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百川歸(gui)海 沈(shen)陽(yang)中(zhong)小企業系(xi)列報(bao)道之(zhi)61(沈(shen)...
2019-07-05138-9810-2027
來源(yuan):行業(ye)動態 閱讀:109483 發布(bu)時(shi)間:2019-07-05
導讀:由于生產(chan)銅(tong)(tong)(tong)(tong)桿的(de)(de)兩者(zhe)的(de)(de)工(gong)(gong)藝不同(tong),所生產(chan)的(de)(de)銅(tong)(tong)(tong)(tong)桿中的(de)(de)含(han)(han)氧(yang)(yang)量及外(wai)觀就(jiu)不同(tong)。上引(yin)生產(chan)的(de)(de)銅(tong)(tong)(tong)(tong)桿,工(gong)(gong)藝得(de)當氧(yang)(yang)含(han)(han)量在(zai)10ppm以(yi)下(xia),叫無氧(yang)(yang)銅(tong)(tong)(tong)(tong)桿;連(lian)鑄連(lian)鑄生產(chan)的(de)(de)銅(tong)(tong)(tong)(tong)桿 是(shi)在(zai)保護(hu)條件下(xia)的(de)(de)熱(re)軋(ya),氧(yang)(yang)含(han)(han)量在(zai)200-500ppm范(fan)圍內,但有時(shi)也(ye)高(gao)達700ppm以(yi)上,一(yi)般情況下(xia),此(ci)種方法(fa)生產(chan)的(de)(de)銅(tong)(tong)(tong)(tong)外(wai)表光(guang)亮(liang),低氧(yang)(yang)銅(tong)(tong)(tong)(tong)桿,有時(shi)也(ye)叫光(guang)桿。
銅桿(gan)是電(dian)(dian)纜行(xing)(xing)業的(de)主要(yao)原(yuan)料,生(sheng)產(chan)的(de)方式(shi)(shi)主要(yao)有兩種(zhong)——連(lian)鑄(zhu)(zhu)(zhu)連(lian)軋(ya)法(fa)和(he)上(shang)(shang)引連(lian)鑄(zhu)(zhu)(zhu)法(fa)。連(lian)鑄(zhu)(zhu)(zhu)連(lian)軋(ya)低(di)氧(yang)(yang)(yang)(yang)銅桿(gan)的(de)生(sheng)產(chan)方法(fa)較(jiao)多(duo)(duo),其(qi)特點(dian)是金(jin)屬在(zai)豎(shu)爐(lu)中融化后(hou),銅液(ye)通過(guo)保溫(wen)爐(lu)、溜(liu)槽、中間(jian)包,從澆管進入(ru)封閉的(de)模腔(qiang)內,采用較(jiao)大(da)的(de)冷卻強度進行(xing)(xing)冷卻,形成鑄(zhu)(zhu)(zhu)坯,然后(hou)進行(xing)(xing)多(duo)(duo)道(dao)次(ci)軋(ya)制(zhi),生(sheng)產(chan)的(de)低(di)氧(yang)(yang)(yang)(yang)銅桿(gan)為(wei)熱(re)加工(gong)組(zu)織(zhi)(zhi),原(yuan)來的(de)鑄(zhu)(zhu)(zhu)造(zao)組(zu)織(zhi)(zhi)已經破碎,含氧(yang)(yang)(yang)(yang)量(liang)一(yi)般為(wei)200~400ppm之間(jian)。無氧(yang)(yang)(yang)(yang)銅桿(gan)國內基本全部采用上(shang)(shang)引連(lian)鑄(zhu)(zhu)(zhu)法(fa)生(sheng)產(chan),金(jin)屬在(zai)感應電(dian)(dian)爐(lu)中融化后(hou)通過(guo)石墨模進行(xing)(xing)上(shang)(shang)引連(lian)續鑄(zhu)(zhu)(zhu)造(zao),之后(hou)進行(xing)(xing)冷軋(ya)或(huo)冷加工(gong),生(sheng)產(chan)的(de)無氧(yang)(yang)(yang)(yang)銅桿(gan)為(wei)鑄(zhu)(zhu)(zhu)造(zao)組(zu)織(zhi)(zhi),含氧(yang)(yang)(yang)(yang)量(liang)一(yi)般在(zai)20ppm以下。由于制(zhi)造(zao)工(gong)藝的(de)不(bu)同(tong),所以在(zai)組(zu)織(zhi)(zhi)結構、氧(yang)(yang)(yang)(yang)含量(liang)分布、雜質的(de)形式(shi)(shi)及分布等(deng)諸多(duo)(duo)方面有較(jiao)大(da)差別。
一、拉制性能
銅(tong)桿的拉制性(xing)能(neng)跟很多因(yin)素(su)有關,如雜(za)質(zhi)的含(han)量、氧含(han)量及(ji)分(fen)布、工藝控制等。下面分(fen)別從以上(shang)幾個方面對(dui)銅(tong)桿的拉制性(xing)能(neng)進(jin)行(xing)分(fen)析。
1、熔化方式對(dui)S等(deng)雜質的影響(xiang)
連(lian)鑄連(lian)軋生產(chan)銅(tong)(tong)桿主要(yao)是(shi)通(tong)過(guo)氣體的燃燒(shao)使銅(tong)(tong)桿熔(rong)化(hua),在(zai)燃燒(shao)的過(guo)程(cheng)中(zhong),通(tong)過(guo)氧(yang)(yang)化(hua)和揮發作(zuo)用,可一(yi)定(ding)程(cheng)度減少(shao)部分雜(za)質進入(ru)銅(tong)(tong)液,因此連(lian)鑄連(lian)軋法(fa)對(dui)原料要(yao)求相(xiang)對(dui)低一(yi)些。上引連(lian)鑄生產(chan)無氧(yang)(yang)銅(tong)(tong)桿,由于是(shi)用感應電爐熔(rong)化(hua),電解銅(tong)(tong)表面的“銅(tong)(tong)綠(lv)”“銅(tong)(tong)豆(dou)”基本都(dou)熔(rong)入(ru)到銅(tong)(tong)液中(zhong)。其中(zhong)熔(rong)入(ru)的S對(dui)無氧(yang)(yang)銅(tong)(tong)桿塑性影響極大(da),會增加拉絲斷線率。
2、鑄造過程中(zhong)雜質的進入
在生(sheng)(sheng)產過程中,連(lian)鑄連(lian)軋(ya)工藝(yi)需通過保(bao)溫爐(lu)、溜槽(cao)、中間包轉(zhuan)運銅液(ye),相對(dui)容(rong)易造(zao)(zao)成(cheng)(cheng)耐(nai)火材料的剝落,在軋(ya)制(zhi)過程中需要通過軋(ya)輥,造(zao)(zao)成(cheng)(cheng)鐵質(zhi)的脫落,會(hui)給銅桿(gan)造(zao)(zao)成(cheng)(cheng)外部夾雜。而熱軋(ya)中皮上(shang)和皮下氧化物的軋(ya)入,會(hui)給低氧桿(gan)的拉絲造(zao)(zao)成(cheng)(cheng)不利的影響。上(shang)引連(lian)鑄法(fa)生(sheng)(sheng)產工藝(yi)流(liu)程較(jiao)短,銅液(ye)是通過聯體爐(lu)內潛流(liu)式完成(cheng)(cheng),對(dui)耐(nai)火材料的沖擊不大,結(jie)晶是通過石(shi)墨模內進行,所(suo)以過程中可能產生(sheng)(sheng)的污(wu)染源較(jiao)少,雜質(zhi)進入的機會(hui)較(jiao)少。
O、S、P是與銅(tong)會生產化合物(wu)的(de)元素。在熔態銅(tong)中,氧(yang)可以(yi)溶(rong)解(jie)一部分,但當銅(tong)冷(leng)凝(ning)時(shi),氧(yang)幾乎不溶(rong)解(jie)于銅(tong)中。熔態時(shi)所溶(rong)解(jie)的(de)氧(yang),以(yi)銅(tong)=氧(yang)化亞(ya)銅(tong)共晶(jing)(jing)體析出,分布在晶(jing)(jing)粒晶(jing)(jing)界處。銅(tong)-氧(yang)化亞(ya)銅(tong)共晶(jing)(jing)體的(de)出現,顯著(zhu)降(jiang)低了銅(tong)的(de)塑性(xing)。
硫可以(yi)溶(rong)(rong)解在(zai)熔體(ti)的銅中,但在(zai)室(shi)溫下,其(qi)溶(rong)(rong)解度幾乎降低到零,它以(yi)硫化亞銅的形(xing)式(shi)出現在(zai)晶粒晶界處,會顯著降低銅的塑性。
3、氧在低氧銅桿和無(wu)氧銅桿中分布形式(shi)及其影響
氧(yang)含(han)(han)量(liang)對低氧(yang)銅(tong)(tong)桿的(de)(de)拉(la)線性能(neng)有(you)著明顯的(de)(de)影響。當氧(yang)含(han)(han)量(liang)增加(jia)到最(zui)佳(jia)值時,銅(tong)(tong)桿的(de)(de)斷線率最(zui)低。這是因(yin)為氧(yang)在(zai)與大(da)部分雜質(zhi)反應的(de)(de)過程中(zhong)都起到了清除(chu)器的(de)(de)作用。適度的(de)(de)氧(yang)還有(you)利于去除(chu)銅(tong)(tong)液(ye)中(zhong)的(de)(de)氫,生成水蒸氣溢出(chu),減少氣孔的(de)(de)形成。最(zui)佳(jia)的(de)(de)氧(yang)含(han)(han)量(liang)為拉(la)線工藝提供了最(zui)好的(de)(de)條件(jian)。
低氧(yang)銅(tong)桿(gan)氧(yang)化物(wu)的分布(bu)(bu):在連續澆鑄中(zhong)凝固的最初階段,散熱(re)速率(lv)和均勻(yun)冷卻是(shi)決(jue)定(ding)銅(tong)桿(gan)氧(yang)化物(wu)分布(bu)(bu)的主要因素。不均勻(yun)冷卻會(hui)引起銅(tong)桿(gan)內部(bu)結構本質上(shang)的差異,但后續的熱(re)加工,柱狀晶通常會(hui)遭到破壞,使氧(yang)化亞銅(tong)顆(ke)粒(li)細微化和均勻(yun)分布(bu)(bu)。氧(yang)化物(wu)顆(ke)粒(li)聚集(ji)(ji)而產生的典型(xing)情況是(shi)中(zhong)心爆裂(lie)。除(chu)氧(yang)化物(wu)顆(ke)粒(li)分布(bu)(bu)的影響外,具有(you)較(jiao)小氧(yang)化物(wu)顆(ke)粒(li)的銅(tong)桿(gan)顯(xian)示出較(jiao)好的拉線特性,較(jiao)大的Cu2O顆(ke)粒(li)容易(yi)造成應(ying)力集(ji)(ji)中(zhong)點而斷裂(lie)。
無氧(yang)(yang)(yang)(yang)銅(tong)(tong)含(han)氧(yang)(yang)(yang)(yang)量(liang)(liang)(liang)超標,銅(tong)(tong)桿(gan)(gan)變脆(cui),延伸(shen)(shen)率(lv)下降,拉伸(shen)(shen)式樣端口顯暗紅色,結晶組織(zhi)疏松(song)。當氧(yang)(yang)(yang)(yang)含(han)量(liang)(liang)(liang)超出8ppm時,工(gong)藝性能變差,表(biao)現為鑄造(zao)及(ji)拉伸(shen)(shen)過程中斷桿(gan)(gan)及(ji)斷線率(lv)極具增高(gao)。這(zhe)是(shi)由于氧(yang)(yang)(yang)(yang)能與銅(tong)(tong)生(sheng)成(cheng)氧(yang)(yang)(yang)(yang)化亞(ya)銅(tong)(tong)脆(cui)性相,形成(cheng)銅(tong)(tong)-氧(yang)(yang)(yang)(yang)化亞(ya)銅(tong)(tong)共晶體,以網狀(zhuang)組織(zhi)分布在(zai)境界(jie)上。這(zhe)種脆(cui)性相硬(ying)度高(gao),在(zai)冷變形時將會與銅(tong)(tong)機(ji)體脫(tuo)離,導致銅(tong)(tong)桿(gan)(gan)的機(ji)械性能下降,在(zai)后續加工(gong)中容易造(zao)成(cheng)斷裂現象。氧(yang)(yang)(yang)(yang)含(han)量(liang)(liang)(liang)高(gao)還能導致無氧(yang)(yang)(yang)(yang)銅(tong)(tong)桿(gan)(gan)導電率(lv)下降。因(yin)此,必須嚴格(ge)控制(zhi)上引(yin)連鑄工(gong)藝及(ji)產(chan)品質量(liang)(liang)(liang)。
4、氫的影響
在上引連鑄中(zhong),氧含量(liang)控制較(jiao)低(di)(di),氧化(hua)物的副作用唄**降低(di)(di),但氫的影(ying)響成為較(jiao)顯(xian)著的問題。吸氣后熔體(ti)中(zhong)存在平衡反應:H2O(g)=[O]+2[H];
氣(qi)體(ti)及疏松(song)是(shi)在結(jie)(jie)晶(jing)(jing)的(de)(de)(de)過程中(zhong),氫(qing)(qing)從過飽和的(de)(de)(de)溶液(ye)(ye)中(zhong)析(xi)出(chu)并聚集而(er)形(xing)(xing)(xing)成(cheng)(cheng)(cheng)的(de)(de)(de)。在結(jie)(jie)晶(jing)(jing)前(qian)析(xi)出(chu)的(de)(de)(de)氫(qing)(qing)又可還原氧化亞銅而(er)生成(cheng)(cheng)(cheng)水(shui)氣(qi)泡。由(you)于上引鑄造的(de)(de)(de)特點是(shi)銅液(ye)(ye)自上而(er)下的(de)(de)(de)結(jie)(jie)晶(jing)(jing),形(xing)(xing)(xing)成(cheng)(cheng)(cheng)的(de)(de)(de)液(ye)(ye)**形(xing)(xing)(xing)狀(zhuang)近似(si)錐型。銅液(ye)(ye)結(jie)(jie)晶(jing)(jing)前(qian)析(xi)出(chu)的(de)(de)(de)氣(qi)體(ti)在上浮過程中(zhong)被堵在凝固組織內,結(jie)(jie)晶(jing)(jing)時在鑄桿內形(xing)(xing)(xing)成(cheng)(cheng)(cheng)氣(qi)孔(kong)。上引的(de)(de)(de)含(han)氣(qi)量少(shao)時,析(xi)出(chu)的(de)(de)(de)氫(qing)(qing)存在于晶(jing)(jing)界處,形(xing)(xing)(xing)成(cheng)(cheng)(cheng)疏松(song);含(han)氣(qi)量多時,則(ze)聚集成(cheng)(cheng)(cheng)氣(qi)孔(kong),因此,氣(qi)孔(kong)和疏松(song)是(shi)氫(qing)(qing)氣(qi)和水(shui)蒸氣(qi)兩者(zhe)形(xing)(xing)(xing)成(cheng)(cheng)(cheng)的(de)(de)(de)。
氫來源于(yu)上引生產過程中的各個工藝環節,如原(yuan)料(liao)電解銅(tong)(tong)的“銅(tong)(tong)綠(lv)”、輔料(liao)木(mu)炭**、氣候環境**、石墨結晶器未干燥等。因此,熔化爐中的銅(tong)(tong)液表面(mian)應(ying)覆蓋經烘(hong)烤的木(mu)炭,電解銅(tong)(tong)應(ying)盡量去除“銅(tong)(tong)綠(lv)”、“銅(tong)(tong)豆”“耳朵(duo)”,對(dui)提高無氧銅(tong)(tong)桿質量非常重要(yao)。
在(zai)連(lian)鑄連(lian)軋(ya)工藝中(zhong),往往采(cai)用適(shi)度控(kong)制(zhi)氧含量(liang)來(lai)控(kong)制(zhi)氫(qing)。Cu2O+ H2= 2Cu+ H2O
由于銅液(ye)在鑄造(zao)過程中是(shi)自下而上(shang)結(jie)晶(jing),銅液(ye)中的(de)(de)(de)氧和氫所產生(sheng)的(de)(de)(de)水蒸氣很容易上(shang)浮跑出,銅液(ye)中的(de)(de)(de)氫大(da)部(bu)分能(neng)被(bei)有效去除,因而對銅桿的(de)(de)(de)影響較小。
二、表面質量
在(zai)生產電磁線等產品的(de)過(guo)程中,對銅(tong)桿的(de)表(biao)面(mian)(mian)質量也需提出(chu)要(yao)求。需要(yao)拉制(zhi)后的(de)銅(tong)絲表(biao)面(mian)(mian)無(wu)毛(mao)刺、銅(tong)粉少、無(wu)油污。并通(tong)過(guo)扭(niu)轉試驗測量表(biao)面(mian)(mian)銅(tong)粉的(de)質量和扭(niu)轉后觀察銅(tong)桿的(de)復原情況來判定其好(hao)壞。
在連(lian)鑄(zhu)連(lian)軋(ya)(ya)過程中(zhong),從鑄(zhu)造到(dao)軋(ya)(ya)制前,溫度高(gao),完全(quan)暴露于(yu)空(kong)氣中(zhong),使鑄(zhu)坯表面形(xing)成較厚(hou)的氧(yang)化(hua)層,在軋(ya)(ya)制過程中(zhong),隨著軋(ya)(ya)輥的轉動,氧(yang)化(hua)物顆(ke)粒軋(ya)(ya)入銅(tong)(tong)線表面。由(you)于(yu)氧(yang)化(hua)亞(ya)銅(tong)(tong)是高(gao)熔點(dian)脆性化(hua)合物,對于(yu)軋(ya)(ya)入較深(shen)的氧(yang)化(hua)亞(ya)銅(tong)(tong),當成條狀的聚集物遇(yu)模具(ju)拉伸時,就(jiu)會是銅(tong)(tong)桿外表面產生毛(mao)刺(ci),給后續(xu)的涂漆造成麻煩。
而上(shang)引連(lian)鑄工藝制造(zao)的無氧銅(tong)桿(gan),由于(yu)鑄造(zao)和冷卻完全與氧隔絕,后續亦無熱軋過程(cheng),銅(tong)桿(gan)表面無軋入表面的氧化物(wu),質(zhi)量較(jiao)好,拉制后銅(tong)粉少,上(shang)述問題(ti)較(jiao)少存(cun)在。
無(wu)氧銅桿也分進口設(she)備(bei)做的(de)(de)和國(guo)(guo)(guo)產(chan)(chan)設(she)備(bei)做的(de)(de),但目前進口產(chan)(chan)品已無(wu)明顯(xian)優(you)勢,銅桿產(chan)(chan)品出(chu)來(lai)后區別不是很大(da),只要銅板選的(de)(de)好,生產(chan)(chan)控制比較穩(wen)定,國(guo)(guo)(guo)產(chan)(chan)設(she)備(bei)也能產(chan)(chan)出(chu)可拉伸(shen)0.05的(de)(de)銅桿.進口設(she)備(bei)一般是芬蘭奧托(tuo)昆普(pu)的(de)(de)設(she)備(bei),國(guo)(guo)(guo)產(chan)(chan)設(she)備(bei)最好的(de)(de)應該是上(shang)海(hai)的(de)(de)海(hai)軍廠的(de)(de)了(le),生產(chan)(chan)時間最長(chang),軍工企(qi)業,質量可靠。
低氧銅桿(gan)進口設(she)備國(guo)際主(zhu)要有兩種,一種是(shi)(shi)美國(guo)南(nan)線設(she)備,英文是(shi)(shi)SOUTHWIRE,國(guo)內廠家是(shi)(shi)南(nan)京(jing)華新,江西銅業,另(ling)一種是(shi)(shi)德國(guo)CONTIROD設(she)備,國(guo)內廠家是(shi)(shi)常州(zhou)金源,天津大(da)無縫。
無(wu)(wu)(wu)(wu)氧(yang)(yang)(yang)及低(di)(di)(di)(di)(di)氧(yang)(yang)(yang)桿(gan)(gan)(gan)(gan)從含氧(yang)(yang)(yang)量上(shang)容易區別,無(wu)(wu)(wu)(wu)氧(yang)(yang)(yang)銅是(shi)(shi)含氧(yang)(yang)(yang)量在(zai)10-20個(ge)PPM以(yi)下,但(dan)目前(qian)有(you)的(de)(de)廠家只能做(zuo)到50個(ge)PPM以(yi)下.低(di)(di)(di)(di)(di)氧(yang)(yang)(yang)銅桿(gan)(gan)(gan)(gan)在(zai) 200-400個(ge)PPM,好的(de)(de)桿(gan)(gan)(gan)(gan)子(zi)一(yi)般含氧(yang)(yang)(yang)量控(kong)制(zhi)在(zai)250個(ge)PPM左右(you),無(wu)(wu)(wu)(wu)氧(yang)(yang)(yang)桿(gan)(gan)(gan)(gan)一(yi)般采(cai)取的(de)(de)是(shi)(shi)上(shang)引法(fa),低(di)(di)(di)(di)(di)氧(yang)(yang)(yang)桿(gan)(gan)(gan)(gan)是(shi)(shi)連鑄連軋,兩種產品(pin)相對(dui)(dui)而(er)(er)言(yan)低(di)(di)(di)(di)(di)氧(yang)(yang)(yang)桿(gan)(gan)(gan)(gan)對(dui)(dui)漆包線(xian)(xian)性(xing) 能更適應些(xie),如柔(rou)軟性(xing),回彈角,繞線(xian)(xian)性(xing)能.但(dan)低(di)(di)(di)(di)(di)氧(yang)(yang)(yang)桿(gan)(gan)(gan)(gan)對(dui)(dui)拉(la)絲條件相對(dui)(dui)要苛(ke)刻些(xie),同樣(yang)拉(la)伸0.2的(de)(de)細(xi)(xi)絲,如果(guo)(guo)伸線(xian)(xian)條件不好,普(pu)通(tong)的(de)(de)無(wu)(wu)(wu)(wu)氧(yang)(yang)(yang)桿(gan)(gan)(gan)(gan)可拉(la)而(er)(er)好的(de)(de)低(di)(di)(di)(di)(di)氧(yang)(yang)(yang)桿(gan)(gan)(gan)(gan)就斷(duan) 線(xian)(xian),但(dan)如果(guo)(guo)放在(zai)好的(de)(de)伸線(xian)(xian)條件,同樣(yang)的(de)(de)桿(gan)(gan)(gan)(gan)子(zi),低(di)(di)(di)(di)(di)氧(yang)(yang)(yang)桿(gan)(gan)(gan)(gan)說(shuo)不定就能拉(la)到雙(shuang)零五(wu),而(er)(er)普(pu)通(tong)無(wu)(wu)(wu)(wu)氧(yang)(yang)(yang)桿(gan)(gan)(gan)(gan)最(zui)多只能拉(la)伸到0.1而(er)(er)已,當(dang)然做(zuo)的(de)(de)最(zui)細(xi)(xi)的(de)(de)如雙(shuang)零二卻非得依靠進口(kou)的(de)(de) 無(wu)(wu)(wu)(wu)氧(yang)(yang)(yang)銅桿(gan)(gan)(gan)(gan)了.目前(qian)有(you)企業嘗(chang)試用剝皮的(de)(de)方式(shi)來處(chu)理低(di)(di)(di)(di)(di)氧(yang)(yang)(yang)桿(gan)(gan)(gan)(gan)來伸0.03線(xian)(xian).但(dan)有(you)關這方面的(de)(de)內容我還(huan)不是(shi)(shi)很清(qing)楚。
音響線(xian)一般反而喜歡用無氧桿,這(zhe)和無氧桿是單(dan)晶銅(tong),低氧桿是多晶銅(tong)有關。
氧(yang)銅(tong)桿(gan)(gan)和無氧(yang)銅(tong)桿(gan)(gan)由于制(zhi)造方法(fa)的不同,致使存在差別,具有各自的特點。
一、關于氧的吸入和(he)脫去(qu)以及它(ta)的存(cun)在狀態
生(sheng)產銅(tong)(tong)桿(gan)(gan)(gan)的(de)(de)(de)(de)陰(yin)極(ji)銅(tong)(tong)的(de)(de)(de)(de)含氧(yang)(yang)(yang)(yang)(yang)量一般(ban)在(zai)(zai)10—50ppm,在(zai)(zai)常(chang)(chang)溫(wen)下氧(yang)(yang)(yang)(yang)(yang)在(zai)(zai)銅(tong)(tong)中(zhong)的(de)(de)(de)(de)固(gu)溶度(du)約(yue)2ppm。低(di)氧(yang)(yang)(yang)(yang)(yang)銅(tong)(tong)桿(gan)(gan)(gan)的(de)(de)(de)(de)含氧(yang)(yang)(yang)(yang)(yang)量一般(ban)在(zai)(zai)200(175)—400(450)ppm,因此氧(yang)(yang)(yang)(yang)(yang)的(de)(de)(de)(de)進入是(shi)在(zai)(zai)銅(tong)(tong)的(de)(de)(de)(de)液(ye)態下吸入的(de)(de)(de)(de),而(er)上引法無氧(yang)(yang)(yang)(yang)(yang)銅(tong)(tong)桿(gan)(gan)(gan)則相反(fan),氧(yang)(yang)(yang)(yang)(yang)在(zai)(zai)液(ye)態銅(tong)(tong)下保(bao)持相當時間后,被還原而(er)脫去,通常(chang)(chang)這(zhe)種(zhong)(zhong)桿(gan)(gan)(gan)的(de)(de)(de)(de)含氧(yang)(yang)(yang)(yang)(yang)量都在(zai)(zai)10—50ppm以下,最(zui)低(di)可達(da)1-2ppm,從組織(zhi)上看,低(di)氧(yang)(yang)(yang)(yang)(yang)銅(tong)(tong)中(zhong)的(de)(de)(de)(de)氧(yang)(yang)(yang)(yang)(yang),以氧(yang)(yang)(yang)(yang)(yang)化銅(tong)(tong)狀態,存在(zai)(zai)于晶粒邊界附近,這(zhe)對低(di)氧(yang)(yang)(yang)(yang)(yang)銅(tong)(tong)桿(gan)(gan)(gan)而(er)言可以說(shuo)是(shi)常(chang)(chang)見的(de)(de)(de)(de)但對無氧(yang)(yang)(yang)(yang)(yang)銅(tong)(tong)桿(gan)(gan)(gan)則很(hen)(hen)少見。氧(yang)(yang)(yang)(yang)(yang)化銅(tong)(tong)以夾雜形式(shi)在(zai)(zai)晶界出現對材料的(de)(de)(de)(de)韌性產生(sheng)負面影響。而(er)無氧(yang)(yang)(yang)(yang)(yang)銅(tong)(tong)中(zhong)的(de)(de)(de)(de)氧(yang)(yang)(yang)(yang)(yang)很(hen)(hen)低(di),所以這(zhe)種(zhong)(zhong)銅(tong)(tong)的(de)(de)(de)(de)組織(zhi)是(shi)均勻的(de)(de)(de)(de)單(dan)相組織(zhi)對韌性有利。在(zai)(zai)無氧(yang)(yang)(yang)(yang)(yang)銅(tong)(tong)桿(gan)(gan)(gan)中(zhong)的(de)(de)(de)(de)多孔性是(shi)不(bu)常(chang)(chang)見的(de)(de)(de)(de),而(er)在(zai)(zai)低(di)氧(yang)(yang)(yang)(yang)(yang)銅(tong)(tong)桿(gan)(gan)(gan)中(zhong)則是(shi)常(chang)(chang)見的(de)(de)(de)(de)一種(zhong)(zhong)缺陷。
二、熱軋組織和鑄(zhu)造(zao)組織的區(qu)別
低(di)(di)氧(yang)銅(tong)(tong)(tong)桿(gan)由(you)于經過熱軋,所(suo)以其(qi)(qi)組(zu)織屬熱加工組(zu)織,原來的(de)(de)(de)(de)(de)鑄造(zao)組(zu)織已(yi)經破碎,在8mm的(de)(de)(de)(de)(de)桿(gan)時已(yi)有再(zai)結晶(jing)(jing)的(de)(de)(de)(de)(de)形式(shi)出現,而無(wu)氧(yang)銅(tong)(tong)(tong)桿(gan)屬鑄造(zao)組(zu)織,晶(jing)(jing)粒(li)粗(cu)大,這是(shi)為(wei)什么,無(wu)氧(yang)銅(tong)(tong)(tong)的(de)(de)(de)(de)(de)再(zai)結晶(jing)(jing)溫度較(jiao)高(gao),需要(yao)較(jiao)高(gao)退(tui)(tui)火(huo)(huo)溫度的(de)(de)(de)(de)(de)固有原因(yin)(yin)。這是(shi)因(yin)(yin)為(wei),再(zai)結晶(jing)(jing)發生在晶(jing)(jing)粒(li)邊(bian)界(jie)附近(jin),無(wu)氧(yang)銅(tong)(tong)(tong)桿(gan)組(zu)織晶(jing)(jing)粒(li)粗(cu)大,晶(jing)(jing)粒(li)尺(chi)寸(cun)甚至(zhi)能達幾(ji)個毫米(mi),因(yin)(yin)而晶(jing)(jing)粒(li)邊(bian)界(jie)少,即(ji)使通過拉(la)制變形,但晶(jing)(jing)粒(li)邊(bian)界(jie)相對低(di)(di)氧(yang)銅(tong)(tong)(tong)桿(gan)還是(shi)較(jiao)少,所(suo)以需要(yao)較(jiao)高(gao)的(de)(de)(de)(de)(de)退(tui)(tui)火(huo)(huo)功率(lv)(lv)。對無(wu)氧(yang)銅(tong)(tong)(tong)成功的(de)(de)(de)(de)(de)退(tui)(tui)火(huo)(huo)要(yao)求是(shi):由(you)桿(gan)經拉(la)制,但尚(shang)未鑄造(zao)組(zu)織的(de)(de)(de)(de)(de)線(xian)(xian)時的(de)(de)(de)(de)(de)第一次退(tui)(tui)火(huo)(huo),其(qi)(qi)退(tui)(tui)火(huo)(huo)功率(lv)(lv)應比同樣情(qing)況的(de)(de)(de)(de)(de)低(di)(di)氧(yang)銅(tong)(tong)(tong)高(gao)10——15%。經繼續拉(la)制,在以后階段的(de)(de)(de)(de)(de)退(tui)(tui)火(huo)(huo)功率(lv)(lv)應留有足夠(gou)的(de)(de)(de)(de)(de)余(yu)量(liang)和對低(di)(di)氧(yang)銅(tong)(tong)(tong)和無(wu)氧(yang)銅(tong)(tong)(tong)切實區(qu)別(bie)執行不(bu)同的(de)(de)(de)(de)(de)退(tui)(tui)火(huo)(huo)工藝,以保證在制品和成品導線(xian)(xian)的(de)(de)(de)(de)(de)柔軟性(xing)。
三、夾雜,氧(yang)(yang)含量(liang)波動,表面氧(yang)(yang)化物和(he)可能存在的熱(re)軋缺(que)陷(xian)的差別(bie)
無(wu)氧(yang)(yang)銅桿(gan)的(de)(de)(de)可拉性(xing)在(zai)(zai)所(suo)有線(xian)(xian)徑里與低氧(yang)(yang)銅桿(gan)相比都是(shi)(shi)優越的(de)(de)(de),除(chu)上述組織原因外(wai),無(wu)氧(yang)(yang)銅桿(gan)夾雜少(shao),含氧(yang)(yang)量(liang)穩定,無(wu)熱軋可能產生的(de)(de)(de)缺陷,桿(gan)表(biao)氧(yang)(yang)化(hua)物(wu)(wu)厚(hou)度可達≤15A。在(zai)(zai)連鑄連軋生產過程中(zhong)如(ru)果(guo)工(gong)藝不(bu)穩定,對(dui)氧(yang)(yang)監控(kong)不(bu)嚴,含氧(yang)(yang)量(liang)不(bu)穩定將(jiang)直(zhi)接影響桿(gan)的(de)(de)(de)性(xing)能。如(ru)果(guo)桿(gan)的(de)(de)(de)表(biao)面氧(yang)(yang)化(hua)物(wu)(wu)能在(zai)(zai)后工(gong)序(xu)的(de)(de)(de)連續清洗中(zhong)得以(yi)彌(mi)補外(wai),但比較麻(ma)煩的(de)(de)(de)是(shi)(shi)有相當多的(de)(de)(de)氧(yang)(yang)化(hua)物(wu)(wu)存在(zai)(zai)于“皮(pi)(pi)下(xia)”,對(dui)拉線(xian)(xian)斷(duan)線(xian)(xian)影響更直(zhi)接,故而(er)在(zai)(zai)拉制微細線(xian)(xian),超微細線(xian)(xian)時(shi),為了減少(shao)斷(duan)線(xian)(xian),有時(shi)要對(dui)銅桿(gan)采取(qu)不(bu)得已的(de)(de)(de)辦法——剝皮(pi)(pi),甚至二次剝皮(pi)(pi)的(de)(de)(de)原因所(suo)在(zai)(zai),目的(de)(de)(de)要除(chu)去皮(pi)(pi)下(xia)氧(yang)(yang)化(hua)物(wu)(wu)。
四、低(di)氧銅桿和(he)無氧銅桿的(de)韌性有差別
兩者(zhe)都可(ke)以(yi)拉到0.015mm,但(dan)在(zai)低溫超(chao)導線中的(de)低溫級無氧銅,其細(xi)絲間(jian)的(de)間(jian)距只有0.001mm.
五、從制桿(gan)的原材料到制線的經濟性有差(cha)別。
制(zhi)造無(wu)氧(yang)銅(tong)桿(gan)要求(qiu)質量較(jiao)(jiao)高的(de)(de)(de)原材料。一般,拉制(zhi)直徑(jing)>1mm的(de)(de)(de)銅(tong)線時(shi),低(di)氧(yang)銅(tong)桿(gan)的(de)(de)(de)優點比(bi)較(jiao)(jiao)明顯,而無(wu)氧(yang)銅(tong)桿(gan)顯得更為(wei)優越的(de)(de)(de)是(shi)拉制(zhi)直徑(jing)<0.5mm的(de)(de)(de)銅(tong)線。
六(liu)、低氧銅桿的(de)制線工(gong)藝與無氧銅桿的(de)有(you)所(suo)不同。
低氧(yang)銅(tong)(tong)桿(gan)的(de)制(zhi)線(xian)工(gong)藝(yi)(yi)不能照搬(ban)到無氧(yang)銅(tong)(tong)桿(gan)的(de)制(zhi)線(xian)工(gong)藝(yi)(yi)上來(lai),至(zhi)少兩者的(de)退(tui)火工(gong)藝(yi)(yi)是不同(tong)的(de)。因為線(xian)的(de)柔軟(ruan)性深受材料成份和制(zhi)桿(gan),制(zhi)線(xian)和退(tui)火工(gong)藝(yi)(yi)的(de)影(ying)響,不能簡單地說(shuo)低氧(yang)銅(tong)(tong)或無氧(yang)銅(tong)(tong)誰(shui)軟(ruan)誰(shui)硬。
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