熱門(men)關鍵詞(ci):
來源:行業動態 閱讀:109531 發布(bu)時(shi)間:2019-07-05
導讀:由于生產銅(tong)(tong)桿的(de)(de)(de)兩(liang)者的(de)(de)(de)工藝(yi)不(bu)同(tong),所(suo)生產的(de)(de)(de)銅(tong)(tong)桿中的(de)(de)(de)含氧(yang)量(liang)及外觀就不(bu)同(tong)。上(shang)引(yin)生產的(de)(de)(de)銅(tong)(tong)桿,工藝(yi)得當氧(yang)含量(liang)在10ppm以(yi)下,叫無氧(yang)銅(tong)(tong)桿;連鑄連鑄生產的(de)(de)(de)銅(tong)(tong)桿 是(shi)在保護條件下的(de)(de)(de)熱軋,氧(yang)含量(liang)在200-500ppm范(fan)圍內,但(dan)有時(shi)也高達700ppm以(yi)上(shang),一般情(qing)況下,此種(zhong)方法生產的(de)(de)(de)銅(tong)(tong)外表(biao)光(guang)亮,低氧(yang)銅(tong)(tong)桿,有時(shi)也叫光(guang)桿。
銅(tong)(tong)桿(gan)是(shi)電纜行業的主要原料(liao),生(sheng)產(chan)的方(fang)式主要有(you)兩種——連(lian)(lian)鑄(zhu)(zhu)連(lian)(lian)軋(ya)法和上(shang)引(yin)連(lian)(lian)鑄(zhu)(zhu)法。連(lian)(lian)鑄(zhu)(zhu)連(lian)(lian)軋(ya)低氧(yang)銅(tong)(tong)桿(gan)的生(sheng)產(chan)方(fang)法較多(duo),其特點是(shi)金(jin)屬在豎爐中融(rong)化(hua)(hua)后,銅(tong)(tong)液通過(guo)保溫(wen)爐、溜槽、中間(jian)包,從澆管(guan)進(jin)(jin)入封閉的模腔(qiang)內(nei)(nei),采(cai)用(yong)較大(da)(da)的冷(leng)卻(que)強度進(jin)(jin)行冷(leng)卻(que),形成鑄(zhu)(zhu)坯,然后進(jin)(jin)行多(duo)道次軋(ya)制,生(sheng)產(chan)的低氧(yang)銅(tong)(tong)桿(gan)為(wei)(wei)熱加工組(zu)織(zhi)(zhi),原來的鑄(zhu)(zhu)造(zao)(zao)(zao)組(zu)織(zhi)(zhi)已經破碎,含(han)氧(yang)量(liang)一般為(wei)(wei)200~400ppm之間(jian)。無(wu)氧(yang)銅(tong)(tong)桿(gan)國內(nei)(nei)基本全部采(cai)用(yong)上(shang)引(yin)連(lian)(lian)鑄(zhu)(zhu)法生(sheng)產(chan),金(jin)屬在感應(ying)電爐中融(rong)化(hua)(hua)后通過(guo)石墨模進(jin)(jin)行上(shang)引(yin)連(lian)(lian)續鑄(zhu)(zhu)造(zao)(zao)(zao),之后進(jin)(jin)行冷(leng)軋(ya)或冷(leng)加工,生(sheng)產(chan)的無(wu)氧(yang)銅(tong)(tong)桿(gan)為(wei)(wei)鑄(zhu)(zhu)造(zao)(zao)(zao)組(zu)織(zhi)(zhi),含(han)氧(yang)量(liang)一般在20ppm以(yi)下。由于制造(zao)(zao)(zao)工藝的不同,所以(yi)在組(zu)織(zhi)(zhi)結構(gou)、氧(yang)含(han)量(liang)分布、雜(za)質的形式及分布等諸(zhu)多(duo)方(fang)面有(you)較大(da)(da)差別。
一、拉制性能
銅桿(gan)的(de)拉(la)制性能跟很多因素(su)有關,如雜質的(de)含(han)量(liang)、氧含(han)量(liang)及分布、工藝控制等。下(xia)面分別從以上幾個(ge)方面對銅桿(gan)的(de)拉(la)制性能進行分析(xi)。
1、熔化方(fang)式對S等雜質的影(ying)響
連鑄(zhu)連軋生(sheng)(sheng)產銅(tong)(tong)(tong)桿(gan)主(zhu)要(yao)是通過(guo)氣體的(de)燃燒(shao)使銅(tong)(tong)(tong)桿(gan)熔(rong)(rong)化(hua),在燃燒(shao)的(de)過(guo)程(cheng)中,通過(guo)氧化(hua)和揮發作用,可一定程(cheng)度(du)減少部(bu)分雜質(zhi)進(jin)入(ru)銅(tong)(tong)(tong)液(ye),因(yin)此連鑄(zhu)連軋法(fa)對原(yuan)料要(yao)求相對低一些。上引連鑄(zhu)生(sheng)(sheng)產無(wu)氧銅(tong)(tong)(tong)桿(gan),由于是用感應電(dian)爐熔(rong)(rong)化(hua),電(dian)解銅(tong)(tong)(tong)表面的(de)“銅(tong)(tong)(tong)綠(lv)”“銅(tong)(tong)(tong)豆”基本都熔(rong)(rong)入(ru)到銅(tong)(tong)(tong)液(ye)中。其(qi)中熔(rong)(rong)入(ru)的(de)S對無(wu)氧銅(tong)(tong)(tong)桿(gan)塑性影響極大,會增加拉(la)絲(si)斷線率。
2、鑄造過程中雜(za)質的進入
在(zai)生(sheng)產過程中(zhong)(zhong)(zhong),連(lian)鑄連(lian)軋工藝(yi)需(xu)通(tong)過保溫爐、溜槽、中(zhong)(zhong)(zhong)間包轉運銅液(ye),相對(dui)容易造(zao)(zao)成(cheng)(cheng)(cheng)耐(nai)火材(cai)料(liao)的(de)(de)剝(bo)落(luo),在(zai)軋制過程中(zhong)(zhong)(zhong)需(xu)要通(tong)過軋輥,造(zao)(zao)成(cheng)(cheng)(cheng)鐵質(zhi)的(de)(de)脫落(luo),會給銅桿造(zao)(zao)成(cheng)(cheng)(cheng)外部(bu)夾雜(za)。而熱軋中(zhong)(zhong)(zhong)皮(pi)上和皮(pi)下(xia)氧化物的(de)(de)軋入,會給低氧桿的(de)(de)拉絲造(zao)(zao)成(cheng)(cheng)(cheng)不(bu)利的(de)(de)影響。上引(yin)連(lian)鑄法生(sheng)產工藝(yi)流程較(jiao)短,銅液(ye)是(shi)通(tong)過聯體爐內潛流式完成(cheng)(cheng)(cheng),對(dui)耐(nai)火材(cai)料(liao)的(de)(de)沖擊(ji)不(bu)大,結晶是(shi)通(tong)過石墨模內進行,所以(yi)過程中(zhong)(zhong)(zhong)可(ke)能產生(sheng)的(de)(de)污染源較(jiao)少,雜(za)質(zhi)進入的(de)(de)機(ji)會較(jiao)少。
O、S、P是與銅(tong)(tong)(tong)會(hui)生產化合物的元素。在熔(rong)態銅(tong)(tong)(tong)中(zhong),氧(yang)(yang)可(ke)以溶(rong)解(jie)一部分,但當(dang)銅(tong)(tong)(tong)冷凝時(shi),氧(yang)(yang)幾乎(hu)不溶(rong)解(jie)于銅(tong)(tong)(tong)中(zhong)。熔(rong)態時(shi)所(suo)溶(rong)解(jie)的氧(yang)(yang),以銅(tong)(tong)(tong)=氧(yang)(yang)化亞銅(tong)(tong)(tong)共晶體(ti)析出(chu),分布在晶粒晶界處。銅(tong)(tong)(tong)-氧(yang)(yang)化亞銅(tong)(tong)(tong)共晶體(ti)的出(chu)現,顯著降低了銅(tong)(tong)(tong)的塑性。
硫可以(yi)溶(rong)解在熔體的(de)銅中(zhong),但在室溫下(xia),其溶(rong)解度幾乎降(jiang)低到(dao)零,它(ta)以(yi)硫化亞銅的(de)形式(shi)出現在晶粒晶界處,會顯(xian)著降(jiang)低銅的(de)塑性。
3、氧在低氧銅(tong)桿和(he)無氧銅(tong)桿中(zhong)分布形式及其影響
氧(yang)(yang)(yang)含(han)量對低氧(yang)(yang)(yang)銅桿的(de)(de)(de)(de)(de)(de)拉(la)線性能有著明顯的(de)(de)(de)(de)(de)(de)影(ying)響。當氧(yang)(yang)(yang)含(han)量增(zeng)加到(dao)最佳值時,銅桿的(de)(de)(de)(de)(de)(de)斷線率最低。這是(shi)因(yin)為氧(yang)(yang)(yang)在與(yu)大部分雜質(zhi)反應的(de)(de)(de)(de)(de)(de)過程(cheng)中都起到(dao)了清(qing)除器的(de)(de)(de)(de)(de)(de)作用。適度的(de)(de)(de)(de)(de)(de)氧(yang)(yang)(yang)還(huan)有利于(yu)去除銅液中的(de)(de)(de)(de)(de)(de)氫,生成水蒸氣溢出,減少氣孔(kong)的(de)(de)(de)(de)(de)(de)形成。最佳的(de)(de)(de)(de)(de)(de)氧(yang)(yang)(yang)含(han)量為拉(la)線工藝提供了最好的(de)(de)(de)(de)(de)(de)條件。
低(di)氧銅(tong)桿(gan)氧化(hua)(hua)物(wu)的(de)分(fen)(fen)(fen)布(bu)(bu):在連(lian)續澆(jiao)鑄中凝固的(de)最(zui)初(chu)階段,散(san)熱(re)速率和均勻冷卻是決定銅(tong)桿(gan)氧化(hua)(hua)物(wu)分(fen)(fen)(fen)布(bu)(bu)的(de)主要因素。不(bu)均勻冷卻會(hui)引起(qi)銅(tong)桿(gan)內部(bu)結構本(ben)質上(shang)的(de)差(cha)異,但后續的(de)熱(re)加工,柱狀晶(jing)通常會(hui)遭到破壞,使(shi)氧化(hua)(hua)亞銅(tong)顆(ke)(ke)粒(li)細微化(hua)(hua)和均勻分(fen)(fen)(fen)布(bu)(bu)。氧化(hua)(hua)物(wu)顆(ke)(ke)粒(li)聚集(ji)而產生的(de)典型情況(kuang)是中心爆裂。除(chu)氧化(hua)(hua)物(wu)顆(ke)(ke)粒(li)分(fen)(fen)(fen)布(bu)(bu)的(de)影響外(wai),具(ju)有較(jiao)小氧化(hua)(hua)物(wu)顆(ke)(ke)粒(li)的(de)銅(tong)桿(gan)顯示出較(jiao)好的(de)拉(la)線特性,較(jiao)大(da)的(de)Cu2O顆(ke)(ke)粒(li)容(rong)易造(zao)成(cheng)應力集(ji)中點(dian)而斷(duan)裂。
無氧銅(tong)含氧量(liang)超標,銅(tong)桿(gan)變脆(cui)(cui),延伸率(lv)下(xia)降,拉(la)伸式樣(yang)端(duan)口顯暗紅色,結晶組織疏松。當氧含量(liang)超出8ppm時,工藝性(xing)能(neng)變差,表現為鑄造及(ji)拉(la)伸過程中(zhong)斷桿(gan)及(ji)斷線率(lv)極具增高。這是(shi)由于(yu)氧能(neng)與(yu)銅(tong)生成(cheng)氧化亞銅(tong)脆(cui)(cui)性(xing)相,形成(cheng)銅(tong)-氧化亞銅(tong)共晶體(ti),以網狀組織分布在境界上。這種脆(cui)(cui)性(xing)相硬度高,在冷變形時將會與(yu)銅(tong)機(ji)體(ti)脫(tuo)離,導(dao)致銅(tong)桿(gan)的機(ji)械性(xing)能(neng)下(xia)降,在后續加工中(zhong)容易造成(cheng)斷裂現象。氧含量(liang)高還能(neng)導(dao)致無氧銅(tong)桿(gan)導(dao)電率(lv)下(xia)降。因此,必須嚴格控制上引連(lian)鑄工藝及(ji)產品質量(liang)。
4、氫的影響
在上引連鑄中(zhong),氧含量控制較低(di),氧化物的副作(zuo)用唄**降低(di),但氫的影響成為(wei)較顯(xian)著的問題。吸氣后(hou)熔(rong)體中(zhong)存在平衡反應(ying):H2O(g)=[O]+2[H];
氣(qi)(qi)體及疏松(song)是在(zai)結(jie)晶(jing)的(de)(de)(de)(de)過(guo)程(cheng)中(zhong),氫(qing)從過(guo)飽和的(de)(de)(de)(de)溶(rong)液中(zhong)析出(chu)(chu)并(bing)聚集而(er)形成(cheng)(cheng)(cheng)的(de)(de)(de)(de)。在(zai)結(jie)晶(jing)前(qian)析出(chu)(chu)的(de)(de)(de)(de)氫(qing)又可還原氧化亞銅而(er)生成(cheng)(cheng)(cheng)水氣(qi)(qi)泡。由于(yu)上(shang)引(yin)鑄(zhu)造(zao)的(de)(de)(de)(de)特點是銅液自上(shang)而(er)下的(de)(de)(de)(de)結(jie)晶(jing),形成(cheng)(cheng)(cheng)的(de)(de)(de)(de)液**形狀近(jin)似錐型。銅液結(jie)晶(jing)前(qian)析出(chu)(chu)的(de)(de)(de)(de)氣(qi)(qi)體在(zai)上(shang)浮過(guo)程(cheng)中(zhong)被堵(du)在(zai)凝(ning)固組織內,結(jie)晶(jing)時在(zai)鑄(zhu)桿內形成(cheng)(cheng)(cheng)氣(qi)(qi)孔(kong)。上(shang)引(yin)的(de)(de)(de)(de)含(han)氣(qi)(qi)量(liang)少時,析出(chu)(chu)的(de)(de)(de)(de)氫(qing)存在(zai)于(yu)晶(jing)界處,形成(cheng)(cheng)(cheng)疏松(song);含(han)氣(qi)(qi)量(liang)多(duo)時,則聚集成(cheng)(cheng)(cheng)氣(qi)(qi)孔(kong),因此(ci),氣(qi)(qi)孔(kong)和疏松(song)是氫(qing)氣(qi)(qi)和水蒸氣(qi)(qi)兩者形成(cheng)(cheng)(cheng)的(de)(de)(de)(de)。
氫來(lai)源于(yu)上引生產過程中(zhong)的(de)各個工藝環節,如原料(liao)電(dian)(dian)解(jie)銅(tong)(tong)的(de)“銅(tong)(tong)綠”、輔料(liao)木炭**、氣候(hou)環境**、石墨結(jie)晶器未(wei)干燥等。因此,熔化爐(lu)中(zhong)的(de)銅(tong)(tong)液表面應覆蓋經烘烤的(de)木炭,電(dian)(dian)解(jie)銅(tong)(tong)應盡量去(qu)除(chu)“銅(tong)(tong)綠”、“銅(tong)(tong)豆”“耳(er)朵(duo)”,對提高(gao)無氧銅(tong)(tong)桿質量非常(chang)重要(yao)。
在連(lian)鑄(zhu)連(lian)軋(ya)工藝(yi)中(zhong),往往采用適(shi)度控(kong)制(zhi)氧含量(liang)來控(kong)制(zhi)氫(qing)。Cu2O+ H2= 2Cu+ H2O
由(you)于銅液在鑄造過程中是自下而上(shang)結晶(jing),銅液中的(de)(de)(de)氧和氫所產生的(de)(de)(de)水蒸氣(qi)很容(rong)易上(shang)浮跑出,銅液中的(de)(de)(de)氫大部分能被有效去除,因(yin)而對銅桿的(de)(de)(de)影響較(jiao)小(xiao)。
二、表面質量
在生(sheng)產電磁線等產品的過(guo)程(cheng)中(zhong),對銅桿(gan)的表面(mian)質(zhi)(zhi)量也需提(ti)出要求(qiu)。需要拉制后(hou)的銅絲(si)表面(mian)無毛刺、銅粉少、無油污(wu)。并通過(guo)扭轉(zhuan)(zhuan)試驗(yan)測量表面(mian)銅粉的質(zhi)(zhi)量和扭轉(zhuan)(zhuan)后(hou)觀(guan)察銅桿(gan)的復原情(qing)況來判定(ding)其好壞。
在連(lian)鑄連(lian)軋(ya)(ya)過(guo)程中,從(cong)鑄造(zao)到軋(ya)(ya)制(zhi)前,溫度高,完全暴露(lu)于空氣中,使鑄坯表(biao)面(mian)形成(cheng)較(jiao)厚的(de)(de)(de)氧(yang)(yang)(yang)化(hua)層,在軋(ya)(ya)制(zhi)過(guo)程中,隨著軋(ya)(ya)輥(gun)的(de)(de)(de)轉動,氧(yang)(yang)(yang)化(hua)物(wu)(wu)顆粒軋(ya)(ya)入銅(tong)線表(biao)面(mian)。由于氧(yang)(yang)(yang)化(hua)亞(ya)銅(tong)是(shi)高熔(rong)點(dian)脆性化(hua)合(he)物(wu)(wu),對于軋(ya)(ya)入較(jiao)深的(de)(de)(de)氧(yang)(yang)(yang)化(hua)亞(ya)銅(tong),當成(cheng)條狀的(de)(de)(de)聚集(ji)物(wu)(wu)遇模具拉伸時(shi),就會是(shi)銅(tong)桿(gan)外表(biao)面(mian)產生毛刺,給后續(xu)的(de)(de)(de)涂漆造(zao)成(cheng)麻煩。
而上引(yin)連鑄工藝制(zhi)造的無氧(yang)銅桿,由于鑄造和冷卻完(wan)全與(yu)氧(yang)隔絕,后續(xu)亦(yi)無熱(re)軋(ya)過程(cheng),銅桿表面(mian)無軋(ya)入表面(mian)的氧(yang)化(hua)物,質量較(jiao)好,拉制(zhi)后銅粉少,上述問題(ti)較(jiao)少存在。
無(wu)氧銅桿也(ye)分進(jin)(jin)口(kou)設備做的(de)(de)(de)和國產(chan)設備做的(de)(de)(de),但目(mu)前進(jin)(jin)口(kou)產(chan)品(pin)已無(wu)明顯優勢,銅桿產(chan)品(pin)出來后區(qu)別不是很(hen)大,只要銅板選的(de)(de)(de)好(hao),生產(chan)控制比較穩定(ding),國產(chan)設備也(ye)能產(chan)出可(ke)拉伸0.05的(de)(de)(de)銅桿.進(jin)(jin)口(kou)設備一般(ban)是芬蘭(lan)奧托昆普的(de)(de)(de)設備,國產(chan)設備最好(hao)的(de)(de)(de)應該是上(shang)海(hai)的(de)(de)(de)海(hai)軍廠(chang)的(de)(de)(de)了,生產(chan)時間最長,軍工企業,質量可(ke)靠。
低氧銅桿進口設備(bei)國際(ji)主(zhu)要有兩種(zhong)(zhong),一種(zhong)(zhong)是美(mei)國南線設備(bei),英文是SOUTHWIRE,國內廠(chang)家(jia)是南京華新(xin),江西(xi)銅業(ye),另一種(zhong)(zhong)是德國CONTIROD設備(bei),國內廠(chang)家(jia)是常州(zhou)金(jin)源,天津大無(wu)縫。
無(wu)(wu)氧(yang)(yang)(yang)(yang)(yang)及(ji)低(di)(di)(di)氧(yang)(yang)(yang)(yang)(yang)桿(gan)從含氧(yang)(yang)(yang)(yang)(yang)量(liang)上容(rong)易區別,無(wu)(wu)氧(yang)(yang)(yang)(yang)(yang)銅是含氧(yang)(yang)(yang)(yang)(yang)量(liang)在(zai)10-20個PPM以(yi)下(xia),但(dan)目前有的(de)(de)(de)廠家只能(neng)做(zuo)到50個PPM以(yi)下(xia).低(di)(di)(di)氧(yang)(yang)(yang)(yang)(yang)銅桿(gan)在(zai) 200-400個PPM,好(hao)(hao)的(de)(de)(de)桿(gan)子一般(ban)含氧(yang)(yang)(yang)(yang)(yang)量(liang)控(kong)制(zhi)在(zai)250個PPM左右,無(wu)(wu)氧(yang)(yang)(yang)(yang)(yang)桿(gan)一般(ban)采取的(de)(de)(de)是上引法,低(di)(di)(di)氧(yang)(yang)(yang)(yang)(yang)桿(gan)是連鑄連軋,兩(liang)種產(chan)品相對(dui)而(er)言低(di)(di)(di)氧(yang)(yang)(yang)(yang)(yang)桿(gan)對(dui)漆包線(xian)(xian)性 能(neng)更適應些,如(ru)柔(rou)軟性,回彈角(jiao),繞線(xian)(xian)性能(neng).但(dan)低(di)(di)(di)氧(yang)(yang)(yang)(yang)(yang)桿(gan)對(dui)拉絲條(tiao)件相對(dui)要(yao)苛刻些,同(tong)樣(yang)(yang)拉伸0.2的(de)(de)(de)細絲,如(ru)果(guo)伸線(xian)(xian)條(tiao)件不好(hao)(hao),普(pu)通(tong)的(de)(de)(de)無(wu)(wu)氧(yang)(yang)(yang)(yang)(yang)桿(gan)可拉而(er)好(hao)(hao)的(de)(de)(de)低(di)(di)(di)氧(yang)(yang)(yang)(yang)(yang)桿(gan)就斷 線(xian)(xian),但(dan)如(ru)果(guo)放在(zai)好(hao)(hao)的(de)(de)(de)伸線(xian)(xian)條(tiao)件,同(tong)樣(yang)(yang)的(de)(de)(de)桿(gan)子,低(di)(di)(di)氧(yang)(yang)(yang)(yang)(yang)桿(gan)說不定(ding)就能(neng)拉到雙(shuang)零五,而(er)普(pu)通(tong)無(wu)(wu)氧(yang)(yang)(yang)(yang)(yang)桿(gan)最多只能(neng)拉伸到0.1而(er)已,當然做(zuo)的(de)(de)(de)最細的(de)(de)(de)如(ru)雙(shuang)零二卻非(fei)得依靠進口的(de)(de)(de) 無(wu)(wu)氧(yang)(yang)(yang)(yang)(yang)銅桿(gan)了.目前有企業嘗試用(yong)剝皮的(de)(de)(de)方(fang)式來處(chu)理低(di)(di)(di)氧(yang)(yang)(yang)(yang)(yang)桿(gan)來伸0.03線(xian)(xian).但(dan)有關這方(fang)面的(de)(de)(de)內(nei)容(rong)我還不是很清楚(chu)。
音響線一般反而(er)喜歡用無氧桿(gan),這和無氧桿(gan)是單(dan)晶(jing)銅,低氧桿(gan)是多(duo)晶(jing)銅有關。
氧(yang)銅(tong)桿(gan)和無(wu)氧(yang)銅(tong)桿(gan)由于制造方法的不同,致使(shi)存(cun)在差(cha)別,具有各自的特點。
一、關于(yu)氧的吸入和脫去以及(ji)它的存(cun)在狀(zhuang)態
生產銅(tong)(tong)桿(gan)(gan)的(de)(de)(de)(de)陰極銅(tong)(tong)的(de)(de)(de)(de)含氧(yang)(yang)(yang)(yang)量一般在(zai)(zai)(zai)10—50ppm,在(zai)(zai)(zai)常溫下氧(yang)(yang)(yang)(yang)在(zai)(zai)(zai)銅(tong)(tong)中(zhong)(zhong)的(de)(de)(de)(de)固溶(rong)度約2ppm。低氧(yang)(yang)(yang)(yang)銅(tong)(tong)桿(gan)(gan)的(de)(de)(de)(de)含氧(yang)(yang)(yang)(yang)量一般在(zai)(zai)(zai)200(175)—400(450)ppm,因此氧(yang)(yang)(yang)(yang)的(de)(de)(de)(de)進入是(shi)在(zai)(zai)(zai)銅(tong)(tong)的(de)(de)(de)(de)液(ye)態(tai)下吸入的(de)(de)(de)(de),而(er)上引(yin)法無(wu)氧(yang)(yang)(yang)(yang)銅(tong)(tong)桿(gan)(gan)則(ze)相(xiang)反(fan),氧(yang)(yang)(yang)(yang)在(zai)(zai)(zai)液(ye)態(tai)銅(tong)(tong)下保持相(xiang)當時間(jian)后,被還原(yuan)而(er)脫去,通常這(zhe)種桿(gan)(gan)的(de)(de)(de)(de)含氧(yang)(yang)(yang)(yang)量都在(zai)(zai)(zai)10—50ppm以(yi)下,最(zui)低可達1-2ppm,從組織上看,低氧(yang)(yang)(yang)(yang)銅(tong)(tong)中(zhong)(zhong)的(de)(de)(de)(de)氧(yang)(yang)(yang)(yang),以(yi)氧(yang)(yang)(yang)(yang)化銅(tong)(tong)狀(zhuang)態(tai),存在(zai)(zai)(zai)于晶粒邊界(jie)附近,這(zhe)對(dui)低氧(yang)(yang)(yang)(yang)銅(tong)(tong)桿(gan)(gan)而(er)言(yan)可以(yi)說是(shi)常見的(de)(de)(de)(de)但(dan)對(dui)無(wu)氧(yang)(yang)(yang)(yang)銅(tong)(tong)桿(gan)(gan)則(ze)很少見。氧(yang)(yang)(yang)(yang)化銅(tong)(tong)以(yi)夾雜形式(shi)在(zai)(zai)(zai)晶界(jie)出現對(dui)材料的(de)(de)(de)(de)韌(ren)性(xing)產生負面影響(xiang)。而(er)無(wu)氧(yang)(yang)(yang)(yang)銅(tong)(tong)中(zhong)(zhong)的(de)(de)(de)(de)氧(yang)(yang)(yang)(yang)很低,所以(yi)這(zhe)種銅(tong)(tong)的(de)(de)(de)(de)組織是(shi)均勻(yun)的(de)(de)(de)(de)單相(xiang)組織對(dui)韌(ren)性(xing)有利。在(zai)(zai)(zai)無(wu)氧(yang)(yang)(yang)(yang)銅(tong)(tong)桿(gan)(gan)中(zhong)(zhong)的(de)(de)(de)(de)多孔性(xing)是(shi)不常見的(de)(de)(de)(de),而(er)在(zai)(zai)(zai)低氧(yang)(yang)(yang)(yang)銅(tong)(tong)桿(gan)(gan)中(zhong)(zhong)則(ze)是(shi)常見的(de)(de)(de)(de)一種缺陷(xian)。
二(er)、熱(re)軋組織和鑄造組織的區別
低(di)氧(yang)(yang)(yang)銅(tong)(tong)(tong)(tong)桿(gan)(gan)(gan)由于經過熱(re)(re)軋,所以(yi)其組織屬(shu)熱(re)(re)加工組織,原(yuan)來的(de)(de)(de)(de)鑄(zhu)造(zao)組織已經破碎,在(zai)(zai)8mm的(de)(de)(de)(de)桿(gan)(gan)(gan)時(shi)已有再結晶(jing)(jing)的(de)(de)(de)(de)形式出現,而無(wu)氧(yang)(yang)(yang)銅(tong)(tong)(tong)(tong)桿(gan)(gan)(gan)屬(shu)鑄(zhu)造(zao)組織,晶(jing)(jing)粒(li)(li)(li)粗大(da),這(zhe)是為什么(me),無(wu)氧(yang)(yang)(yang)銅(tong)(tong)(tong)(tong)的(de)(de)(de)(de)再結晶(jing)(jing)溫度較(jiao)高,需要(yao)較(jiao)高退(tui)火(huo)溫度的(de)(de)(de)(de)固有原(yuan)因。這(zhe)是因為,再結晶(jing)(jing)發生在(zai)(zai)晶(jing)(jing)粒(li)(li)(li)邊界(jie)附近,無(wu)氧(yang)(yang)(yang)銅(tong)(tong)(tong)(tong)桿(gan)(gan)(gan)組織晶(jing)(jing)粒(li)(li)(li)粗大(da),晶(jing)(jing)粒(li)(li)(li)尺寸甚(shen)至能達幾個毫米,因而晶(jing)(jing)粒(li)(li)(li)邊界(jie)少,即使通過拉(la)制(zhi)(zhi)(zhi)變形,但晶(jing)(jing)粒(li)(li)(li)邊界(jie)相對低(di)氧(yang)(yang)(yang)銅(tong)(tong)(tong)(tong)桿(gan)(gan)(gan)還是較(jiao)少,所以(yi)需要(yao)較(jiao)高的(de)(de)(de)(de)退(tui)火(huo)功率。對無(wu)氧(yang)(yang)(yang)銅(tong)(tong)(tong)(tong)成功的(de)(de)(de)(de)退(tui)火(huo)要(yao)求是:由桿(gan)(gan)(gan)經拉(la)制(zhi)(zhi)(zhi),但尚(shang)未鑄(zhu)造(zao)組織的(de)(de)(de)(de)線時(shi)的(de)(de)(de)(de)第(di)一次退(tui)火(huo),其退(tui)火(huo)功率應比同樣情況的(de)(de)(de)(de)低(di)氧(yang)(yang)(yang)銅(tong)(tong)(tong)(tong)高10——15%。經繼續拉(la)制(zhi)(zhi)(zhi),在(zai)(zai)以(yi)后階段的(de)(de)(de)(de)退(tui)火(huo)功率應留(liu)有足夠的(de)(de)(de)(de)余量和(he)對低(di)氧(yang)(yang)(yang)銅(tong)(tong)(tong)(tong)和(he)無(wu)氧(yang)(yang)(yang)銅(tong)(tong)(tong)(tong)切實區別執行(xing)不(bu)同的(de)(de)(de)(de)退(tui)火(huo)工藝,以(yi)保證在(zai)(zai)制(zhi)(zhi)(zhi)品(pin)和(he)成品(pin)導線的(de)(de)(de)(de)柔軟性。
三、夾雜(za),氧含量波動,表面氧化物和(he)可(ke)能存在的(de)熱軋(ya)缺陷的(de)差別
無(wu)(wu)氧(yang)銅桿(gan)(gan)的(de)(de)(de)可拉(la)性在(zai)所有(you)線(xian)徑里與低氧(yang)銅桿(gan)(gan)相比(bi)(bi)都是優(you)越的(de)(de)(de),除(chu)上述組織原因(yin)外(wai),無(wu)(wu)氧(yang)銅桿(gan)(gan)夾雜少(shao),含氧(yang)量穩(wen)定,無(wu)(wu)熱軋(ya)可能(neng)產生(sheng)的(de)(de)(de)缺陷(xian),桿(gan)(gan)表氧(yang)化(hua)物(wu)厚(hou)度可達(da)≤15A。在(zai)連(lian)鑄連(lian)軋(ya)生(sheng)產過(guo)程中(zhong)如果(guo)工藝不(bu)穩(wen)定,對(dui)氧(yang)監控(kong)不(bu)嚴,含氧(yang)量不(bu)穩(wen)定將直(zhi)接(jie)影響桿(gan)(gan)的(de)(de)(de)性能(neng)。如果(guo)桿(gan)(gan)的(de)(de)(de)表面氧(yang)化(hua)物(wu)能(neng)在(zai)后工序的(de)(de)(de)連(lian)續清洗中(zhong)得以彌(mi)補(bu)外(wai),但比(bi)(bi)較麻煩(fan)的(de)(de)(de)是有(you)相當多的(de)(de)(de)氧(yang)化(hua)物(wu)存在(zai)于“皮(pi)(pi)下(xia)”,對(dui)拉(la)線(xian)斷線(xian)影響更直(zhi)接(jie),故而在(zai)拉(la)制微細線(xian),超微細線(xian)時,為了減少(shao)斷線(xian),有(you)時要(yao)對(dui)銅桿(gan)(gan)采取不(bu)得已的(de)(de)(de)辦法——剝皮(pi)(pi),甚至二次剝皮(pi)(pi)的(de)(de)(de)原因(yin)所在(zai),目的(de)(de)(de)要(yao)除(chu)去皮(pi)(pi)下(xia)氧(yang)化(hua)物(wu)。
四、低氧銅(tong)桿和(he)無氧銅(tong)桿的韌性有差別
兩(liang)者都可以拉(la)到0.015mm,但在低(di)溫(wen)超導線中的低(di)溫(wen)級無氧(yang)銅,其細絲間的間距只有0.001mm.
五、從制(zhi)桿的原材料到制(zhi)線的經(jing)濟(ji)性有(you)差別。
制(zhi)造無氧銅桿要求質量較(jiao)高的(de)(de)原材料。一般,拉制(zhi)直徑>1mm的(de)(de)銅線(xian)時,低氧銅桿的(de)(de)優點比(bi)較(jiao)明顯,而無氧銅桿顯得更為優越的(de)(de)是拉制(zhi)直徑<0.5mm的(de)(de)銅線(xian)。
六、低氧(yang)銅(tong)桿的制線工藝與無(wu)氧(yang)銅(tong)桿的有所(suo)不同。
低氧(yang)(yang)銅(tong)(tong)桿(gan)的制(zhi)線(xian)工(gong)藝(yi)不能(neng)照搬到無氧(yang)(yang)銅(tong)(tong)桿(gan)的制(zhi)線(xian)工(gong)藝(yi)上來,至少(shao)兩者的退火工(gong)藝(yi)是不同的。因為線(xian)的柔軟(ruan)性(xing)深受材料(liao)成份(fen)和(he)制(zhi)桿(gan),制(zhi)線(xian)和(he)退火工(gong)藝(yi)的影響,不能(neng)簡單地說低氧(yang)(yang)銅(tong)(tong)或無氧(yang)(yang)銅(tong)(tong)誰軟(ruan)誰硬(ying)。
下(xia)一條文圣如何分辨劣質線纜(電纜人必備)