熱(re)門關(guan)鍵詞:
來源(yuan):行業動態 閱讀:109423 發布時間:2019-07-05
導讀:由于生產銅(tong)桿的(de)(de)(de)(de)兩者的(de)(de)(de)(de)工藝不同,所生產的(de)(de)(de)(de)銅(tong)桿中的(de)(de)(de)(de)含氧量及外(wai)觀就不同。上引生產的(de)(de)(de)(de)銅(tong)桿,工藝得(de)當氧含量在10ppm以下(xia),叫無氧銅(tong)桿;連鑄(zhu)連鑄(zhu)生產的(de)(de)(de)(de)銅(tong)桿 是在保護(hu)條件下(xia)的(de)(de)(de)(de)熱軋,氧含量在200-500ppm范圍內,但(dan)有(you)時也高達700ppm以上,一般情況下(xia),此(ci)種方法生產的(de)(de)(de)(de)銅(tong)外(wai)表光(guang)亮,低(di)氧銅(tong)桿,有(you)時也叫光(guang)桿。
銅桿(gan)(gan)是電纜(lan)行(xing)業的(de)(de)主(zhu)要(yao)原料(liao),生(sheng)(sheng)產(chan)的(de)(de)方(fang)式(shi)主(zhu)要(yao)有兩種——連(lian)鑄(zhu)(zhu)(zhu)(zhu)連(lian)軋法和上(shang)引(yin)連(lian)鑄(zhu)(zhu)(zhu)(zhu)法。連(lian)鑄(zhu)(zhu)(zhu)(zhu)連(lian)軋低(di)氧銅桿(gan)(gan)的(de)(de)生(sheng)(sheng)產(chan)方(fang)法較(jiao)多,其特點(dian)是金(jin)屬(shu)在(zai)豎(shu)爐中融(rong)化(hua)后(hou),銅液通過保溫爐、溜槽、中間(jian)包,從澆管(guan)進入封閉的(de)(de)模(mo)腔內,采用較(jiao)大的(de)(de)冷卻(que)強度進行(xing)冷卻(que),形成鑄(zhu)(zhu)(zhu)(zhu)坯,然后(hou)進行(xing)多道次(ci)軋制,生(sheng)(sheng)產(chan)的(de)(de)低(di)氧銅桿(gan)(gan)為熱加工(gong)組織(zhi),原來的(de)(de)鑄(zhu)(zhu)(zhu)(zhu)造(zao)組織(zhi)已(yi)經破碎(sui),含(han)氧量(liang)一般為200~400ppm之間(jian)。無氧銅桿(gan)(gan)國內基(ji)本全部采用上(shang)引(yin)連(lian)鑄(zhu)(zhu)(zhu)(zhu)法生(sheng)(sheng)產(chan),金(jin)屬(shu)在(zai)感應(ying)電爐中融(rong)化(hua)后(hou)通過石(shi)墨模(mo)進行(xing)上(shang)引(yin)連(lian)續鑄(zhu)(zhu)(zhu)(zhu)造(zao),之后(hou)進行(xing)冷軋或(huo)冷加工(gong),生(sheng)(sheng)產(chan)的(de)(de)無氧銅桿(gan)(gan)為鑄(zhu)(zhu)(zhu)(zhu)造(zao)組織(zhi),含(han)氧量(liang)一般在(zai)20ppm以下(xia)。由于制造(zao)工(gong)藝的(de)(de)不(bu)同,所(suo)以在(zai)組織(zhi)結構、氧含(han)量(liang)分布、雜質的(de)(de)形式(shi)及分布等諸多方(fang)面有較(jiao)大差別。
一、拉制性能
銅桿(gan)的拉制(zhi)性(xing)能跟(gen)很多因素有關,如雜質的含(han)量、氧含(han)量及(ji)分布、工藝控制(zhi)等(deng)。下面(mian)(mian)分別從以上幾(ji)個方(fang)面(mian)(mian)對銅桿(gan)的拉制(zhi)性(xing)能進行分析。
1、熔化方(fang)式(shi)對S等雜質的影響
連鑄(zhu)連軋生產銅(tong)桿主要是通(tong)(tong)過氣體的(de)(de)燃燒使銅(tong)桿熔化,在燃燒的(de)(de)過程中(zhong),通(tong)(tong)過氧(yang)化和揮發作(zuo)用(yong),可一(yi)定程度減少部分(fen)雜質(zhi)進入(ru)銅(tong)液(ye),因此連鑄(zhu)連軋法對(dui)原料要求相對(dui)低一(yi)些。上(shang)引連鑄(zhu)生產無(wu)氧(yang)銅(tong)桿,由于是用(yong)感應電(dian)爐(lu)熔化,電(dian)解(jie)銅(tong)表面的(de)(de)“銅(tong)綠”“銅(tong)豆”基本都熔入(ru)到銅(tong)液(ye)中(zhong)。其中(zhong)熔入(ru)的(de)(de)S對(dui)無(wu)氧(yang)銅(tong)桿塑性影響極大(da),會增加拉(la)絲斷線率。
2、鑄造(zao)過程中雜(za)質的(de)進入
在生(sheng)產(chan)過程(cheng)(cheng)中(zhong),連(lian)(lian)鑄連(lian)(lian)軋工藝(yi)需(xu)通過保溫爐(lu)、溜槽、中(zhong)間包(bao)轉運銅(tong)液(ye),相對(dui)容(rong)易造(zao)(zao)成耐(nai)火(huo)材(cai)料的(de)(de)剝落,在軋制過程(cheng)(cheng)中(zhong)需(xu)要通過軋輥,造(zao)(zao)成鐵質的(de)(de)脫落,會給銅(tong)桿(gan)(gan)造(zao)(zao)成外部(bu)夾雜。而熱軋中(zhong)皮上(shang)和(he)皮下(xia)氧化(hua)物的(de)(de)軋入,會給低氧桿(gan)(gan)的(de)(de)拉(la)絲造(zao)(zao)成不(bu)利的(de)(de)影響。上(shang)引連(lian)(lian)鑄法生(sheng)產(chan)工藝(yi)流程(cheng)(cheng)較短(duan),銅(tong)液(ye)是通過聯體(ti)爐(lu)內潛流式完成,對(dui)耐(nai)火(huo)材(cai)料的(de)(de)沖擊不(bu)大,結晶(jing)是通過石墨(mo)模內進行,所以過程(cheng)(cheng)中(zhong)可能(neng)產(chan)生(sheng)的(de)(de)污染(ran)源(yuan)較少,雜質進入的(de)(de)機會較少。
O、S、P是與銅(tong)(tong)(tong)(tong)會生產(chan)化合物的元素。在熔(rong)態(tai)銅(tong)(tong)(tong)(tong)中(zhong),氧(yang)可(ke)以溶解(jie)(jie)一部(bu)分,但當銅(tong)(tong)(tong)(tong)冷凝時,氧(yang)幾乎不溶解(jie)(jie)于銅(tong)(tong)(tong)(tong)中(zhong)。熔(rong)態(tai)時所溶解(jie)(jie)的氧(yang),以銅(tong)(tong)(tong)(tong)=氧(yang)化亞(ya)銅(tong)(tong)(tong)(tong)共晶(jing)體析出,分布在晶(jing)粒晶(jing)界處。銅(tong)(tong)(tong)(tong)-氧(yang)化亞(ya)銅(tong)(tong)(tong)(tong)共晶(jing)體的出現,顯著(zhu)降(jiang)低了(le)銅(tong)(tong)(tong)(tong)的塑性。
硫可以溶解(jie)在(zai)熔體的(de)銅(tong)中,但在(zai)室溫下(xia),其(qi)溶解(jie)度(du)幾乎降(jiang)低到(dao)零,它以硫化亞銅(tong)的(de)形(xing)式出現在(zai)晶(jing)粒晶(jing)界(jie)處,會顯(xian)著降(jiang)低銅(tong)的(de)塑性。
3、氧在低(di)氧銅桿和無(wu)氧銅桿中(zhong)分布(bu)形式及其影響
氧(yang)含(han)量(liang)對低氧(yang)銅(tong)桿的(de)拉線性能有著(zhu)明顯(xian)的(de)影響(xiang)。當氧(yang)含(han)量(liang)增加(jia)到最(zui)佳值(zhi)時,銅(tong)桿的(de)斷線率最(zui)低。這是因為氧(yang)在與(yu)大部分雜質反應的(de)過程中都起(qi)到了(le)清除器的(de)作用。適(shi)度的(de)氧(yang)還有利于(yu)去除銅(tong)液中的(de)氫,生(sheng)成(cheng)水蒸氣溢出(chu),減少氣孔(kong)的(de)形成(cheng)。最(zui)佳的(de)氧(yang)含(han)量(liang)為拉線工藝提供了(le)最(zui)好的(de)條(tiao)件。
低氧(yang)銅桿氧(yang)化(hua)物(wu)(wu)的(de)(de)分(fen)布:在連續澆鑄中凝固(gu)的(de)(de)最初(chu)階(jie)段,散熱速率和均勻冷卻是決定銅桿氧(yang)化(hua)物(wu)(wu)分(fen)布的(de)(de)主要因素。不均勻冷卻會(hui)引起銅桿內部結構本質上的(de)(de)差異,但后續的(de)(de)熱加工,柱狀晶(jing)通常會(hui)遭到破壞(huai),使氧(yang)化(hua)亞(ya)銅顆(ke)粒(li)細微化(hua)和均勻分(fen)布。氧(yang)化(hua)物(wu)(wu)顆(ke)粒(li)聚集而(er)產生(sheng)的(de)(de)典型情(qing)況是中心(xin)爆(bao)裂。除氧(yang)化(hua)物(wu)(wu)顆(ke)粒(li)分(fen)布的(de)(de)影響(xiang)外,具(ju)有較小(xiao)氧(yang)化(hua)物(wu)(wu)顆(ke)粒(li)的(de)(de)銅桿顯示出較好(hao)的(de)(de)拉線特性(xing),較大的(de)(de)Cu2O顆(ke)粒(li)容易造成應(ying)力集中點而(er)斷裂。
無氧(yang)(yang)(yang)銅(tong)(tong)(tong)含氧(yang)(yang)(yang)量(liang)超標,銅(tong)(tong)(tong)桿(gan)變脆,延伸率下降(jiang),拉伸式樣端口顯暗紅(hong)色,結晶組(zu)織(zhi)疏松(song)。當氧(yang)(yang)(yang)含量(liang)超出(chu)8ppm時(shi),工(gong)(gong)(gong)藝性能(neng)變差(cha),表現為鑄(zhu)造(zao)及(ji)拉伸過程中(zhong)斷(duan)桿(gan)及(ji)斷(duan)線率極具增高(gao)。這(zhe)(zhe)是(shi)由于氧(yang)(yang)(yang)能(neng)與銅(tong)(tong)(tong)生成氧(yang)(yang)(yang)化亞(ya)銅(tong)(tong)(tong)脆性相,形成銅(tong)(tong)(tong)-氧(yang)(yang)(yang)化亞(ya)銅(tong)(tong)(tong)共晶體,以網狀組(zu)織(zhi)分布在(zai)境(jing)界上。這(zhe)(zhe)種(zhong)脆性相硬(ying)度高(gao),在(zai)冷變形時(shi)將會與銅(tong)(tong)(tong)機體脫離,導致(zhi)銅(tong)(tong)(tong)桿(gan)的機械性能(neng)下降(jiang),在(zai)后(hou)續(xu)加工(gong)(gong)(gong)中(zhong)容易造(zao)成斷(duan)裂現象。氧(yang)(yang)(yang)含量(liang)高(gao)還能(neng)導致(zhi)無氧(yang)(yang)(yang)銅(tong)(tong)(tong)桿(gan)導電(dian)率下降(jiang)。因此,必(bi)須嚴格控(kong)制上引連(lian)鑄(zhu)工(gong)(gong)(gong)藝及(ji)產(chan)品質量(liang)。
4、氫的影響
在上引連鑄中,氧含量(liang)控制較低,氧化物的副作用唄**降低,但氫的影響成為較顯(xian)著的問題。吸氣后熔(rong)體(ti)中存在平衡反(fan)應:H2O(g)=[O]+2[H];
氣(qi)(qi)(qi)體(ti)及疏(shu)松是(shi)在結晶(jing)的(de)(de)(de)(de)過(guo)程中(zhong),氫(qing)從過(guo)飽和(he)的(de)(de)(de)(de)溶液(ye)(ye)中(zhong)析(xi)出并(bing)聚集而形(xing)(xing)(xing)成(cheng)的(de)(de)(de)(de)。在結晶(jing)前(qian)析(xi)出的(de)(de)(de)(de)氫(qing)又可還原氧化亞銅(tong)而生成(cheng)水氣(qi)(qi)(qi)泡。由于上(shang)(shang)引鑄(zhu)造的(de)(de)(de)(de)特點是(shi)銅(tong)液(ye)(ye)自(zi)上(shang)(shang)而下的(de)(de)(de)(de)結晶(jing),形(xing)(xing)(xing)成(cheng)的(de)(de)(de)(de)液(ye)(ye)**形(xing)(xing)(xing)狀(zhuang)近似(si)錐型。銅(tong)液(ye)(ye)結晶(jing)前(qian)析(xi)出的(de)(de)(de)(de)氣(qi)(qi)(qi)體(ti)在上(shang)(shang)浮(fu)過(guo)程中(zhong)被堵在凝固組織內,結晶(jing)時在鑄(zhu)桿(gan)內形(xing)(xing)(xing)成(cheng)氣(qi)(qi)(qi)孔。上(shang)(shang)引的(de)(de)(de)(de)含氣(qi)(qi)(qi)量少時,析(xi)出的(de)(de)(de)(de)氫(qing)存在于晶(jing)界處,形(xing)(xing)(xing)成(cheng)疏(shu)松;含氣(qi)(qi)(qi)量多時,則聚集成(cheng)氣(qi)(qi)(qi)孔,因此,氣(qi)(qi)(qi)孔和(he)疏(shu)松是(shi)氫(qing)氣(qi)(qi)(qi)和(he)水蒸氣(qi)(qi)(qi)兩(liang)者形(xing)(xing)(xing)成(cheng)的(de)(de)(de)(de)。
氫來源于上引生產過程中的(de)各(ge)個(ge)工藝環(huan)節(jie),如(ru)原料電解銅(tong)(tong)(tong)的(de)“銅(tong)(tong)(tong)綠”、輔料木(mu)炭**、氣(qi)候環(huan)境(jing)**、石墨(mo)結晶(jing)器(qi)未干燥等。因此,熔化爐中的(de)銅(tong)(tong)(tong)液表面應(ying)覆蓋經烘(hong)烤的(de)木(mu)炭,電解銅(tong)(tong)(tong)應(ying)盡量(liang)去除“銅(tong)(tong)(tong)綠”、“銅(tong)(tong)(tong)豆”“耳朵”,對提高無氧銅(tong)(tong)(tong)桿(gan)質量(liang)非(fei)常重要(yao)。
在連鑄連軋工(gong)藝中,往(wang)往(wang)采用適度控(kong)制氧含量來控(kong)制氫。Cu2O+ H2= 2Cu+ H2O
由于銅液(ye)在鑄造(zao)過(guo)程中(zhong)是自下而(er)上結(jie)晶,銅液(ye)中(zhong)的(de)氧和氫所產生的(de)水蒸氣很(hen)容(rong)易上浮跑(pao)出,銅液(ye)中(zhong)的(de)氫大部分能被有效去除,因(yin)而(er)對銅桿的(de)影響較小。
二、表面質量
在生產電磁線等產品的過程(cheng)中,對銅(tong)(tong)桿(gan)的表(biao)面(mian)質(zhi)量也需提(ti)出要求。需要拉制后的銅(tong)(tong)絲表(biao)面(mian)無(wu)毛刺、銅(tong)(tong)粉少、無(wu)油污。并(bing)通過扭轉(zhuan)試驗測(ce)量表(biao)面(mian)銅(tong)(tong)粉的質(zhi)量和(he)扭轉(zhuan)后觀察銅(tong)(tong)桿(gan)的復原(yuan)情況(kuang)來判(pan)定其好壞。
在連(lian)鑄(zhu)連(lian)軋(ya)(ya)過(guo)程中,從鑄(zhu)造到軋(ya)(ya)制前,溫度高,完全暴露于空氣中,使鑄(zhu)坯表面形成(cheng)較厚的(de)(de)氧(yang)化(hua)層,在軋(ya)(ya)制過(guo)程中,隨著軋(ya)(ya)輥的(de)(de)轉動,氧(yang)化(hua)物(wu)顆(ke)粒軋(ya)(ya)入銅(tong)線表面。由(you)于氧(yang)化(hua)亞銅(tong)是(shi)高熔(rong)點(dian)脆(cui)性化(hua)合(he)物(wu),對于軋(ya)(ya)入較深的(de)(de)氧(yang)化(hua)亞銅(tong),當成(cheng)條狀的(de)(de)聚集物(wu)遇模具(ju)拉伸時,就會是(shi)銅(tong)桿(gan)外表面產生毛刺,給后續的(de)(de)涂漆造成(cheng)麻煩。
而上引(yin)連(lian)鑄(zhu)(zhu)工藝制造(zao)的(de)無氧(yang)銅桿,由于鑄(zhu)(zhu)造(zao)和冷卻完(wan)全與氧(yang)隔絕,后(hou)續亦無熱軋(ya)過(guo)程,銅桿表面(mian)(mian)無軋(ya)入表面(mian)(mian)的(de)氧(yang)化物,質量較好,拉制后(hou)銅粉少,上述問題較少存在。
無(wu)氧銅桿也(ye)分進(jin)口(kou)設(she)備(bei)做的和(he)國(guo)產(chan)設(she)備(bei)做的,但目前進(jin)口(kou)產(chan)品已無(wu)明顯(xian)優(you)勢(shi),銅桿產(chan)品出來(lai)后(hou)區(qu)別不(bu)是很大,只要銅板選的好(hao)(hao),生產(chan)控(kong)制比較穩定,國(guo)產(chan)設(she)備(bei)也(ye)能(neng)產(chan)出可拉伸0.05的銅桿.進(jin)口(kou)設(she)備(bei)一般是芬蘭奧(ao)托(tuo)昆普的設(she)備(bei),國(guo)產(chan)設(she)備(bei)最(zui)好(hao)(hao)的應該是上海(hai)的海(hai)軍廠的了,生產(chan)時(shi)間最(zui)長,軍工企業,質量可靠(kao)。
低氧銅桿進口設備(bei)國(guo)(guo)際主要有兩種,一(yi)種是(shi)美國(guo)(guo)南(nan)線設備(bei),英(ying)文是(shi)SOUTHWIRE,國(guo)(guo)內廠家是(shi)南(nan)京(jing)華新,江西銅業(ye),另(ling)一(yi)種是(shi)德(de)國(guo)(guo)CONTIROD設備(bei),國(guo)(guo)內廠家是(shi)常州金(jin)源,天津大無縫。
無氧(yang)(yang)(yang)及低(di)氧(yang)(yang)(yang)桿(gan)(gan)從含氧(yang)(yang)(yang)量上容易區別,無氧(yang)(yang)(yang)銅是(shi)含氧(yang)(yang)(yang)量在(zai)10-20個PPM以(yi)下(xia),但(dan)目前有(you)的(de)廠家只(zhi)能做(zuo)到50個PPM以(yi)下(xia).低(di)氧(yang)(yang)(yang)銅桿(gan)(gan)在(zai) 200-400個PPM,好(hao)的(de)桿(gan)(gan)子(zi)一(yi)般含氧(yang)(yang)(yang)量控制在(zai)250個PPM左右(you),無氧(yang)(yang)(yang)桿(gan)(gan)一(yi)般采(cai)取的(de)是(shi)上引法(fa),低(di)氧(yang)(yang)(yang)桿(gan)(gan)是(shi)連(lian)鑄(zhu)連(lian)軋,兩(liang)種產品相對(dui)而(er)言低(di)氧(yang)(yang)(yang)桿(gan)(gan)對(dui)漆包線(xian)性 能更適應(ying)些,如(ru)柔軟性,回(hui)彈角,繞線(xian)性能.但(dan)低(di)氧(yang)(yang)(yang)桿(gan)(gan)對(dui)拉絲(si)條(tiao)件相對(dui)要苛刻些,同樣(yang)拉伸0.2的(de)細絲(si),如(ru)果(guo)(guo)伸線(xian)條(tiao)件不好(hao),普(pu)通的(de)無氧(yang)(yang)(yang)桿(gan)(gan)可拉而(er)好(hao)的(de)低(di)氧(yang)(yang)(yang)桿(gan)(gan)就斷 線(xian),但(dan)如(ru)果(guo)(guo)放在(zai)好(hao)的(de)伸線(xian)條(tiao)件,同樣(yang)的(de)桿(gan)(gan)子(zi),低(di)氧(yang)(yang)(yang)桿(gan)(gan)說不定(ding)就能拉到雙零五,而(er)普(pu)通無氧(yang)(yang)(yang)桿(gan)(gan)最多只(zhi)能拉伸到0.1而(er)已,當(dang)然做(zuo)的(de)最細的(de)如(ru)雙零二(er)卻非得依靠進口(kou)的(de) 無氧(yang)(yang)(yang)銅桿(gan)(gan)了.目前有(you)企業嘗(chang)試用剝皮的(de)方式來處(chu)理低(di)氧(yang)(yang)(yang)桿(gan)(gan)來伸0.03線(xian).但(dan)有(you)關這方面(mian)的(de)內容我還不是(shi)很(hen)清(qing)楚。
音響(xiang)線一般反(fan)而喜歡(huan)用無氧(yang)桿,這和(he)無氧(yang)桿是(shi)單晶銅(tong),低氧(yang)桿是(shi)多晶銅(tong)有關。
氧銅桿(gan)和無氧銅桿(gan)由于(yu)制造方(fang)法的(de)不同,致使存在差別(bie),具有各自的(de)特點(dian)。
一、關(guan)于氧的吸入和脫去以及它的存在狀(zhuang)態
生(sheng)(sheng)產銅(tong)(tong)(tong)(tong)桿(gan)(gan)(gan)的(de)(de)(de)(de)(de)陰極銅(tong)(tong)(tong)(tong)的(de)(de)(de)(de)(de)含氧(yang)(yang)(yang)(yang)(yang)量一(yi)般在(zai)(zai)10—50ppm,在(zai)(zai)常(chang)(chang)溫下氧(yang)(yang)(yang)(yang)(yang)在(zai)(zai)銅(tong)(tong)(tong)(tong)中(zhong)(zhong)(zhong)的(de)(de)(de)(de)(de)固溶(rong)度(du)約2ppm。低(di)氧(yang)(yang)(yang)(yang)(yang)銅(tong)(tong)(tong)(tong)桿(gan)(gan)(gan)的(de)(de)(de)(de)(de)含氧(yang)(yang)(yang)(yang)(yang)量一(yi)般在(zai)(zai)200(175)—400(450)ppm,因(yin)此氧(yang)(yang)(yang)(yang)(yang)的(de)(de)(de)(de)(de)進(jin)入是(shi)(shi)在(zai)(zai)銅(tong)(tong)(tong)(tong)的(de)(de)(de)(de)(de)液態下吸入的(de)(de)(de)(de)(de),而(er)(er)上(shang)引法無(wu)(wu)氧(yang)(yang)(yang)(yang)(yang)銅(tong)(tong)(tong)(tong)桿(gan)(gan)(gan)則相(xiang)(xiang)反,氧(yang)(yang)(yang)(yang)(yang)在(zai)(zai)液態銅(tong)(tong)(tong)(tong)下保持(chi)相(xiang)(xiang)當時間(jian)后,被還原而(er)(er)脫去,通常(chang)(chang)這(zhe)種桿(gan)(gan)(gan)的(de)(de)(de)(de)(de)含氧(yang)(yang)(yang)(yang)(yang)量都在(zai)(zai)10—50ppm以(yi)下,最低(di)可達1-2ppm,從組織上(shang)看,低(di)氧(yang)(yang)(yang)(yang)(yang)銅(tong)(tong)(tong)(tong)中(zhong)(zhong)(zhong)的(de)(de)(de)(de)(de)氧(yang)(yang)(yang)(yang)(yang),以(yi)氧(yang)(yang)(yang)(yang)(yang)化(hua)銅(tong)(tong)(tong)(tong)狀態,存在(zai)(zai)于晶粒邊界附(fu)近,這(zhe)對低(di)氧(yang)(yang)(yang)(yang)(yang)銅(tong)(tong)(tong)(tong)桿(gan)(gan)(gan)而(er)(er)言(yan)可以(yi)說是(shi)(shi)常(chang)(chang)見的(de)(de)(de)(de)(de)但對無(wu)(wu)氧(yang)(yang)(yang)(yang)(yang)銅(tong)(tong)(tong)(tong)桿(gan)(gan)(gan)則很少見。氧(yang)(yang)(yang)(yang)(yang)化(hua)銅(tong)(tong)(tong)(tong)以(yi)夾雜形(xing)式在(zai)(zai)晶界出現對材料的(de)(de)(de)(de)(de)韌性產生(sheng)(sheng)負面影響。而(er)(er)無(wu)(wu)氧(yang)(yang)(yang)(yang)(yang)銅(tong)(tong)(tong)(tong)中(zhong)(zhong)(zhong)的(de)(de)(de)(de)(de)氧(yang)(yang)(yang)(yang)(yang)很低(di),所(suo)以(yi)這(zhe)種銅(tong)(tong)(tong)(tong)的(de)(de)(de)(de)(de)組織是(shi)(shi)均勻的(de)(de)(de)(de)(de)單相(xiang)(xiang)組織對韌性有利。在(zai)(zai)無(wu)(wu)氧(yang)(yang)(yang)(yang)(yang)銅(tong)(tong)(tong)(tong)桿(gan)(gan)(gan)中(zhong)(zhong)(zhong)的(de)(de)(de)(de)(de)多(duo)孔性是(shi)(shi)不(bu)常(chang)(chang)見的(de)(de)(de)(de)(de),而(er)(er)在(zai)(zai)低(di)氧(yang)(yang)(yang)(yang)(yang)銅(tong)(tong)(tong)(tong)桿(gan)(gan)(gan)中(zhong)(zhong)(zhong)則是(shi)(shi)常(chang)(chang)見的(de)(de)(de)(de)(de)一(yi)種缺陷(xian)。
二(er)、熱軋組(zu)織(zhi)(zhi)和鑄造組(zu)織(zhi)(zhi)的區別
低(di)氧(yang)銅(tong)(tong)桿(gan)由于(yu)經(jing)過(guo)熱軋,所(suo)以(yi)其組(zu)織屬(shu)熱加工組(zu)織,原(yuan)來的(de)(de)(de)鑄造(zao)(zao)組(zu)織已經(jing)破碎,在8mm的(de)(de)(de)桿(gan)時已有再結(jie)晶(jing)的(de)(de)(de)形(xing)式出現,而(er)無氧(yang)銅(tong)(tong)桿(gan)屬(shu)鑄造(zao)(zao)組(zu)織,晶(jing)粒粗(cu)大,這(zhe)是(shi)為什么,無氧(yang)銅(tong)(tong)的(de)(de)(de)再結(jie)晶(jing)溫(wen)度較(jiao)高,需(xu)(xu)要較(jiao)高退(tui)(tui)火(huo)溫(wen)度的(de)(de)(de)固有原(yuan)因(yin)。這(zhe)是(shi)因(yin)為,再結(jie)晶(jing)發生(sheng)在晶(jing)粒邊(bian)界(jie)(jie)附近,無氧(yang)銅(tong)(tong)桿(gan)組(zu)織晶(jing)粒粗(cu)大,晶(jing)粒尺寸甚至(zhi)能達幾個毫(hao)米,因(yin)而(er)晶(jing)粒邊(bian)界(jie)(jie)少,即使通過(guo)拉(la)(la)制變形(xing),但晶(jing)粒邊(bian)界(jie)(jie)相對(dui)低(di)氧(yang)銅(tong)(tong)桿(gan)還是(shi)較(jiao)少,所(suo)以(yi)需(xu)(xu)要較(jiao)高的(de)(de)(de)退(tui)(tui)火(huo)功率(lv)。對(dui)無氧(yang)銅(tong)(tong)成(cheng)功的(de)(de)(de)退(tui)(tui)火(huo)要求是(shi):由桿(gan)經(jing)拉(la)(la)制,但尚未(wei)鑄造(zao)(zao)組(zu)織的(de)(de)(de)線時的(de)(de)(de)第(di)一次退(tui)(tui)火(huo),其退(tui)(tui)火(huo)功率(lv)應比同(tong)樣情況的(de)(de)(de)低(di)氧(yang)銅(tong)(tong)高10——15%。經(jing)繼續拉(la)(la)制,在以(yi)后階(jie)段的(de)(de)(de)退(tui)(tui)火(huo)功率(lv)應留有足夠的(de)(de)(de)余量和(he)對(dui)低(di)氧(yang)銅(tong)(tong)和(he)無氧(yang)銅(tong)(tong)切實(shi)區別執行不同(tong)的(de)(de)(de)退(tui)(tui)火(huo)工藝,以(yi)保(bao)證在制品(pin)和(he)成(cheng)品(pin)導線的(de)(de)(de)柔(rou)軟(ruan)性。
三、夾雜,氧(yang)含量波動,表面(mian)氧(yang)化物和可(ke)能存在的熱軋缺陷的差別
無氧(yang)(yang)(yang)銅桿的(de)(de)(de)可(ke)(ke)拉性在(zai)所有(you)線(xian)(xian)徑(jing)里與低氧(yang)(yang)(yang)銅桿相比都是(shi)優越的(de)(de)(de),除(chu)上述組織(zhi)原因外(wai),無氧(yang)(yang)(yang)銅桿夾雜少,含(han)氧(yang)(yang)(yang)量穩定,無熱(re)軋可(ke)(ke)能產生的(de)(de)(de)缺(que)陷,桿表氧(yang)(yang)(yang)化(hua)物厚(hou)度可(ke)(ke)達≤15A。在(zai)連鑄連軋生產過程中(zhong)如(ru)果工(gong)藝不穩定,對(dui)(dui)氧(yang)(yang)(yang)監控不嚴,含(han)氧(yang)(yang)(yang)量不穩定將直(zhi)接(jie)影響桿的(de)(de)(de)性能。如(ru)果桿的(de)(de)(de)表面氧(yang)(yang)(yang)化(hua)物能在(zai)后工(gong)序(xu)的(de)(de)(de)連續清洗(xi)中(zhong)得(de)以彌補外(wai),但比較麻煩的(de)(de)(de)是(shi)有(you)相當(dang)多的(de)(de)(de)氧(yang)(yang)(yang)化(hua)物存在(zai)于(yu)“皮(pi)下”,對(dui)(dui)拉線(xian)(xian)斷線(xian)(xian)影響更直(zhi)接(jie),故而在(zai)拉制(zhi)微細(xi)線(xian)(xian),超(chao)微細(xi)線(xian)(xian)時,為(wei)了減少斷線(xian)(xian),有(you)時要對(dui)(dui)銅桿采取不得(de)已的(de)(de)(de)辦法——剝(bo)皮(pi),甚至二(er)次剝(bo)皮(pi)的(de)(de)(de)原因所在(zai),目的(de)(de)(de)要除(chu)去皮(pi)下氧(yang)(yang)(yang)化(hua)物。
四(si)、低(di)氧銅(tong)桿和無氧銅(tong)桿的韌性有(you)差別
兩(liang)者都可(ke)以拉到(dao)0.015mm,但在低溫超導線中的低溫級無(wu)氧銅,其細絲間(jian)的間(jian)距(ju)只有0.001mm.
五、從制桿的原(yuan)材(cai)料到制線(xian)的經濟性有差別。
制造無氧(yang)銅桿(gan)要求(qiu)質量較高的原(yuan)材料(liao)。一般,拉(la)制直(zhi)徑(jing)>1mm的銅線(xian)時,低(di)氧(yang)銅桿(gan)的優點比較明顯(xian),而無氧(yang)銅桿(gan)顯(xian)得更為優越的是拉(la)制直(zhi)徑(jing)<0.5mm的銅線(xian)。
六、低氧(yang)銅桿的(de)制線工藝與無(wu)氧(yang)銅桿的(de)有所不同。
低(di)氧(yang)(yang)銅(tong)桿(gan)(gan)(gan)的(de)制(zhi)線(xian)工藝不(bu)(bu)能照(zhao)搬到無氧(yang)(yang)銅(tong)桿(gan)(gan)(gan)的(de)制(zhi)線(xian)工藝上來,至少兩者的(de)退火(huo)工藝是不(bu)(bu)同(tong)的(de)。因(yin)為(wei)線(xian)的(de)柔軟性深受(shou)材料(liao)成份和(he)制(zhi)桿(gan)(gan)(gan),制(zhi)線(xian)和(he)退火(huo)工藝的(de)影響,不(bu)(bu)能簡單地(di)說低(di)氧(yang)(yang)銅(tong)或無氧(yang)(yang)銅(tong)誰軟誰硬。
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