熱門關(guan)鍵詞:
來(lai)源:行(xing)業動(dong)態 閱讀:109433 發(fa)布時間:2019-07-05
導讀:由(you)于生(sheng)產銅(tong)桿(gan)(gan)的(de)兩者的(de)工藝不同(tong),所生(sheng)產的(de)銅(tong)桿(gan)(gan)中的(de)含氧(yang)(yang)量及外觀(guan)就不同(tong)。上(shang)引生(sheng)產的(de)銅(tong)桿(gan)(gan),工藝得當(dang)氧(yang)(yang)含量在10ppm以下,叫無氧(yang)(yang)銅(tong)桿(gan)(gan);連鑄連鑄生(sheng)產的(de)銅(tong)桿(gan)(gan) 是(shi)在保護條件下的(de)熱軋,氧(yang)(yang)含量在200-500ppm范圍內,但有(you)時(shi)也(ye)高達(da)700ppm以上(shang),一般情況下,此種方法(fa)生(sheng)產的(de)銅(tong)外表光亮,低氧(yang)(yang)銅(tong)桿(gan)(gan),有(you)時(shi)也(ye)叫光桿(gan)(gan)。
銅(tong)(tong)桿(gan)是電纜行(xing)(xing)(xing)(xing)業的(de)(de)主(zhu)要(yao)(yao)原(yuan)料,生(sheng)產的(de)(de)方(fang)式主(zhu)要(yao)(yao)有(you)兩種(zhong)——連(lian)(lian)鑄連(lian)(lian)軋(ya)法和(he)上引(yin)連(lian)(lian)鑄法。連(lian)(lian)鑄連(lian)(lian)軋(ya)低氧(yang)(yang)(yang)銅(tong)(tong)桿(gan)的(de)(de)生(sheng)產方(fang)法較多,其特點是金屬在(zai)豎爐中(zhong)融化(hua)后(hou),銅(tong)(tong)液通過保溫爐、溜槽、中(zhong)間包(bao),從澆(jiao)管進(jin)入封閉的(de)(de)模腔內,采用較大的(de)(de)冷卻強度進(jin)行(xing)(xing)(xing)(xing)冷卻,形成鑄坯,然(ran)后(hou)進(jin)行(xing)(xing)(xing)(xing)多道次軋(ya)制(zhi),生(sheng)產的(de)(de)低氧(yang)(yang)(yang)銅(tong)(tong)桿(gan)為熱加工組織,原(yuan)來的(de)(de)鑄造(zao)(zao)組織已經破碎(sui),含氧(yang)(yang)(yang)量一般為200~400ppm之間。無氧(yang)(yang)(yang)銅(tong)(tong)桿(gan)國內基本全(quan)部采用上引(yin)連(lian)(lian)鑄法生(sheng)產,金屬在(zai)感(gan)應電爐中(zhong)融化(hua)后(hou)通過石(shi)墨模進(jin)行(xing)(xing)(xing)(xing)上引(yin)連(lian)(lian)續(xu)鑄造(zao)(zao),之后(hou)進(jin)行(xing)(xing)(xing)(xing)冷軋(ya)或冷加工,生(sheng)產的(de)(de)無氧(yang)(yang)(yang)銅(tong)(tong)桿(gan)為鑄造(zao)(zao)組織,含氧(yang)(yang)(yang)量一般在(zai)20ppm以下(xia)。由于制(zhi)造(zao)(zao)工藝的(de)(de)不同,所以在(zai)組織結構、氧(yang)(yang)(yang)含量分(fen)布、雜質的(de)(de)形式及分(fen)布等諸多方(fang)面有(you)較大差別。
一、拉制性能
銅(tong)桿的(de)拉制性(xing)能(neng)跟很多因素(su)有關,如雜(za)質(zhi)的(de)含量、氧含量及(ji)分布、工藝(yi)控(kong)制等。下面分別從以上幾個(ge)方面對銅(tong)桿的(de)拉制性(xing)能(neng)進行分析。
1、熔化方(fang)式對S等雜質的影響
連(lian)(lian)(lian)鑄連(lian)(lian)(lian)軋(ya)生產(chan)(chan)銅(tong)桿主要是通過氣體(ti)的燃燒使銅(tong)桿熔(rong)化,在(zai)燃燒的過程中(zhong),通過氧(yang)化和揮(hui)發作用(yong),可一定程度減(jian)少部分雜(za)質進入銅(tong)液,因此連(lian)(lian)(lian)鑄連(lian)(lian)(lian)軋(ya)法對(dui)原料要求相對(dui)低一些。上引連(lian)(lian)(lian)鑄生產(chan)(chan)無氧(yang)銅(tong)桿,由于是用(yong)感應(ying)電爐(lu)熔(rong)化,電解銅(tong)表面(mian)的“銅(tong)綠”“銅(tong)豆”基(ji)本都熔(rong)入到(dao)銅(tong)液中(zhong)。其中(zhong)熔(rong)入的S對(dui)無氧(yang)銅(tong)桿塑性影響極(ji)大,會(hui)增加拉絲斷(duan)線率(lv)。
2、鑄造(zao)過程中雜質的進入
在(zai)生(sheng)產(chan)過(guo)程(cheng)(cheng)中(zhong)(zhong)(zhong),連鑄連軋(ya)工藝需通過(guo)保溫爐、溜槽、中(zhong)(zhong)(zhong)間(jian)包轉運(yun)銅液(ye),相對容易造成(cheng)(cheng)(cheng)耐火材(cai)料的(de)剝(bo)落,在(zai)軋(ya)制(zhi)過(guo)程(cheng)(cheng)中(zhong)(zhong)(zhong)需要通過(guo)軋(ya)輥(gun),造成(cheng)(cheng)(cheng)鐵質(zhi)的(de)脫(tuo)落,會給銅桿造成(cheng)(cheng)(cheng)外部夾(jia)雜。而熱軋(ya)中(zhong)(zhong)(zhong)皮上和皮下(xia)氧(yang)化物的(de)軋(ya)入(ru),會給低氧(yang)桿的(de)拉絲造成(cheng)(cheng)(cheng)不(bu)利的(de)影響。上引連鑄法(fa)生(sheng)產(chan)工藝流程(cheng)(cheng)較短,銅液(ye)是通過(guo)聯體爐內(nei)潛流式完成(cheng)(cheng)(cheng),對耐火材(cai)料的(de)沖擊不(bu)大,結(jie)晶是通過(guo)石墨模內(nei)進(jin)行,所以過(guo)程(cheng)(cheng)中(zhong)(zhong)(zhong)可能產(chan)生(sheng)的(de)污染(ran)源(yuan)較少,雜質(zhi)進(jin)入(ru)的(de)機會較少。
O、S、P是(shi)與銅(tong)(tong)會生產化合物的(de)(de)元素。在熔態銅(tong)(tong)中,氧(yang)可以溶(rong)解一部分(fen)(fen),但當(dang)銅(tong)(tong)冷凝時,氧(yang)幾乎不溶(rong)解于(yu)銅(tong)(tong)中。熔態時所溶(rong)解的(de)(de)氧(yang),以銅(tong)(tong)=氧(yang)化亞銅(tong)(tong)共(gong)晶體析出(chu),分(fen)(fen)布在晶粒(li)晶界(jie)處。銅(tong)(tong)-氧(yang)化亞銅(tong)(tong)共(gong)晶體的(de)(de)出(chu)現,顯(xian)著(zhu)降(jiang)低了銅(tong)(tong)的(de)(de)塑(su)性(xing)。
硫可以(yi)溶解在(zai)熔體的銅中(zhong),但在(zai)室(shi)溫下,其溶解度幾乎降(jiang)低(di)到零(ling),它以(yi)硫化亞銅的形式出現在(zai)晶粒晶界處(chu),會顯著(zhu)降(jiang)低(di)銅的塑(su)性。
3、氧在低氧銅(tong)桿和無氧銅(tong)桿中分布形式及其影響
氧含量對低(di)氧銅(tong)桿的(de)(de)(de)拉(la)線性能有(you)著明顯的(de)(de)(de)影響。當(dang)氧含量增(zeng)加到(dao)最(zui)佳值時,銅(tong)桿的(de)(de)(de)斷線率最(zui)低(di)。這是因為氧在與大部分雜(za)質反應的(de)(de)(de)過程中(zhong)都(dou)起到(dao)了(le)清(qing)除器的(de)(de)(de)作(zuo)用。適度的(de)(de)(de)氧還有(you)利于(yu)去(qu)除銅(tong)液中(zhong)的(de)(de)(de)氫,生成(cheng)水蒸氣(qi)溢出,減少氣(qi)孔的(de)(de)(de)形(xing)成(cheng)。最(zui)佳的(de)(de)(de)氧含量為拉(la)線工藝提供(gong)了(le)最(zui)好的(de)(de)(de)條件(jian)。
低氧(yang)銅桿氧(yang)化物的(de)(de)分(fen)布:在連續澆鑄中凝固的(de)(de)最初階段,散熱速率和均勻(yun)冷卻是(shi)(shi)決定(ding)銅桿氧(yang)化物分(fen)布的(de)(de)主要因(yin)素(su)。不均勻(yun)冷卻會引(yin)起銅桿內部結構本質上的(de)(de)差(cha)異,但(dan)后續的(de)(de)熱加工,柱狀晶通常會遭到破壞,使(shi)氧(yang)化亞銅顆粒(li)(li)細微(wei)化和均勻(yun)分(fen)布。氧(yang)化物顆粒(li)(li)聚集而(er)產生的(de)(de)典型情況是(shi)(shi)中心爆裂。除(chu)氧(yang)化物顆粒(li)(li)分(fen)布的(de)(de)影響(xiang)外,具有(you)較小氧(yang)化物顆粒(li)(li)的(de)(de)銅桿顯(xian)示出較好的(de)(de)拉(la)線特性,較大的(de)(de)Cu2O顆粒(li)(li)容易造成應力集中點而(er)斷裂。
無氧(yang)(yang)銅(tong)含(han)氧(yang)(yang)量(liang)超標,銅(tong)桿(gan)變脆,延伸(shen)率(lv)下(xia)(xia)降,拉伸(shen)式樣(yang)端口顯(xian)暗紅色(se),結晶組織疏松。當(dang)氧(yang)(yang)含(han)量(liang)超出8ppm時,工(gong)藝性能變差,表現(xian)為鑄造及(ji)拉伸(shen)過程中(zhong)斷桿(gan)及(ji)斷線率(lv)極具增高(gao)。這是由于氧(yang)(yang)能與銅(tong)生成(cheng)氧(yang)(yang)化(hua)亞(ya)銅(tong)脆性相,形成(cheng)銅(tong)-氧(yang)(yang)化(hua)亞(ya)銅(tong)共(gong)晶體(ti)(ti),以網狀組織分布在(zai)境(jing)界上。這種脆性相硬度高(gao),在(zai)冷變形時將會與銅(tong)機體(ti)(ti)脫離(li),導(dao)致銅(tong)桿(gan)的機械性能下(xia)(xia)降,在(zai)后續加工(gong)中(zhong)容易造成(cheng)斷裂現(xian)象。氧(yang)(yang)含(han)量(liang)高(gao)還能導(dao)致無氧(yang)(yang)銅(tong)桿(gan)導(dao)電率(lv)下(xia)(xia)降。因此,必須(xu)嚴格(ge)控制上引連鑄工(gong)藝及(ji)產品質(zhi)量(liang)。
4、氫的影響
在上引連鑄中(zhong),氧含量控制較低,氧化(hua)物的副作用唄**降低,但氫(qing)的影響成為較顯著的問題。吸氣后熔體中(zhong)存在平衡反(fan)應:H2O(g)=[O]+2[H];
氣(qi)(qi)體及(ji)疏(shu)松是(shi)在(zai)結(jie)晶(jing)(jing)的(de)(de)過程(cheng)中(zhong),氫(qing)從(cong)過飽和的(de)(de)溶液中(zhong)析(xi)出(chu)并聚集而(er)形(xing)(xing)成(cheng)的(de)(de)。在(zai)結(jie)晶(jing)(jing)前(qian)析(xi)出(chu)的(de)(de)氫(qing)又(you)可還原氧化亞銅(tong)而(er)生成(cheng)水氣(qi)(qi)泡(pao)。由(you)于上引鑄(zhu)造的(de)(de)特點是(shi)銅(tong)液自(zi)上而(er)下的(de)(de)結(jie)晶(jing)(jing),形(xing)(xing)成(cheng)的(de)(de)液**形(xing)(xing)狀近似錐型。銅(tong)液結(jie)晶(jing)(jing)前(qian)析(xi)出(chu)的(de)(de)氣(qi)(qi)體在(zai)上浮過程(cheng)中(zhong)被堵(du)在(zai)凝固組織內,結(jie)晶(jing)(jing)時(shi)(shi)在(zai)鑄(zhu)桿內形(xing)(xing)成(cheng)氣(qi)(qi)孔(kong)(kong)。上引的(de)(de)含氣(qi)(qi)量少時(shi)(shi),析(xi)出(chu)的(de)(de)氫(qing)存(cun)在(zai)于晶(jing)(jing)界處(chu),形(xing)(xing)成(cheng)疏(shu)松;含氣(qi)(qi)量多時(shi)(shi),則聚集成(cheng)氣(qi)(qi)孔(kong)(kong),因此,氣(qi)(qi)孔(kong)(kong)和疏(shu)松是(shi)氫(qing)氣(qi)(qi)和水蒸氣(qi)(qi)兩(liang)者形(xing)(xing)成(cheng)的(de)(de)。
氫來源于上引生(sheng)產過(guo)程(cheng)中的(de)各(ge)個(ge)工藝環(huan)節,如原料(liao)電(dian)解銅(tong)的(de)“銅(tong)綠”、輔料(liao)木炭**、氣候環(huan)境**、石墨結晶器未干燥等。因此,熔化爐中的(de)銅(tong)液表面(mian)應(ying)覆蓋經(jing)烘烤的(de)木炭,電(dian)解銅(tong)應(ying)盡(jin)量去除“銅(tong)綠”、“銅(tong)豆”“耳(er)朵”,對提高無氧銅(tong)桿質量非常重(zhong)要。
在連(lian)鑄(zhu)連(lian)軋工(gong)藝中(zhong),往往采用適度控制氧含量(liang)來控制氫。Cu2O+ H2= 2Cu+ H2O
由于銅液在鑄(zhu)造(zao)過(guo)程中是自下而上結晶,銅液中的(de)氧和氫(qing)所(suo)產(chan)生的(de)水蒸氣很容易上浮跑出,銅液中的(de)氫(qing)大部(bu)分能被(bei)有效去除,因而對銅桿(gan)的(de)影響較小(xiao)。
二、表面質量
在生產(chan)電磁線等產(chan)品的過(guo)程中,對(dui)銅(tong)(tong)桿(gan)的表面質量也需(xu)提出要(yao)求。需(xu)要(yao)拉(la)制(zhi)后的銅(tong)(tong)絲(si)表面無(wu)毛刺、銅(tong)(tong)粉(fen)少(shao)、無(wu)油(you)污。并通(tong)過(guo)扭(niu)轉試驗測量表面銅(tong)(tong)粉(fen)的質量和扭(niu)轉后觀察銅(tong)(tong)桿(gan)的復原情況來判(pan)定其好壞。
在(zai)連鑄(zhu)連軋(ya)過(guo)程中(zhong),從鑄(zhu)造(zao)到軋(ya)制(zhi)前(qian),溫(wen)度高(gao)(gao),完全暴露于(yu)空(kong)氣(qi)中(zhong),使鑄(zhu)坯(pi)表面形(xing)成較厚(hou)的氧(yang)化(hua)(hua)(hua)層,在(zai)軋(ya)制(zhi)過(guo)程中(zhong),隨著軋(ya)輥的轉動,氧(yang)化(hua)(hua)(hua)物顆粒(li)軋(ya)入銅(tong)線表面。由于(yu)氧(yang)化(hua)(hua)(hua)亞銅(tong)是(shi)高(gao)(gao)熔點脆(cui)性化(hua)(hua)(hua)合物,對于(yu)軋(ya)入較深的氧(yang)化(hua)(hua)(hua)亞銅(tong),當(dang)成條狀的聚集物遇模具(ju)拉伸時(shi),就會是(shi)銅(tong)桿外表面產生(sheng)毛刺(ci),給后(hou)續(xu)的涂漆(qi)造(zao)成麻煩(fan)。
而上引連鑄工(gong)藝制(zhi)造(zao)的無氧(yang)銅桿(gan),由于鑄造(zao)和冷(leng)卻完全與氧(yang)隔絕(jue),后(hou)續亦無熱軋過程,銅桿(gan)表面無軋入表面的氧(yang)化物,質(zhi)量(liang)較好,拉制(zhi)后(hou)銅粉少,上述(shu)問(wen)題較少存在。
無(wu)氧銅(tong)桿(gan)也(ye)分進(jin)口設(she)(she)(she)備做的和(he)國產(chan)設(she)(she)(she)備做的,但(dan)目前進(jin)口產(chan)品已無(wu)明顯優勢,銅(tong)桿(gan)產(chan)品出來(lai)后區(qu)別不是很大,只要銅(tong)板選的好,生(sheng)產(chan)控制(zhi)比較穩(wen)定,國產(chan)設(she)(she)(she)備也(ye)能(neng)產(chan)出可拉伸0.05的銅(tong)桿(gan).進(jin)口設(she)(she)(she)備一般是芬蘭奧托昆普的設(she)(she)(she)備,國產(chan)設(she)(she)(she)備最好的應該(gai)是上海(hai)的海(hai)軍(jun)廠的了,生(sheng)產(chan)時間最長,軍(jun)工企業(ye),質(zhi)量可靠。
低(di)氧銅(tong)桿進口設(she)(she)備國(guo)際(ji)主要有兩種,一(yi)種是(shi)美國(guo)南線(xian)設(she)(she)備,英文是(shi)SOUTHWIRE,國(guo)內廠(chang)家是(shi)南京(jing)華新(xin),江西銅(tong)業,另一(yi)種是(shi)德國(guo)CONTIROD設(she)(she)備,國(guo)內廠(chang)家是(shi)常州(zhou)金源,天津大(da)無(wu)縫。
無(wu)氧(yang)(yang)(yang)及低氧(yang)(yang)(yang)桿(gan)從含氧(yang)(yang)(yang)量(liang)上(shang)(shang)容易(yi)區別,無(wu)氧(yang)(yang)(yang)銅是含氧(yang)(yang)(yang)量(liang)在(zai)(zai)10-20個(ge)PPM以下,但(dan)(dan)(dan)(dan)目前(qian)有的(de)(de)(de)廠家(jia)只能(neng)做到(dao)50個(ge)PPM以下.低氧(yang)(yang)(yang)銅桿(gan)在(zai)(zai) 200-400個(ge)PPM,好(hao)(hao)的(de)(de)(de)桿(gan)子(zi)一般(ban)(ban)含氧(yang)(yang)(yang)量(liang)控(kong)制在(zai)(zai)250個(ge)PPM左右(you),無(wu)氧(yang)(yang)(yang)桿(gan)一般(ban)(ban)采取的(de)(de)(de)是上(shang)(shang)引法,低氧(yang)(yang)(yang)桿(gan)是連(lian)鑄連(lian)軋,兩種產品相對(dui)而言低氧(yang)(yang)(yang)桿(gan)對(dui)漆包線(xian)(xian)性(xing)(xing) 能(neng)更適應些,如柔軟(ruan)性(xing)(xing),回(hui)彈角,繞線(xian)(xian)性(xing)(xing)能(neng).但(dan)(dan)(dan)(dan)低氧(yang)(yang)(yang)桿(gan)對(dui)拉絲條(tiao)件(jian)相對(dui)要苛刻些,同樣(yang)拉伸(shen)0.2的(de)(de)(de)細絲,如果(guo)伸(shen)線(xian)(xian)條(tiao)件(jian)不好(hao)(hao),普(pu)通的(de)(de)(de)無(wu)氧(yang)(yang)(yang)桿(gan)可(ke)拉而好(hao)(hao)的(de)(de)(de)低氧(yang)(yang)(yang)桿(gan)就(jiu)斷 線(xian)(xian),但(dan)(dan)(dan)(dan)如果(guo)放在(zai)(zai)好(hao)(hao)的(de)(de)(de)伸(shen)線(xian)(xian)條(tiao)件(jian),同樣(yang)的(de)(de)(de)桿(gan)子(zi),低氧(yang)(yang)(yang)桿(gan)說(shuo)不定(ding)就(jiu)能(neng)拉到(dao)雙(shuang)零五,而普(pu)通無(wu)氧(yang)(yang)(yang)桿(gan)最多只能(neng)拉伸(shen)到(dao)0.1而已,當然(ran)做的(de)(de)(de)最細的(de)(de)(de)如雙(shuang)零二卻非得(de)依靠(kao)進口的(de)(de)(de) 無(wu)氧(yang)(yang)(yang)銅桿(gan)了.目前(qian)有企業嘗試用(yong)剝皮的(de)(de)(de)方式來(lai)處理低氧(yang)(yang)(yang)桿(gan)來(lai)伸(shen)0.03線(xian)(xian).但(dan)(dan)(dan)(dan)有關這方面的(de)(de)(de)內容我(wo)還不是很清楚。
音響線一般反而喜歡用(yong)無氧桿,這和無氧桿是單晶銅,低氧桿是多(duo)晶銅有關。
氧銅(tong)桿和無(wu)氧銅(tong)桿由于制(zhi)造(zao)方法(fa)的不同,致使存在差別,具有各自(zi)的特(te)點(dian)。
一、關于(yu)氧的吸入(ru)和脫去(qu)以及它的存在狀態
生(sheng)產銅(tong)(tong)(tong)(tong)桿(gan)(gan)(gan)的(de)(de)陰極銅(tong)(tong)(tong)(tong)的(de)(de)含氧(yang)(yang)量一(yi)般在10—50ppm,在常(chang)溫(wen)下(xia)氧(yang)(yang)在銅(tong)(tong)(tong)(tong)中的(de)(de)固(gu)溶(rong)度約(yue)2ppm。低(di)(di)(di)氧(yang)(yang)銅(tong)(tong)(tong)(tong)桿(gan)(gan)(gan)的(de)(de)含氧(yang)(yang)量一(yi)般在200(175)—400(450)ppm,因此氧(yang)(yang)的(de)(de)進(jin)入是在銅(tong)(tong)(tong)(tong)的(de)(de)液態下(xia)吸(xi)入的(de)(de),而上(shang)引法無氧(yang)(yang)銅(tong)(tong)(tong)(tong)桿(gan)(gan)(gan)則相(xiang)反,氧(yang)(yang)在液態銅(tong)(tong)(tong)(tong)下(xia)保持(chi)相(xiang)當時間后,被還原而脫去,通常(chang)這(zhe)種桿(gan)(gan)(gan)的(de)(de)含氧(yang)(yang)量都(dou)在10—50ppm以(yi)下(xia),最低(di)(di)(di)可達1-2ppm,從組(zu)織(zhi)上(shang)看,低(di)(di)(di)氧(yang)(yang)銅(tong)(tong)(tong)(tong)中的(de)(de)氧(yang)(yang),以(yi)氧(yang)(yang)化(hua)銅(tong)(tong)(tong)(tong)狀態,存在于(yu)晶(jing)粒邊(bian)界附(fu)近,這(zhe)對(dui)(dui)(dui)低(di)(di)(di)氧(yang)(yang)銅(tong)(tong)(tong)(tong)桿(gan)(gan)(gan)而言可以(yi)說是常(chang)見的(de)(de)但對(dui)(dui)(dui)無氧(yang)(yang)銅(tong)(tong)(tong)(tong)桿(gan)(gan)(gan)則很少(shao)見。氧(yang)(yang)化(hua)銅(tong)(tong)(tong)(tong)以(yi)夾雜(za)形式在晶(jing)界出現對(dui)(dui)(dui)材料的(de)(de)韌性產生(sheng)負面影(ying)響。而無氧(yang)(yang)銅(tong)(tong)(tong)(tong)中的(de)(de)氧(yang)(yang)很低(di)(di)(di),所以(yi)這(zhe)種銅(tong)(tong)(tong)(tong)的(de)(de)組(zu)織(zhi)是均勻的(de)(de)單相(xiang)組(zu)織(zhi)對(dui)(dui)(dui)韌性有利。在無氧(yang)(yang)銅(tong)(tong)(tong)(tong)桿(gan)(gan)(gan)中的(de)(de)多孔性是不常(chang)見的(de)(de),而在低(di)(di)(di)氧(yang)(yang)銅(tong)(tong)(tong)(tong)桿(gan)(gan)(gan)中則是常(chang)見的(de)(de)一(yi)種缺陷。
二(er)、熱軋組(zu)織和鑄造組(zu)織的區別
低(di)氧(yang)(yang)(yang)銅(tong)桿由于經(jing)過(guo)熱(re)軋,所以其組(zu)(zu)織(zhi)屬(shu)熱(re)加工(gong)組(zu)(zu)織(zhi),原來的(de)(de)(de)鑄造組(zu)(zu)織(zhi)已(yi)經(jing)破碎,在(zai)8mm的(de)(de)(de)桿時(shi)(shi)已(yi)有(you)(you)再結晶(jing)的(de)(de)(de)形式出現,而(er)無氧(yang)(yang)(yang)銅(tong)桿屬(shu)鑄造組(zu)(zu)織(zhi),晶(jing)粒粗大,這是(shi)為(wei)什么,無氧(yang)(yang)(yang)銅(tong)的(de)(de)(de)再結晶(jing)溫(wen)(wen)度較(jiao)高(gao),需要(yao)較(jiao)高(gao)退火溫(wen)(wen)度的(de)(de)(de)固有(you)(you)原因。這是(shi)因為(wei),再結晶(jing)發生在(zai)晶(jing)粒邊界(jie)附近,無氧(yang)(yang)(yang)銅(tong)桿組(zu)(zu)織(zhi)晶(jing)粒粗大,晶(jing)粒尺寸甚至能(neng)達幾個毫(hao)米,因而(er)晶(jing)粒邊界(jie)少,即使通過(guo)拉制(zhi)變(bian)形,但(dan)晶(jing)粒邊界(jie)相對(dui)低(di)氧(yang)(yang)(yang)銅(tong)桿還是(shi)較(jiao)少,所以需要(yao)較(jiao)高(gao)的(de)(de)(de)退火功(gong)(gong)率(lv)。對(dui)無氧(yang)(yang)(yang)銅(tong)成(cheng)功(gong)(gong)的(de)(de)(de)退火要(yao)求是(shi):由桿經(jing)拉制(zhi),但(dan)尚未鑄造組(zu)(zu)織(zhi)的(de)(de)(de)線時(shi)(shi)的(de)(de)(de)第一次退火,其退火功(gong)(gong)率(lv)應比同(tong)樣情(qing)況(kuang)的(de)(de)(de)低(di)氧(yang)(yang)(yang)銅(tong)高(gao)10——15%。經(jing)繼續拉制(zhi),在(zai)以后階段的(de)(de)(de)退火功(gong)(gong)率(lv)應留有(you)(you)足夠的(de)(de)(de)余量和對(dui)低(di)氧(yang)(yang)(yang)銅(tong)和無氧(yang)(yang)(yang)銅(tong)切實區別執(zhi)行不同(tong)的(de)(de)(de)退火工(gong)藝(yi),以保證在(zai)制(zhi)品和成(cheng)品導線的(de)(de)(de)柔軟性。
三、夾雜(za),氧(yang)含量波動,表面氧(yang)化物和可能存(cun)在的(de)熱軋(ya)缺陷(xian)的(de)差別
無氧(yang)銅桿(gan)的(de)(de)可拉(la)性在(zai)(zai)所有線(xian)徑里與(yu)低氧(yang)銅桿(gan)相比都是(shi)優越的(de)(de),除上述組織原(yuan)因外(wai),無氧(yang)銅桿(gan)夾雜少,含氧(yang)量穩(wen)定(ding)(ding),無熱軋可能產(chan)生的(de)(de)缺陷,桿(gan)表(biao)氧(yang)化(hua)物(wu)厚度(du)可達≤15A。在(zai)(zai)連鑄連軋生產(chan)過程中如果工(gong)藝不(bu)(bu)穩(wen)定(ding)(ding),對氧(yang)監控不(bu)(bu)嚴,含氧(yang)量不(bu)(bu)穩(wen)定(ding)(ding)將(jiang)直接影(ying)響桿(gan)的(de)(de)性能。如果桿(gan)的(de)(de)表(biao)面(mian)氧(yang)化(hua)物(wu)能在(zai)(zai)后(hou)工(gong)序(xu)的(de)(de)連續(xu)清(qing)洗中得以彌(mi)補外(wai),但(dan)比較麻煩的(de)(de)是(shi)有相當(dang)多的(de)(de)氧(yang)化(hua)物(wu)存在(zai)(zai)于“皮下”,對拉(la)線(xian)斷線(xian)影(ying)響更直接,故而在(zai)(zai)拉(la)制微(wei)細線(xian),超(chao)微(wei)細線(xian)時,為了(le)減(jian)少斷線(xian),有時要對銅桿(gan)采取不(bu)(bu)得已的(de)(de)辦法——剝皮,甚至二次剝皮的(de)(de)原(yuan)因所在(zai)(zai),目(mu)的(de)(de)要除去(qu)皮下氧(yang)化(hua)物(wu)。
四、低氧(yang)銅桿和無氧(yang)銅桿的韌性(xing)有(you)差別
兩者都可以拉到0.015mm,但在(zai)低(di)溫超導線(xian)中的(de)低(di)溫級無氧(yang)銅,其細絲間(jian)的(de)間(jian)距只有(you)0.001mm.
五(wu)、從制桿(gan)的(de)原(yuan)材料(liao)到制線的(de)經濟性(xing)有差別。
制造無氧(yang)銅桿(gan)要求質(zhi)量較(jiao)高(gao)的(de)(de)原材(cai)料。一般,拉制直徑(jing)>1mm的(de)(de)銅線(xian)時,低氧(yang)銅桿(gan)的(de)(de)優點比較(jiao)明顯,而無氧(yang)銅桿(gan)顯得更(geng)為優越的(de)(de)是拉制直徑(jing)<0.5mm的(de)(de)銅線(xian)。
六、低(di)氧(yang)(yang)銅(tong)桿的制線工藝與(yu)無氧(yang)(yang)銅(tong)桿的有所不同。
低氧銅桿的(de)(de)制線工藝不(bu)能照搬到(dao)無氧銅桿的(de)(de)制線工藝上來,至少兩者的(de)(de)退(tui)(tui)火工藝是不(bu)同的(de)(de)。因為線的(de)(de)柔軟(ruan)性深受材料(liao)成(cheng)份和制桿,制線和退(tui)(tui)火工藝的(de)(de)影響,不(bu)能簡單地說低氧銅或無氧銅誰軟(ruan)誰硬。
下一(yi)條通遼如何分辨劣質線纜(電纜人必備)