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烏馬河電纜中的銅都是一樣的嗎?什么樣的是好銅?一篇文章解釋清楚

來源:行業動態(tai) 閱讀:109607 發(fa)布時(shi)間(jian):2019-07-05

導讀:由于生產(chan)銅(tong)(tong)桿的(de)(de)兩者的(de)(de)工藝不同(tong),所生產(chan)的(de)(de)銅(tong)(tong)桿中的(de)(de)含氧(yang)(yang)量(liang)及外觀就不同(tong)。上(shang)引生產(chan)的(de)(de)銅(tong)(tong)桿,工藝得(de)當(dang)氧(yang)(yang)含量(liang)在(zai)10ppm以(yi)下(xia),叫無氧(yang)(yang)銅(tong)(tong)桿;連(lian)鑄連(lian)鑄生產(chan)的(de)(de)銅(tong)(tong)桿 是在(zai)保(bao)護條件(jian)下(xia)的(de)(de)熱軋,氧(yang)(yang)含量(liang)在(zai)200-500ppm范(fan)圍內,但有時也高(gao)達700ppm以(yi)上(shang),一般情況下(xia),此種方法生產(chan)的(de)(de)銅(tong)(tong)外表光亮,低氧(yang)(yang)銅(tong)(tong)桿,有時也叫光桿。

銅(tong)(tong)桿(gan)是電纜行(xing)(xing)業的(de)(de)主(zhu)要原(yuan)料(liao),生產(chan)(chan)的(de)(de)方(fang)式主(zhu)要有兩種——連(lian)(lian)鑄(zhu)(zhu)連(lian)(lian)軋(ya)(ya)法(fa)和上(shang)引(yin)連(lian)(lian)鑄(zhu)(zhu)法(fa)。連(lian)(lian)鑄(zhu)(zhu)連(lian)(lian)軋(ya)(ya)低(di)(di)氧(yang)(yang)銅(tong)(tong)桿(gan)的(de)(de)生產(chan)(chan)方(fang)法(fa)較多(duo),其特點是金屬在(zai)豎爐(lu)中融化后,銅(tong)(tong)液通過保(bao)溫爐(lu)、溜(liu)槽、中間包,從澆管進(jin)入(ru)封閉的(de)(de)模腔內(nei),采用(yong)較大的(de)(de)冷(leng)(leng)卻(que)強度進(jin)行(xing)(xing)冷(leng)(leng)卻(que),形成(cheng)鑄(zhu)(zhu)坯,然后進(jin)行(xing)(xing)多(duo)道(dao)次(ci)軋(ya)(ya)制(zhi)(zhi),生產(chan)(chan)的(de)(de)低(di)(di)氧(yang)(yang)銅(tong)(tong)桿(gan)為熱加工組(zu)織(zhi),原(yuan)來的(de)(de)鑄(zhu)(zhu)造組(zu)織(zhi)已經(jing)破碎,含(han)氧(yang)(yang)量(liang)一(yi)般為200~400ppm之間。無(wu)(wu)氧(yang)(yang)銅(tong)(tong)桿(gan)國內(nei)基本全部采用(yong)上(shang)引(yin)連(lian)(lian)鑄(zhu)(zhu)法(fa)生產(chan)(chan),金屬在(zai)感(gan)應電爐(lu)中融化后通過石墨模進(jin)行(xing)(xing)上(shang)引(yin)連(lian)(lian)續鑄(zhu)(zhu)造,之后進(jin)行(xing)(xing)冷(leng)(leng)軋(ya)(ya)或(huo)冷(leng)(leng)加工,生產(chan)(chan)的(de)(de)無(wu)(wu)氧(yang)(yang)銅(tong)(tong)桿(gan)為鑄(zhu)(zhu)造組(zu)織(zhi),含(han)氧(yang)(yang)量(liang)一(yi)般在(zai)20ppm以下。由于制(zhi)(zhi)造工藝的(de)(de)不同(tong),所以在(zai)組(zu)織(zhi)結(jie)構、氧(yang)(yang)含(han)量(liang)分布、雜質(zhi)的(de)(de)形式及(ji)分布等諸多(duo)方(fang)面有較大差別。

一、拉制性能

銅桿的(de)(de)拉制性(xing)能跟很(hen)多因素有關(guan),如雜質的(de)(de)含(han)量(liang)、氧含(han)量(liang)及分布(bu)、工藝控(kong)制等。下面(mian)分別從(cong)以上幾個方面(mian)對銅桿的(de)(de)拉制性(xing)能進行分析(xi)。

1、熔化方式對S等雜質的影響

連鑄(zhu)(zhu)連軋(ya)生產銅(tong)(tong)桿主要是通過(guo)(guo)氣(qi)體的燃燒使銅(tong)(tong)桿熔(rong)化,在燃燒的過(guo)(guo)程(cheng)中,通過(guo)(guo)氧化和揮(hui)發作用,可一定程(cheng)度減(jian)少部分(fen)雜質進入銅(tong)(tong)液,因此連鑄(zhu)(zhu)連軋(ya)法對(dui)原料要求相對(dui)低一些。上引連鑄(zhu)(zhu)生產無氧銅(tong)(tong)桿,由(you)于是用感應電爐(lu)熔(rong)化,電解銅(tong)(tong)表面的“銅(tong)(tong)綠(lv)”“銅(tong)(tong)豆(dou)”基本(ben)都熔(rong)入到銅(tong)(tong)液中。其中熔(rong)入的S對(dui)無氧銅(tong)(tong)桿塑(su)性影響極大(da),會增加拉絲斷線率。

2、鑄造過程中(zhong)雜質的進入

在生(sheng)(sheng)產(chan)過(guo)程(cheng)中,連鑄連軋(ya)工藝需通過(guo)保溫(wen)爐(lu)、溜(liu)槽、中間包轉運銅液(ye),相(xiang)對(dui)容易造(zao)(zao)成(cheng)(cheng)(cheng)耐(nai)火材(cai)(cai)料的(de)(de)剝落,在軋(ya)制(zhi)過(guo)程(cheng)中需要通過(guo)軋(ya)輥,造(zao)(zao)成(cheng)(cheng)(cheng)鐵質的(de)(de)脫(tuo)落,會給銅桿造(zao)(zao)成(cheng)(cheng)(cheng)外部(bu)夾雜。而熱軋(ya)中皮上和皮下氧化物的(de)(de)軋(ya)入(ru),會給低氧桿的(de)(de)拉絲造(zao)(zao)成(cheng)(cheng)(cheng)不(bu)利的(de)(de)影響。上引(yin)連鑄法生(sheng)(sheng)產(chan)工藝流程(cheng)較短,銅液(ye)是通過(guo)聯(lian)體爐(lu)內(nei)潛(qian)流式完成(cheng)(cheng)(cheng),對(dui)耐(nai)火材(cai)(cai)料的(de)(de)沖(chong)擊不(bu)大(da),結(jie)晶是通過(guo)石(shi)墨模(mo)內(nei)進行(xing),所以過(guo)程(cheng)中可能產(chan)生(sheng)(sheng)的(de)(de)污(wu)染源較少,雜質進入(ru)的(de)(de)機會較少。

O、S、P是與銅會生產化合物的元素。在(zai)熔態(tai)銅中,氧(yang)(yang)(yang)可以(yi)溶解(jie)一部(bu)分,但當銅冷凝(ning)時,氧(yang)(yang)(yang)幾乎不(bu)溶解(jie)于(yu)銅中。熔態(tai)時所溶解(jie)的氧(yang)(yang)(yang),以(yi)銅=氧(yang)(yang)(yang)化亞銅共(gong)晶(jing)體(ti)析出,分布(bu)在(zai)晶(jing)粒晶(jing)界處。銅-氧(yang)(yang)(yang)化亞銅共(gong)晶(jing)體(ti)的出現,顯(xian)著降低了銅的塑性。

硫(liu)(liu)可以溶解在(zai)熔體(ti)的銅(tong)中,但在(zai)室(shi)溫下,其溶解度(du)幾乎降(jiang)低到(dao)零,它以硫(liu)(liu)化亞(ya)銅(tong)的形(xing)式出現在(zai)晶粒晶界處(chu),會顯著(zhu)降(jiang)低銅(tong)的塑性。

3、氧在低(di)氧銅桿和無(wu)氧銅桿中分布形式及其影響

氧(yang)(yang)含(han)量(liang)(liang)對(dui)低(di)氧(yang)(yang)銅(tong)桿(gan)的(de)(de)(de)(de)拉(la)線性(xing)能(neng)有(you)著明顯的(de)(de)(de)(de)影響。當氧(yang)(yang)含(han)量(liang)(liang)增加到最(zui)佳值時(shi),銅(tong)桿(gan)的(de)(de)(de)(de)斷線率最(zui)低(di)。這(zhe)是因為(wei)氧(yang)(yang)在(zai)與大部(bu)分雜(za)質反應的(de)(de)(de)(de)過程中(zhong)都(dou)起到了(le)清(qing)除(chu)器(qi)的(de)(de)(de)(de)作用。適(shi)度(du)的(de)(de)(de)(de)氧(yang)(yang)還有(you)利于去除(chu)銅(tong)液中(zhong)的(de)(de)(de)(de)氫(qing),生(sheng)成(cheng)水蒸(zheng)氣溢出,減少(shao)氣孔的(de)(de)(de)(de)形(xing)成(cheng)。最(zui)佳的(de)(de)(de)(de)氧(yang)(yang)含(han)量(liang)(liang)為(wei)拉(la)線工藝提供了(le)最(zui)好的(de)(de)(de)(de)條件。

低(di)氧(yang)銅(tong)(tong)(tong)桿(gan)氧(yang)化物(wu)(wu)的(de)(de)分布:在連續(xu)澆(jiao)鑄中凝固的(de)(de)最(zui)初階段,散熱速率和均勻(yun)冷(leng)卻是決定銅(tong)(tong)(tong)桿(gan)氧(yang)化物(wu)(wu)分布的(de)(de)主要(yao)因素。不均勻(yun)冷(leng)卻會引起銅(tong)(tong)(tong)桿(gan)內部結(jie)構本質上的(de)(de)差異(yi),但(dan)后(hou)續(xu)的(de)(de)熱加工,柱狀晶通常會遭(zao)到(dao)破壞(huai),使氧(yang)化亞銅(tong)(tong)(tong)顆(ke)粒細微化和均勻(yun)分布。氧(yang)化物(wu)(wu)顆(ke)粒聚集而(er)產生(sheng)的(de)(de)典(dian)型情況是中心爆裂(lie)。除氧(yang)化物(wu)(wu)顆(ke)粒分布的(de)(de)影響(xiang)外,具有較小(xiao)氧(yang)化物(wu)(wu)顆(ke)粒的(de)(de)銅(tong)(tong)(tong)桿(gan)顯示出較好的(de)(de)拉(la)線特性(xing),較大(da)的(de)(de)Cu2O顆(ke)粒容易造成應力集中點而(er)斷(duan)裂(lie)。

無氧(yang)銅(tong)含氧(yang)量(liang)(liang)(liang)超標,銅(tong)桿(gan)變(bian)脆(cui)(cui),延伸(shen)率下(xia)降(jiang),拉(la)伸(shen)式樣端口顯暗紅色,結(jie)晶組(zu)織疏(shu)松。當氧(yang)含量(liang)(liang)(liang)超出8ppm時(shi),工(gong)藝(yi)性(xing)能(neng)變(bian)差,表現(xian)為鑄造及(ji)(ji)拉(la)伸(shen)過程(cheng)中斷桿(gan)及(ji)(ji)斷線率極具增高。這是由于氧(yang)能(neng)與銅(tong)生成(cheng)氧(yang)化(hua)亞(ya)銅(tong)脆(cui)(cui)性(xing)相,形成(cheng)銅(tong)-氧(yang)化(hua)亞(ya)銅(tong)共晶體,以網狀組(zu)織分布在(zai)(zai)境界上。這種脆(cui)(cui)性(xing)相硬度高,在(zai)(zai)冷變(bian)形時(shi)將會與銅(tong)機體脫離(li),導致銅(tong)桿(gan)的機械性(xing)能(neng)下(xia)降(jiang),在(zai)(zai)后續加工(gong)中容易造成(cheng)斷裂現(xian)象。氧(yang)含量(liang)(liang)(liang)高還能(neng)導致無氧(yang)銅(tong)桿(gan)導電率下(xia)降(jiang)。因此,必須嚴格控制上引連鑄工(gong)藝(yi)及(ji)(ji)產品(pin)質量(liang)(liang)(liang)。

4、氫的影響

在上引連鑄中(zhong),氧含量(liang)控制較低,氧化物(wu)的(de)副作用唄(bai)**降低,但氫的(de)影響(xiang)成為較顯著的(de)問題。吸氣后熔(rong)體中(zhong)存在平衡反應(ying):H2O(g)=[O]+2[H];

氣(qi)(qi)體(ti)及(ji)疏松(song)是(shi)在(zai)結晶(jing)的(de)過(guo)程中(zhong),氫(qing)(qing)從過(guo)飽和的(de)溶液(ye)中(zhong)析出(chu)并(bing)聚集(ji)而(er)形(xing)成(cheng)(cheng)(cheng)的(de)。在(zai)結晶(jing)前(qian)析出(chu)的(de)氫(qing)(qing)又可(ke)還原氧化(hua)亞銅(tong)而(er)生成(cheng)(cheng)(cheng)水(shui)氣(qi)(qi)泡(pao)。由于(yu)(yu)上(shang)引鑄造的(de)特(te)點(dian)是(shi)銅(tong)液(ye)自上(shang)而(er)下的(de)結晶(jing),形(xing)成(cheng)(cheng)(cheng)的(de)液(ye)**形(xing)狀近似(si)錐型。銅(tong)液(ye)結晶(jing)前(qian)析出(chu)的(de)氣(qi)(qi)體(ti)在(zai)上(shang)浮(fu)過(guo)程中(zhong)被(bei)堵(du)在(zai)凝固組織內,結晶(jing)時(shi)在(zai)鑄桿內形(xing)成(cheng)(cheng)(cheng)氣(qi)(qi)孔。上(shang)引的(de)含氣(qi)(qi)量少時(shi),析出(chu)的(de)氫(qing)(qing)存在(zai)于(yu)(yu)晶(jing)界處(chu),形(xing)成(cheng)(cheng)(cheng)疏松(song);含氣(qi)(qi)量多時(shi),則聚集(ji)成(cheng)(cheng)(cheng)氣(qi)(qi)孔,因此,氣(qi)(qi)孔和疏松(song)是(shi)氫(qing)(qing)氣(qi)(qi)和水(shui)蒸氣(qi)(qi)兩者(zhe)形(xing)成(cheng)(cheng)(cheng)的(de)。

氫來源于上引生產(chan)過程中(zhong)的(de)各個工藝環(huan)節(jie),如原料電(dian)解銅(tong)的(de)“銅(tong)綠”、輔料木炭**、氣候環(huan)境**、石(shi)墨結晶器未干燥等(deng)。因此,熔化爐中(zhong)的(de)銅(tong)液表面應覆蓋經烘烤的(de)木炭,電(dian)解銅(tong)應盡量去除“銅(tong)綠”、“銅(tong)豆”“耳朵”,對(dui)提高無氧銅(tong)桿質(zhi)量非常重要(yao)。

在連鑄(zhu)連軋(ya)工藝中,往(wang)往(wang)采用適(shi)度控制氧含量來控制氫(qing)。Cu2O+ H2= 2Cu+ H2O

由于(yu)銅(tong)(tong)液在(zai)鑄(zhu)造過程中是(shi)自(zi)下而(er)(er)上結晶,銅(tong)(tong)液中的氧(yang)和氫(qing)(qing)所(suo)產生的水(shui)蒸氣很容易上浮跑出(chu),銅(tong)(tong)液中的氫(qing)(qing)大部分能被(bei)有效去除,因(yin)而(er)(er)對銅(tong)(tong)桿的影響(xiang)較(jiao)小。

二、表面質量

在生產(chan)電磁(ci)線等產(chan)品的過程中,對銅(tong)桿(gan)的表(biao)面(mian)質量(liang)也需(xu)提出要求。需(xu)要拉制后的銅(tong)絲表(biao)面(mian)無(wu)毛(mao)刺(ci)、銅(tong)粉(fen)少、無(wu)油(you)污。并通過扭(niu)轉試(shi)驗(yan)測(ce)量(liang)表(biao)面(mian)銅(tong)粉(fen)的質量(liang)和(he)扭(niu)轉后觀察(cha)銅(tong)桿(gan)的復原情(qing)況來判(pan)定(ding)其好(hao)壞。

在連(lian)鑄連(lian)軋(ya)(ya)過程中,從鑄造(zao)到軋(ya)(ya)制前,溫(wen)度(du)高,完全暴露于空氣(qi)中,使鑄坯表面形成(cheng)(cheng)較厚的氧化層(ceng),在軋(ya)(ya)制過程中,隨(sui)著軋(ya)(ya)輥(gun)的轉動,氧化物(wu)(wu)顆粒軋(ya)(ya)入銅(tong)線表面。由于氧化亞銅(tong)是高熔點脆性(xing)化合(he)物(wu)(wu),對于軋(ya)(ya)入較深的氧化亞銅(tong),當成(cheng)(cheng)條狀的聚(ju)集物(wu)(wu)遇模具(ju)拉伸時,就(jiu)會是銅(tong)桿外表面產生毛刺,給后續(xu)的涂漆(qi)造(zao)成(cheng)(cheng)麻煩。

而(er)上(shang)引連鑄(zhu)(zhu)工(gong)藝制造的無氧銅(tong)桿,由于鑄(zhu)(zhu)造和冷卻完全與氧隔絕,后(hou)(hou)續亦(yi)無熱軋過程,銅(tong)桿表面無軋入表面的氧化物,質量較(jiao)好(hao),拉制后(hou)(hou)銅(tong)粉少(shao),上(shang)述(shu)問題較(jiao)少(shao)存在(zai)。

無氧銅桿(gan)也分進口(kou)(kou)設(she)(she)備(bei)(bei)做(zuo)的和國產(chan)設(she)(she)備(bei)(bei)做(zuo)的,但目(mu)前進口(kou)(kou)產(chan)品已無明顯優勢(shi),銅桿(gan)產(chan)品出來(lai)后區別不是(shi)很(hen)大(da),只要銅板選(xuan)的好(hao),生(sheng)產(chan)控制比較穩定(ding),國產(chan)設(she)(she)備(bei)(bei)也能產(chan)出可(ke)拉伸0.05的銅桿(gan).進口(kou)(kou)設(she)(she)備(bei)(bei)一般是(shi)芬蘭(lan)奧(ao)托昆普(pu)的設(she)(she)備(bei)(bei),國產(chan)設(she)(she)備(bei)(bei)最好(hao)的應該是(shi)上海的海軍(jun)廠的了,生(sheng)產(chan)時(shi)間最長,軍(jun)工企業,質(zhi)量(liang)可(ke)靠。

低氧銅(tong)桿(gan)進(jin)口(kou)設(she)備國(guo)(guo)際主要(yao)有兩種,一(yi)種是(shi)美國(guo)(guo)南(nan)線(xian)設(she)備,英(ying)文是(shi)SOUTHWIRE,國(guo)(guo)內廠家是(shi)南(nan)京華(hua)新(xin),江(jiang)西銅(tong)業,另一(yi)種是(shi)德國(guo)(guo)CONTIROD設(she)備,國(guo)(guo)內廠家是(shi)常州金(jin)源,天津大(da)無縫。

無(wu)(wu)(wu)氧(yang)(yang)(yang)(yang)(yang)(yang)(yang)及低(di)(di)氧(yang)(yang)(yang)(yang)(yang)(yang)(yang)桿(gan)從含氧(yang)(yang)(yang)(yang)(yang)(yang)(yang)量(liang)上(shang)容易(yi)區別,無(wu)(wu)(wu)氧(yang)(yang)(yang)(yang)(yang)(yang)(yang)銅(tong)(tong)是(shi)含氧(yang)(yang)(yang)(yang)(yang)(yang)(yang)量(liang)在10-20個(ge)(ge)PPM以下,但(dan)目前有(you)的(de)廠家(jia)只能(neng)做到(dao)50個(ge)(ge)PPM以下.低(di)(di)氧(yang)(yang)(yang)(yang)(yang)(yang)(yang)銅(tong)(tong)桿(gan)在 200-400個(ge)(ge)PPM,好(hao)(hao)的(de)桿(gan)子一般含氧(yang)(yang)(yang)(yang)(yang)(yang)(yang)量(liang)控制在250個(ge)(ge)PPM左右,無(wu)(wu)(wu)氧(yang)(yang)(yang)(yang)(yang)(yang)(yang)桿(gan)一般采取的(de)是(shi)上(shang)引法(fa),低(di)(di)氧(yang)(yang)(yang)(yang)(yang)(yang)(yang)桿(gan)是(shi)連鑄(zhu)連軋,兩種產品相(xiang)對(dui)而(er)言低(di)(di)氧(yang)(yang)(yang)(yang)(yang)(yang)(yang)桿(gan)對(dui)漆包(bao)線(xian)性 能(neng)更適應些,如(ru)(ru)柔軟性,回彈角,繞(rao)線(xian)性能(neng).但(dan)低(di)(di)氧(yang)(yang)(yang)(yang)(yang)(yang)(yang)桿(gan)對(dui)拉絲(si)條(tiao)(tiao)件相(xiang)對(dui)要苛刻些,同(tong)樣(yang)拉伸(shen)(shen)0.2的(de)細絲(si),如(ru)(ru)果(guo)伸(shen)(shen)線(xian)條(tiao)(tiao)件不好(hao)(hao),普(pu)通的(de)無(wu)(wu)(wu)氧(yang)(yang)(yang)(yang)(yang)(yang)(yang)桿(gan)可拉而(er)好(hao)(hao)的(de)低(di)(di)氧(yang)(yang)(yang)(yang)(yang)(yang)(yang)桿(gan)就斷 線(xian),但(dan)如(ru)(ru)果(guo)放在好(hao)(hao)的(de)伸(shen)(shen)線(xian)條(tiao)(tiao)件,同(tong)樣(yang)的(de)桿(gan)子,低(di)(di)氧(yang)(yang)(yang)(yang)(yang)(yang)(yang)桿(gan)說不定就能(neng)拉到(dao)雙零五(wu),而(er)普(pu)通無(wu)(wu)(wu)氧(yang)(yang)(yang)(yang)(yang)(yang)(yang)桿(gan)最多只能(neng)拉伸(shen)(shen)到(dao)0.1而(er)已,當然做的(de)最細的(de)如(ru)(ru)雙零二(er)卻非得(de)依靠進口的(de) 無(wu)(wu)(wu)氧(yang)(yang)(yang)(yang)(yang)(yang)(yang)銅(tong)(tong)桿(gan)了(le).目前有(you)企(qi)業嘗試用剝皮的(de)方(fang)式來處(chu)理低(di)(di)氧(yang)(yang)(yang)(yang)(yang)(yang)(yang)桿(gan)來伸(shen)(shen)0.03線(xian).但(dan)有(you)關這方(fang)面的(de)內容我還不是(shi)很清楚(chu)。

音響(xiang)線(xian)一(yi)般反而(er)喜(xi)歡用無氧(yang)桿(gan),這和(he)無氧(yang)桿(gan)是單晶(jing)銅,低氧(yang)桿(gan)是多晶(jing)銅有關。

氧(yang)銅(tong)(tong)桿和無氧(yang)銅(tong)(tong)桿由于制造(zao)方法的不同,致使存在差別,具(ju)有各(ge)自(zi)的特點。

一(yi)、關于氧的(de)吸入和脫去以(yi)及它的(de)存在狀(zhuang)態

生產(chan)銅(tong)(tong)(tong)(tong)桿(gan)(gan)的(de)(de)(de)陰極(ji)銅(tong)(tong)(tong)(tong)的(de)(de)(de)含(han)氧(yang)(yang)量(liang)(liang)一(yi)(yi)般(ban)在(zai)(zai)(zai)(zai)(zai)10—50ppm,在(zai)(zai)(zai)(zai)(zai)常(chang)溫下(xia)(xia)氧(yang)(yang)在(zai)(zai)(zai)(zai)(zai)銅(tong)(tong)(tong)(tong)中(zhong)的(de)(de)(de)固溶(rong)度約(yue)2ppm。低(di)氧(yang)(yang)銅(tong)(tong)(tong)(tong)桿(gan)(gan)的(de)(de)(de)含(han)氧(yang)(yang)量(liang)(liang)一(yi)(yi)般(ban)在(zai)(zai)(zai)(zai)(zai)200(175)—400(450)ppm,因此(ci)氧(yang)(yang)的(de)(de)(de)進入是在(zai)(zai)(zai)(zai)(zai)銅(tong)(tong)(tong)(tong)的(de)(de)(de)液態(tai)下(xia)(xia)吸入的(de)(de)(de),而(er)上(shang)引法無(wu)(wu)氧(yang)(yang)銅(tong)(tong)(tong)(tong)桿(gan)(gan)則(ze)(ze)相反,氧(yang)(yang)在(zai)(zai)(zai)(zai)(zai)液態(tai)銅(tong)(tong)(tong)(tong)下(xia)(xia)保持相當時間(jian)后(hou),被(bei)還原而(er)脫去,通(tong)常(chang)這(zhe)種(zhong)桿(gan)(gan)的(de)(de)(de)含(han)氧(yang)(yang)量(liang)(liang)都在(zai)(zai)(zai)(zai)(zai)10—50ppm以(yi)(yi)下(xia)(xia),最(zui)低(di)可達1-2ppm,從組織(zhi)上(shang)看,低(di)氧(yang)(yang)銅(tong)(tong)(tong)(tong)中(zhong)的(de)(de)(de)氧(yang)(yang),以(yi)(yi)氧(yang)(yang)化(hua)銅(tong)(tong)(tong)(tong)狀態(tai),存在(zai)(zai)(zai)(zai)(zai)于晶粒邊界(jie)(jie)附近,這(zhe)對(dui)低(di)氧(yang)(yang)銅(tong)(tong)(tong)(tong)桿(gan)(gan)而(er)言可以(yi)(yi)說是常(chang)見(jian)的(de)(de)(de)但對(dui)無(wu)(wu)氧(yang)(yang)銅(tong)(tong)(tong)(tong)桿(gan)(gan)則(ze)(ze)很少見(jian)。氧(yang)(yang)化(hua)銅(tong)(tong)(tong)(tong)以(yi)(yi)夾雜形式在(zai)(zai)(zai)(zai)(zai)晶界(jie)(jie)出現(xian)對(dui)材料的(de)(de)(de)韌性(xing)產(chan)生負面(mian)影響(xiang)。而(er)無(wu)(wu)氧(yang)(yang)銅(tong)(tong)(tong)(tong)中(zhong)的(de)(de)(de)氧(yang)(yang)很低(di),所(suo)以(yi)(yi)這(zhe)種(zhong)銅(tong)(tong)(tong)(tong)的(de)(de)(de)組織(zhi)是均勻的(de)(de)(de)單(dan)相組織(zhi)對(dui)韌性(xing)有利。在(zai)(zai)(zai)(zai)(zai)無(wu)(wu)氧(yang)(yang)銅(tong)(tong)(tong)(tong)桿(gan)(gan)中(zhong)的(de)(de)(de)多(duo)孔性(xing)是不(bu)常(chang)見(jian)的(de)(de)(de),而(er)在(zai)(zai)(zai)(zai)(zai)低(di)氧(yang)(yang)銅(tong)(tong)(tong)(tong)桿(gan)(gan)中(zhong)則(ze)(ze)是常(chang)見(jian)的(de)(de)(de)一(yi)(yi)種(zhong)缺(que)陷。

二、熱軋組織和(he)鑄造(zao)組織的(de)區別

低(di)(di)氧(yang)(yang)銅(tong)(tong)(tong)桿(gan)(gan)(gan)由于經過(guo)熱軋,所(suo)以(yi)其(qi)組織(zhi)屬熱加工(gong)組織(zhi),原來的(de)鑄造組織(zhi)已(yi)經破碎,在8mm的(de)桿(gan)(gan)(gan)時已(yi)有再(zai)(zai)結(jie)晶(jing)的(de)形(xing)式出現,而(er)無(wu)氧(yang)(yang)銅(tong)(tong)(tong)桿(gan)(gan)(gan)屬鑄造組織(zhi),晶(jing)粒(li)粗(cu)大,這(zhe)是為(wei)什(shen)么,無(wu)氧(yang)(yang)銅(tong)(tong)(tong)的(de)再(zai)(zai)結(jie)晶(jing)溫(wen)度較(jiao)(jiao)高(gao)(gao),需要(yao)較(jiao)(jiao)高(gao)(gao)退(tui)火(huo)(huo)(huo)溫(wen)度的(de)固(gu)有原因(yin)。這(zhe)是因(yin)為(wei),再(zai)(zai)結(jie)晶(jing)發生在晶(jing)粒(li)邊(bian)(bian)界附近,無(wu)氧(yang)(yang)銅(tong)(tong)(tong)桿(gan)(gan)(gan)組織(zhi)晶(jing)粒(li)粗(cu)大,晶(jing)粒(li)尺寸甚至能達(da)幾個(ge)毫米,因(yin)而(er)晶(jing)粒(li)邊(bian)(bian)界少,即使(shi)通過(guo)拉制變形(xing),但晶(jing)粒(li)邊(bian)(bian)界相(xiang)對低(di)(di)氧(yang)(yang)銅(tong)(tong)(tong)桿(gan)(gan)(gan)還是較(jiao)(jiao)少,所(suo)以(yi)需要(yao)較(jiao)(jiao)高(gao)(gao)的(de)退(tui)火(huo)(huo)(huo)功率。對無(wu)氧(yang)(yang)銅(tong)(tong)(tong)成功的(de)退(tui)火(huo)(huo)(huo)要(yao)求是:由桿(gan)(gan)(gan)經拉制,但尚未鑄造組織(zhi)的(de)線時的(de)第一(yi)次退(tui)火(huo)(huo)(huo),其(qi)退(tui)火(huo)(huo)(huo)功率應比(bi)同(tong)樣情況的(de)低(di)(di)氧(yang)(yang)銅(tong)(tong)(tong)高(gao)(gao)10——15%。經繼續拉制,在以(yi)后(hou)階段(duan)的(de)退(tui)火(huo)(huo)(huo)功率應留(liu)有足(zu)夠(gou)的(de)余量和(he)對低(di)(di)氧(yang)(yang)銅(tong)(tong)(tong)和(he)無(wu)氧(yang)(yang)銅(tong)(tong)(tong)切實區別執行(xing)不(bu)同(tong)的(de)退(tui)火(huo)(huo)(huo)工(gong)藝,以(yi)保證在制品和(he)成品導線的(de)柔軟性。

三、夾雜,氧含量波(bo)動,表面氧化物和(he)可能存在的熱軋缺陷的差別

無氧銅(tong)(tong)桿(gan)(gan)的(de)(de)(de)可拉性在(zai)(zai)(zai)所有線(xian)徑里與低氧銅(tong)(tong)桿(gan)(gan)相比(bi)都是優越的(de)(de)(de),除(chu)上(shang)述組織原因(yin)(yin)外,無氧銅(tong)(tong)桿(gan)(gan)夾雜少,含氧量(liang)穩(wen)定(ding),無熱軋(ya)可能產(chan)生(sheng)的(de)(de)(de)缺(que)陷,桿(gan)(gan)表氧化物厚(hou)度可達≤15A。在(zai)(zai)(zai)連鑄(zhu)連軋(ya)生(sheng)產(chan)過程(cheng)中如果(guo)工(gong)藝不穩(wen)定(ding),對氧監控不嚴(yan),含氧量(liang)不穩(wen)定(ding)將直接影響桿(gan)(gan)的(de)(de)(de)性能。如果(guo)桿(gan)(gan)的(de)(de)(de)表面(mian)氧化物能在(zai)(zai)(zai)后工(gong)序的(de)(de)(de)連續清洗(xi)中得(de)以彌補外,但比(bi)較麻煩的(de)(de)(de)是有相當多的(de)(de)(de)氧化物存在(zai)(zai)(zai)于“皮下(xia)”,對拉線(xian)斷線(xian)影響更直接,故而在(zai)(zai)(zai)拉制(zhi)微細線(xian),超微細線(xian)時(shi),為(wei)了減少斷線(xian),有時(shi)要對銅(tong)(tong)桿(gan)(gan)采取不得(de)已的(de)(de)(de)辦法——剝皮,甚至(zhi)二(er)次剝皮的(de)(de)(de)原因(yin)(yin)所在(zai)(zai)(zai),目(mu)的(de)(de)(de)要除(chu)去(qu)皮下(xia)氧化物。

四、低氧(yang)銅桿(gan)和無氧(yang)銅桿(gan)的韌性有差別(bie)

兩(liang)者都可(ke)以拉到0.015mm,但在低(di)溫超導線中的低(di)溫級(ji)無氧銅,其細絲間的間距只有0.001mm.

五、從制桿的原材料到(dao)制線(xian)的經(jing)濟(ji)性有差別。

制(zhi)造無(wu)氧(yang)(yang)銅桿要求(qiu)質量較高(gao)的原材料。一般,拉制(zhi)直徑(jing)>1mm的銅線時,低氧(yang)(yang)銅桿的優(you)點比較明顯,而無(wu)氧(yang)(yang)銅桿顯得更為優(you)越的是拉制(zhi)直徑(jing)<0.5mm的銅線。

六(liu)、低(di)氧銅桿的(de)制線工(gong)藝(yi)與無氧銅桿的(de)有所不同。

低氧(yang)銅桿(gan)的(de)制(zhi)線工藝不(bu)能(neng)照(zhao)搬(ban)到無(wu)氧(yang)銅桿(gan)的(de)制(zhi)線工藝上來,至少兩(liang)者的(de)退火工藝是不(bu)同的(de)。因為線的(de)柔軟性深受材料(liao)成份和(he)制(zhi)桿(gan),制(zhi)線和(he)退火工藝的(de)影(ying)響(xiang),不(bu)能(neng)簡(jian)單(dan)地說(shuo)低氧(yang)銅或無(wu)氧(yang)銅誰軟誰硬。