低銅(tong)的(de)(de)塑性。
3、氧在低(di)氧銅桿和(he)無氧銅桿中分布形式及其(qi)影響
氧含量對低氧銅桿(gan)的(de)(de)(de)(de)拉線(xian)性能有(you)著明顯(xian)的(de)(de)(de)(de)影(ying)響(xiang)。當氧含量增加到最(zui)佳值時,銅桿(gan)的(de)(de)(de)(de)斷線(xian)率最(zui)低。這是因為氧在與(yu)大部分(fen)雜(za)質反應(ying)的(de)(de)(de)(de)過程中(zhong)都起到了清除(chu)器的(de)(de)(de)(de)作用。適度的(de)(de)(de)(de)氧還有(you)利于去(qu)除(chu)銅液(ye)中(zhong)的(de)(de)(de)(de)氫,生成水蒸氣溢出(chu),減(jian)少氣孔的(de)(de)(de)(de)形成。最(zui)佳的(de)(de)(de)(de)氧含量為拉線(xian)工藝提供了最(zui)好的(de)(de)(de)(de)條(tiao)件(jian)。
低氧(yang)(yang)(yang)銅(tong)桿(gan)(gan)氧(yang)(yang)(yang)化(hua)(hua)(hua)(hua)物的(de)(de)(de)(de)分(fen)布:在連續澆鑄中凝固的(de)(de)(de)(de)最初階段,散熱速率和均(jun)勻冷卻(que)是決(jue)定銅(tong)桿(gan)(gan)氧(yang)(yang)(yang)化(hua)(hua)(hua)(hua)物分(fen)布的(de)(de)(de)(de)主要因素。不均(jun)勻冷卻(que)會引起銅(tong)桿(gan)(gan)內部結構本質上的(de)(de)(de)(de)差異,但(dan)后續的(de)(de)(de)(de)熱加工,柱(zhu)狀(zhuang)晶通(tong)常會遭到破壞,使氧(yang)(yang)(yang)化(hua)(hua)(hua)(hua)亞銅(tong)顆(ke)粒細微(wei)化(hua)(hua)(hua)(hua)和均(jun)勻分(fen)布。氧(yang)(yang)(yang)化(hua)(hua)(hua)(hua)物顆(ke)粒聚(ju)集而產(chan)生的(de)(de)(de)(de)典型情況是中心爆裂。除氧(yang)(yang)(yang)化(hua)(hua)(hua)(hua)物顆(ke)粒分(fen)布的(de)(de)(de)(de)影響外,具有較(jiao)小(xiao)氧(yang)(yang)(yang)化(hua)(hua)(hua)(hua)物顆(ke)粒的(de)(de)(de)(de)銅(tong)桿(gan)(gan)顯示(shi)出較(jiao)好的(de)(de)(de)(de)拉線特性(xing),較(jiao)大的(de)(de)(de)(de)Cu2O顆(ke)粒容易造成應力集中點而斷裂。
無氧(yang)銅(tong)含氧(yang)量(liang)超標,銅(tong)桿變脆,延伸(shen)率(lv)(lv)下降,拉伸(shen)式樣端口顯暗紅色,結晶(jing)(jing)組織疏松。當氧(yang)含量(liang)超出8ppm時,工(gong)藝性能變差,表現(xian)為鑄(zhu)造(zao)及(ji)拉伸(shen)過程中(zhong)斷(duan)桿及(ji)斷(duan)線率(lv)(lv)極具增高。這是由(you)于(yu)氧(yang)能與(yu)銅(tong)生成氧(yang)化(hua)亞(ya)銅(tong)脆性相,形成銅(tong)-氧(yang)化(hua)亞(ya)銅(tong)共晶(jing)(jing)體,以網狀組織分布在境界上(shang)。這種脆性相硬度高,在冷(leng)變形時將(jiang)會與(yu)銅(tong)機體脫離,導(dao)致(zhi)銅(tong)桿的(de)機械(xie)性能下降,在后續(xu)加工(gong)中(zhong)容易造(zao)成斷(duan)裂現(xian)象。氧(yang)含量(liang)高還能導(dao)致(zhi)無氧(yang)銅(tong)桿導(dao)電率(lv)(lv)下降。因(yin)此,必須嚴格(ge)控制上(shang)引連鑄(zhu)工(gong)藝及(ji)產品(pin)質量(liang)。
4、氫的影響
在(zai)上引連(lian)鑄中(zhong),氧含量控制較低,氧化物(wu)的副作用(yong)唄**降低,但氫的影響成為(wei)較顯(xian)著的問題。吸氣后(hou)熔體中(zhong)存在(zai)平衡反(fan)應:H2O(g)=[O]+2[H];
氣體(ti)及(ji)疏(shu)松是(shi)在(zai)(zai)結晶的(de)(de)過程中,氫從過飽(bao)和(he)(he)的(de)(de)溶液中析出并(bing)聚(ju)集而(er)形(xing)(xing)(xing)成的(de)(de)。在(zai)(zai)結晶前析出的(de)(de)氫又(you)可還原氧化亞銅(tong)而(er)生成水(shui)氣泡。由于上(shang)引鑄造(zao)的(de)(de)特點是(shi)銅(tong)液自(zi)上(shang)而(er)下的(de)(de)結晶,形(xing)(xing)(xing)成的(de)(de)液**形(xing)(xing)(xing)狀近似(si)錐(zhui)型。銅(tong)液結晶前析出的(de)(de)氣體(ti)在(zai)(zai)上(shang)浮(fu)過程中被堵在(zai)(zai)凝固(gu)組織內,結晶時(shi)在(zai)(zai)鑄桿內形(xing)(xing)(xing)成氣孔(kong)。上(shang)引的(de)(de)含(han)氣量(liang)少時(shi),析出的(de)(de)氫存在(zai)(zai)于晶界處,形(xing)(xing)(xing)成疏(shu)松;含(han)氣量(liang)多時(shi),則聚(ju)集成氣孔(kong),因此,氣孔(kong)和(he)(he)疏(shu)松是(shi)氫氣和(he)(he)水(shui)蒸氣兩者形(xing)(xing)(xing)成的(de)(de)。
氫來(lai)源于上引生產(chan)過程中的(de)各個工藝環節,如(ru)原料電解(jie)銅(tong)的(de)“銅(tong)綠”、輔料木(mu)炭**、氣候(hou)環境(jing)**、石墨結晶器未干燥(zao)等。因此,熔化(hua)爐中的(de)銅(tong)液表面應覆蓋(gai)經烘烤的(de)木(mu)炭,電解(jie)銅(tong)應盡量去除“銅(tong)綠”、“銅(tong)豆”“耳(er)朵(duo)”,對(dui)提高無氧銅(tong)桿(gan)質量非常重要(yao)。
在連(lian)(lian)鑄連(lian)(lian)軋(ya)工藝(yi)中,往往采用(yong)適度(du)控(kong)制氧含(han)量來控(kong)制氫。Cu2O+ H2= 2Cu+ H2O
由于銅液(ye)在鑄(zhu)造過程(cheng)中(zhong)是自下而上結晶,銅液(ye)中(zhong)的(de)(de)氧(yang)和氫所產生的(de)(de)水蒸氣很容易上浮跑出,銅液(ye)中(zhong)的(de)(de)氫大部分能被有(you)效去除,因而對銅桿(gan)的(de)(de)影響(xiang)較小。
二、表面質量
在生產電磁線等(deng)產品(pin)的(de)(de)(de)過程中,對銅(tong)桿的(de)(de)(de)表(biao)面質(zhi)量也需提出要(yao)求。需要(yao)拉制后(hou)的(de)(de)(de)銅(tong)絲表(biao)面無(wu)毛刺、銅(tong)粉少(shao)、無(wu)油污。并通過扭(niu)轉試驗測量表(biao)面銅(tong)粉的(de)(de)(de)質(zhi)量和(he)扭(niu)轉后(hou)觀察銅(tong)桿的(de)(de)(de)復(fu)原情況來判定其好壞(huai)。
在(zai)連鑄(zhu)連軋(ya)(ya)過程中(zhong),從鑄(zhu)造到軋(ya)(ya)制前(qian),溫度高(gao),完全暴露于空氣中(zhong),使(shi)鑄(zhu)坯(pi)表(biao)面(mian)形成(cheng)較厚的(de)氧化層,在(zai)軋(ya)(ya)制過程中(zhong),隨(sui)著(zhu)軋(ya)(ya)輥的(de)轉動,氧化物(wu)顆粒(li)軋(ya)(ya)入(ru)銅線表(biao)面(mian)。由于氧化亞銅是高(gao)熔點脆性(xing)化合物(wu),對(dui)于軋(ya)(ya)入(ru)較深(shen)的(de)氧化亞銅,當成(cheng)條狀的(de)聚集物(wu)遇模具拉(la)伸(shen)時,就會是銅桿外(wai)表(biao)面(mian)產生毛刺(ci),給(gei)后續的(de)涂漆(qi)造成(cheng)麻煩。
而上引連(lian)鑄工藝制造(zao)的(de)無氧(yang)銅桿,由于鑄造(zao)和(he)冷卻完(wan)全(quan)與氧(yang)隔絕,后續(xu)亦無熱軋(ya)過(guo)程,銅桿表面無軋(ya)入(ru)表面的(de)氧(yang)化物,質量較好(hao),拉(la)制后銅粉少(shao),上述問(wen)題較少(shao)存(cun)在。
無(wu)氧銅(tong)桿(gan)(gan)也(ye)分進口設(she)備做的(de)(de)和國(guo)產(chan)設(she)備做的(de)(de),但目前進口產(chan)品已無(wu)明顯(xian)優勢(shi),銅(tong)桿(gan)(gan)產(chan)品出(chu)來(lai)后區別不是很大,只要銅(tong)板選的(de)(de)好(hao),生產(chan)控制(zhi)比較穩定,國(guo)產(chan)設(she)備也(ye)能產(chan)出(chu)可拉(la)伸(shen)0.05的(de)(de)銅(tong)桿(gan)(gan).進口設(she)備一般(ban)是芬蘭奧托昆普的(de)(de)設(she)備,國(guo)產(chan)設(she)備最好(hao)的(de)(de)應(ying)該是上海(hai)的(de)(de)海(hai)軍(jun)廠的(de)(de)了,生產(chan)時間最長,軍(jun)工企業,質量可靠。
低氧銅桿進(jin)口設備國(guo)際主要(yao)有兩種(zhong),一種(zhong)是(shi)美國(guo)南線設備,英文(wen)是(shi)SOUTHWIRE,國(guo)內廠(chang)家是(shi)南京華新,江西(xi)銅業(ye),另一種(zhong)是(shi)德國(guo)CONTIROD設備,國(guo)內廠(chang)家是(shi)常(chang)州金(jin)源,天津(jin)大(da)無(wu)縫。
無(wu)氧及低(di)氧桿(gan)(gan)從含氧量上(shang)容易區別,無(wu)氧銅是含氧量在(zai)10-20個(ge)(ge)PPM以下,但(dan)目(mu)前有(you)的廠家只能(neng)做到50個(ge)(ge)PPM以下.低(di)氧銅桿(gan)(gan)在(zai) 200-400個(ge)(ge)PPM,好(hao)的桿(gan)(gan)子一般(ban)含氧量控制(zhi)在(zai)250個(ge)(ge)PPM左右,無(wu)氧桿(gan)(gan)一般(ban)采取的是上(shang)引法,低(di)氧桿(gan)(gan)是連鑄(zhu)連軋,兩種(zhong)產品相(xiang)對(dui)而言低(di)氧桿(gan)(gan)對(dui)漆(qi)包線(xian)(xian)(xian)(xian)性(xing) 能(neng)更適應些,如(ru)柔軟性(xing),回彈角,繞線(xian)(xian)(xian)(xian)性(xing)能(neng).但(dan)低(di)氧桿(gan)(gan)對(dui)拉(la)絲條件相(xiang)對(dui)要苛(ke)刻些,同(tong)樣拉(la)伸(shen)(shen)0.2的細絲,如(ru)果(guo)伸(shen)(shen)線(xian)(xian)(xian)(xian)條件不好(hao),普(pu)(pu)通的無(wu)氧桿(gan)(gan)可拉(la)而好(hao)的低(di)氧桿(gan)(gan)就(jiu)斷 線(xian)(xian)(xian)(xian),但(dan)如(ru)果(guo)放在(zai)好(hao)的伸(shen)(shen)線(xian)(xian)(xian)(xian)條件,同(tong)樣的桿(gan)(gan)子,低(di)氧桿(gan)(gan)說不定就(jiu)能(neng)拉(la)到雙(shuang)零五,而普(pu)(pu)通無(wu)氧桿(gan)(gan)最多只能(neng)拉(la)伸(shen)(shen)到0.1而已,當然做的最細的如(ru)雙(shuang)零二卻非得依靠進口的 無(wu)氧銅桿(gan)(gan)了.目(mu)前有(you)企(qi)業嘗試用剝皮的方式來(lai)處(chu)理低(di)氧桿(gan)(gan)來(lai)伸(shen)(shen)0.03線(xian)(xian)(xian)(xian).但(dan)有(you)關這方面的內容我(wo)還不是很清楚。
音(yin)響線一(yi)般(ban)反而(er)喜歡(huan)用(yong)無(wu)氧(yang)桿,這和(he)無(wu)氧(yang)桿是單晶(jing)銅,低氧(yang)桿是多(duo)晶(jing)銅有關。
氧銅(tong)桿和無(wu)氧銅(tong)桿由于制造方(fang)法的不同,致(zhi)使存在差(cha)別,具有各自的特點。
一、關于氧的吸入(ru)和脫去以及它的存在(zai)狀態(tai)
生產銅(tong)(tong)(tong)(tong)桿(gan)(gan)的(de)(de)(de)(de)(de)(de)陰(yin)極銅(tong)(tong)(tong)(tong)的(de)(de)(de)(de)(de)(de)含氧(yang)量一(yi)般在(zai)(zai)10—50ppm,在(zai)(zai)常(chang)(chang)溫下(xia)(xia)(xia)氧(yang)在(zai)(zai)銅(tong)(tong)(tong)(tong)中的(de)(de)(de)(de)(de)(de)固溶度約(yue)2ppm。低氧(yang)銅(tong)(tong)(tong)(tong)桿(gan)(gan)的(de)(de)(de)(de)(de)(de)含氧(yang)量一(yi)般在(zai)(zai)200(175)—400(450)ppm,因此氧(yang)的(de)(de)(de)(de)(de)(de)進入是(shi)(shi)在(zai)(zai)銅(tong)(tong)(tong)(tong)的(de)(de)(de)(de)(de)(de)液(ye)態下(xia)(xia)(xia)吸入的(de)(de)(de)(de)(de)(de),而(er)上(shang)引法無(wu)氧(yang)銅(tong)(tong)(tong)(tong)桿(gan)(gan)則(ze)相(xiang)反,氧(yang)在(zai)(zai)液(ye)態銅(tong)(tong)(tong)(tong)下(xia)(xia)(xia)保持相(xiang)當(dang)時間后,被還原而(er)脫去,通常(chang)(chang)這(zhe)種桿(gan)(gan)的(de)(de)(de)(de)(de)(de)含氧(yang)量都在(zai)(zai)10—50ppm以(yi)下(xia)(xia)(xia),最低可達(da)1-2ppm,從組織上(shang)看(kan),低氧(yang)銅(tong)(tong)(tong)(tong)中的(de)(de)(de)(de)(de)(de)氧(yang),以(yi)氧(yang)化銅(tong)(tong)(tong)(tong)狀態,存在(zai)(zai)于晶(jing)粒邊界(jie)附近,這(zhe)對(dui)低氧(yang)銅(tong)(tong)(tong)(tong)桿(gan)(gan)而(er)言可以(yi)說是(shi)(shi)常(chang)(chang)見的(de)(de)(de)(de)(de)(de)但(dan)對(dui)無(wu)氧(yang)銅(tong)(tong)(tong)(tong)桿(gan)(gan)則(ze)很少見。氧(yang)化銅(tong)(tong)(tong)(tong)以(yi)夾雜形式在(zai)(zai)晶(jing)界(jie)出現對(dui)材(cai)料的(de)(de)(de)(de)(de)(de)韌性產生負面影響。而(er)無(wu)氧(yang)銅(tong)(tong)(tong)(tong)中的(de)(de)(de)(de)(de)(de)氧(yang)很低,所以(yi)這(zhe)種銅(tong)(tong)(tong)(tong)的(de)(de)(de)(de)(de)(de)組織是(shi)(shi)均勻(yun)的(de)(de)(de)(de)(de)(de)單相(xiang)組織對(dui)韌性有(you)利。在(zai)(zai)無(wu)氧(yang)銅(tong)(tong)(tong)(tong)桿(gan)(gan)中的(de)(de)(de)(de)(de)(de)多孔性是(shi)(shi)不常(chang)(chang)見的(de)(de)(de)(de)(de)(de),而(er)在(zai)(zai)低氧(yang)銅(tong)(tong)(tong)(tong)桿(gan)(gan)中則(ze)是(shi)(shi)常(chang)(chang)見的(de)(de)(de)(de)(de)(de)一(yi)種缺陷。
二、熱軋(ya)組(zu)織和鑄造(zao)組(zu)織的區別
低(di)(di)氧銅(tong)(tong)桿(gan)(gan)(gan)由(you)于(yu)經過熱軋,所以(yi)其(qi)組織(zhi)(zhi)(zhi)屬熱加工組織(zhi)(zhi)(zhi),原來(lai)的(de)(de)(de)鑄(zhu)造(zao)(zao)組織(zhi)(zhi)(zhi)已(yi)經破(po)碎,在(zai)8mm的(de)(de)(de)桿(gan)(gan)(gan)時(shi)已(yi)有再結晶(jing)(jing)的(de)(de)(de)形式出現,而無(wu)(wu)氧銅(tong)(tong)桿(gan)(gan)(gan)屬鑄(zhu)造(zao)(zao)組織(zhi)(zhi)(zhi),晶(jing)(jing)粒(li)(li)(li)粗大,這(zhe)是為什么(me),無(wu)(wu)氧銅(tong)(tong)的(de)(de)(de)再結晶(jing)(jing)溫(wen)度(du)較高(gao),需要較高(gao)退(tui)(tui)火(huo)溫(wen)度(du)的(de)(de)(de)固有原因(yin)。這(zhe)是因(yin)為,再結晶(jing)(jing)發生在(zai)晶(jing)(jing)粒(li)(li)(li)邊(bian)界(jie)附(fu)近(jin),無(wu)(wu)氧銅(tong)(tong)桿(gan)(gan)(gan)組織(zhi)(zhi)(zhi)晶(jing)(jing)粒(li)(li)(li)粗大,晶(jing)(jing)粒(li)(li)(li)尺寸(cun)甚至能(neng)達幾(ji)個毫米,因(yin)而晶(jing)(jing)粒(li)(li)(li)邊(bian)界(jie)少,即使通過拉制(zhi)(zhi)變形,但晶(jing)(jing)粒(li)(li)(li)邊(bian)界(jie)相對低(di)(di)氧銅(tong)(tong)桿(gan)(gan)(gan)還是較少,所以(yi)需要較高(gao)的(de)(de)(de)退(tui)(tui)火(huo)功(gong)率(lv)(lv)。對無(wu)(wu)氧銅(tong)(tong)成功(gong)的(de)(de)(de)退(tui)(tui)火(huo)要求是:由(you)桿(gan)(gan)(gan)經拉制(zhi)(zhi),但尚未(wei)鑄(zhu)造(zao)(zao)組織(zhi)(zhi)(zhi)的(de)(de)(de)線(xian)時(shi)的(de)(de)(de)第一次退(tui)(tui)火(huo),其(qi)退(tui)(tui)火(huo)功(gong)率(lv)(lv)應比同樣情況(kuang)的(de)(de)(de)低(di)(di)氧銅(tong)(tong)高(gao)10——15%。經繼續拉制(zhi)(zhi),在(zai)以(yi)后階(jie)段(duan)的(de)(de)(de)退(tui)(tui)火(huo)功(gong)率(lv)(lv)應留(liu)有足夠的(de)(de)(de)余量和(he)對低(di)(di)氧銅(tong)(tong)和(he)無(wu)(wu)氧銅(tong)(tong)切實區別執行不同的(de)(de)(de)退(tui)(tui)火(huo)工藝(yi),以(yi)保(bao)證在(zai)制(zhi)(zhi)品(pin)和(he)成品(pin)導線(xian)的(de)(de)(de)柔軟性。
三、夾雜,氧含量(liang)波動,表面氧化(hua)物和可能存(cun)在的(de)熱軋(ya)缺陷的(de)差別(bie)
無氧(yang)(yang)(yang)銅桿的(de)(de)(de)可(ke)拉(la)(la)性在(zai)所(suo)有線(xian)(xian)徑里(li)與低氧(yang)(yang)(yang)銅桿相比都(dou)是優(you)越(yue)的(de)(de)(de),除上述組織(zhi)原(yuan)因(yin)(yin)外(wai),無氧(yang)(yang)(yang)銅桿夾(jia)雜少,含氧(yang)(yang)(yang)量(liang)穩定,無熱軋可(ke)能(neng)(neng)產生的(de)(de)(de)缺陷,桿表(biao)(biao)氧(yang)(yang)(yang)化物厚度可(ke)達≤15A。在(zai)連(lian)鑄連(lian)軋生產過程中如(ru)果工藝(yi)不(bu)穩定,對(dui)氧(yang)(yang)(yang)監控不(bu)嚴,含氧(yang)(yang)(yang)量(liang)不(bu)穩定將直接影響(xiang)(xiang)桿的(de)(de)(de)性能(neng)(neng)。如(ru)果桿的(de)(de)(de)表(biao)(biao)面氧(yang)(yang)(yang)化物能(neng)(neng)在(zai)后工序的(de)(de)(de)連(lian)續(xu)清洗中得以彌補(bu)外(wai),但(dan)比較(jiao)麻煩的(de)(de)(de)是有相當多的(de)(de)(de)氧(yang)(yang)(yang)化物存在(zai)于(yu)“皮(pi)下(xia)”,對(dui)拉(la)(la)線(xian)(xian)斷線(xian)(xian)影響(xiang)(xiang)更直接,故而在(zai)拉(la)(la)制微(wei)細(xi)線(xian)(xian),超(chao)微(wei)細(xi)線(xian)(xian)時(shi),為(wei)了減少斷線(xian)(xian),有時(shi)要(yao)對(dui)銅桿采取不(bu)得已的(de)(de)(de)辦法——剝皮(pi),甚至二次(ci)剝皮(pi)的(de)(de)(de)原(yuan)因(yin)(yin)所(suo)在(zai),目的(de)(de)(de)要(yao)除去皮(pi)下(xia)氧(yang)(yang)(yang)化物。
四(si)、低氧(yang)銅桿(gan)(gan)和無(wu)氧(yang)銅桿(gan)(gan)的(de)韌(ren)性(xing)有差別
兩者(zhe)都可以拉到0.015mm,但在低溫(wen)超(chao)導(dao)線中的低溫(wen)級無(wu)氧銅(tong),其細(xi)絲間的間距只(zhi)有0.001mm.
五、從(cong)制桿的原材(cai)料(liao)到制線的經(jing)濟性(xing)有差(cha)別(bie)。
制造無氧銅(tong)(tong)(tong)桿(gan)要求質量較高的(de)原材料。一般,拉制直徑>1mm的(de)銅(tong)(tong)(tong)線時,低氧銅(tong)(tong)(tong)桿(gan)的(de)優點比較明(ming)顯(xian),而無氧銅(tong)(tong)(tong)桿(gan)顯(xian)得更為優越的(de)是拉制直徑<0.5mm的(de)銅(tong)(tong)(tong)線。
六、低氧(yang)銅(tong)桿的(de)制線工藝與(yu)無氧(yang)銅(tong)桿的(de)有(you)所不同。
低(di)氧銅桿(gan)的制(zhi)線(xian)(xian)(xian)工(gong)(gong)(gong)藝(yi)不(bu)能照搬到無(wu)(wu)氧銅桿(gan)的制(zhi)線(xian)(xian)(xian)工(gong)(gong)(gong)藝(yi)上來,至少兩者的退(tui)火工(gong)(gong)(gong)藝(yi)是(shi)不(bu)同(tong)的。因為線(xian)(xian)(xian)的柔軟性深(shen)受(shou)材料(liao)成(cheng)份和(he)制(zhi)桿(gan),制(zhi)線(xian)(xian)(xian)和(he)退(tui)火工(gong)(gong)(gong)藝(yi)的影響,不(bu)能簡單地說(shuo)低(di)氧銅或無(wu)(wu)氧銅誰(shui)軟誰(shui)硬(ying)。
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