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新邱電纜中的銅都是一樣的嗎?什么樣的是好銅?一篇文章解釋清楚

來源:行業動態(tai) 閱(yue)讀:109551 發(fa)布(bu)時間:2019-07-05

導讀(du):由于生(sheng)(sheng)(sheng)產銅(tong)(tong)(tong)桿的(de)兩者的(de)工(gong)藝不(bu)同,所生(sheng)(sheng)(sheng)產的(de)銅(tong)(tong)(tong)桿中的(de)含(han)氧(yang)量(liang)及外觀就不(bu)同。上引生(sheng)(sheng)(sheng)產的(de)銅(tong)(tong)(tong)桿,工(gong)藝得當氧(yang)含(han)量(liang)在(zai)10ppm以下(xia),叫(jiao)無氧(yang)銅(tong)(tong)(tong)桿;連(lian)鑄連(lian)鑄生(sheng)(sheng)(sheng)產的(de)銅(tong)(tong)(tong)桿 是(shi)在(zai)保護條件(jian)下(xia)的(de)熱軋,氧(yang)含(han)量(liang)在(zai)200-500ppm范圍內,但(dan)有(you)時也(ye)高達700ppm以上,一般情(qing)況下(xia),此(ci)種(zhong)方(fang)法生(sheng)(sheng)(sheng)產的(de)銅(tong)(tong)(tong)外表(biao)光(guang)亮,低氧(yang)銅(tong)(tong)(tong)桿,有(you)時也(ye)叫(jiao)光(guang)桿。

銅(tong)桿(gan)是電纜行(xing)業的(de)(de)主要(yao)原料,生(sheng)產的(de)(de)方式(shi)主要(yao)有兩種——連(lian)(lian)鑄(zhu)(zhu)(zhu)連(lian)(lian)軋(ya)法和上(shang)引連(lian)(lian)鑄(zhu)(zhu)(zhu)法。連(lian)(lian)鑄(zhu)(zhu)(zhu)連(lian)(lian)軋(ya)低氧銅(tong)桿(gan)的(de)(de)生(sheng)產方法較(jiao)(jiao)(jiao)多(duo),其(qi)特點是金(jin)屬在(zai)(zai)豎爐(lu)中融(rong)化(hua)后,銅(tong)液通(tong)(tong)過(guo)保(bao)溫爐(lu)、溜槽、中間包,從澆管進入封閉的(de)(de)模腔內,采用較(jiao)(jiao)(jiao)大(da)的(de)(de)冷卻(que)強度進行(xing)冷卻(que),形成鑄(zhu)(zhu)(zhu)坯,然后進行(xing)多(duo)道次(ci)軋(ya)制,生(sheng)產的(de)(de)低氧銅(tong)桿(gan)為(wei)熱加(jia)工(gong)(gong)組織,原來的(de)(de)鑄(zhu)(zhu)(zhu)造(zao)組織已經(jing)破碎,含氧量(liang)(liang)一般為(wei)200~400ppm之間。無(wu)氧銅(tong)桿(gan)國內基本全部采用上(shang)引連(lian)(lian)鑄(zhu)(zhu)(zhu)法生(sheng)產,金(jin)屬在(zai)(zai)感應電爐(lu)中融(rong)化(hua)后通(tong)(tong)過(guo)石(shi)墨模進行(xing)上(shang)引連(lian)(lian)續鑄(zhu)(zhu)(zhu)造(zao),之后進行(xing)冷軋(ya)或冷加(jia)工(gong)(gong),生(sheng)產的(de)(de)無(wu)氧銅(tong)桿(gan)為(wei)鑄(zhu)(zhu)(zhu)造(zao)組織,含氧量(liang)(liang)一般在(zai)(zai)20ppm以下。由于制造(zao)工(gong)(gong)藝(yi)的(de)(de)不同(tong),所(suo)以在(zai)(zai)組織結構、氧含量(liang)(liang)分(fen)布(bu)、雜質的(de)(de)形式(shi)及分(fen)布(bu)等諸(zhu)多(duo)方面有較(jiao)(jiao)(jiao)大(da)差別。

一、拉制性能

銅桿的(de)拉(la)制(zhi)性能跟很多因(yin)素(su)有關,如雜(za)質的(de)含(han)量、氧含(han)量及分布、工(gong)藝控制(zhi)等。下面(mian)分別從以上幾個方面(mian)對(dui)銅桿的(de)拉(la)制(zhi)性能進行(xing)分析。

1、熔(rong)化方式對(dui)S等雜質的影響

連(lian)鑄(zhu)(zhu)連(lian)軋生產銅(tong)桿主要(yao)(yao)是通過氣體的燃燒使銅(tong)桿熔化,在燃燒的過程中,通過氧化和揮發作用(yong),可一(yi)定程度減少(shao)部分雜質進(jin)入銅(tong)液(ye)(ye),因此連(lian)鑄(zhu)(zhu)連(lian)軋法(fa)對原料要(yao)(yao)求相(xiang)對低一(yi)些。上引連(lian)鑄(zhu)(zhu)生產無氧銅(tong)桿,由于是用(yong)感應電爐熔化,電解(jie)銅(tong)表面的“銅(tong)綠”“銅(tong)豆”基(ji)本都熔入到銅(tong)液(ye)(ye)中。其中熔入的S對無氧銅(tong)桿塑性(xing)影響極大,會增加(jia)拉絲斷(duan)線率。

2、鑄造過程中(zhong)雜質(zhi)的進入(ru)

在(zai)生產(chan)過(guo)(guo)程(cheng)中(zhong),連(lian)鑄(zhu)連(lian)軋(ya)工藝需(xu)(xu)通(tong)(tong)過(guo)(guo)保(bao)溫爐(lu)、溜槽(cao)、中(zhong)間包(bao)轉運(yun)銅(tong)液,相對容易造(zao)成(cheng)(cheng)(cheng)耐(nai)火(huo)材料(liao)的(de)(de)剝落(luo),在(zai)軋(ya)制過(guo)(guo)程(cheng)中(zhong)需(xu)(xu)要通(tong)(tong)過(guo)(guo)軋(ya)輥,造(zao)成(cheng)(cheng)(cheng)鐵質(zhi)的(de)(de)脫(tuo)落(luo),會給(gei)銅(tong)桿(gan)造(zao)成(cheng)(cheng)(cheng)外部夾雜(za)(za)。而熱軋(ya)中(zhong)皮(pi)(pi)上和皮(pi)(pi)下氧化物的(de)(de)軋(ya)入,會給(gei)低氧桿(gan)的(de)(de)拉絲造(zao)成(cheng)(cheng)(cheng)不利(li)的(de)(de)影響。上引連(lian)鑄(zhu)法生產(chan)工藝流程(cheng)較(jiao)短,銅(tong)液是(shi)通(tong)(tong)過(guo)(guo)聯體(ti)爐(lu)內(nei)潛流式(shi)完成(cheng)(cheng)(cheng),對耐(nai)火(huo)材料(liao)的(de)(de)沖(chong)擊不大(da),結晶(jing)是(shi)通(tong)(tong)過(guo)(guo)石墨模內(nei)進行,所以過(guo)(guo)程(cheng)中(zhong)可(ke)能產(chan)生的(de)(de)污染源(yuan)較(jiao)少(shao),雜(za)(za)質(zhi)進入的(de)(de)機(ji)會較(jiao)少(shao)。

O、S、P是與銅(tong)會生產化(hua)合物的元素。在熔態銅(tong)中,氧(yang)(yang)可(ke)以(yi)溶解一部分(fen)(fen),但當銅(tong)冷(leng)凝時,氧(yang)(yang)幾乎不溶解于(yu)銅(tong)中。熔態時所溶解的氧(yang)(yang),以(yi)銅(tong)=氧(yang)(yang)化(hua)亞(ya)銅(tong)共晶體(ti)析出,分(fen)(fen)布在晶粒晶界(jie)處。銅(tong)-氧(yang)(yang)化(hua)亞(ya)銅(tong)共晶體(ti)的出現(xian),顯著降低了銅(tong)的塑性。

硫(liu)可以(yi)溶解(jie)在(zai)熔體的銅(tong)(tong)中,但(dan)在(zai)室溫(wen)下(xia),其溶解(jie)度幾乎降(jiang)低到零(ling),它以(yi)硫(liu)化亞銅(tong)(tong)的形式出現在(zai)晶(jing)粒晶(jing)界處(chu),會顯著降(jiang)低銅(tong)(tong)的塑性。

3、氧在低(di)氧銅桿和無氧銅桿中分布形(xing)式及其影響

氧(yang)(yang)(yang)含(han)量(liang)(liang)對(dui)低氧(yang)(yang)(yang)銅(tong)(tong)桿的(de)(de)(de)拉線(xian)(xian)性能(neng)有(you)著明(ming)顯(xian)的(de)(de)(de)影響。當氧(yang)(yang)(yang)含(han)量(liang)(liang)增(zeng)加到最佳值時(shi),銅(tong)(tong)桿的(de)(de)(de)斷線(xian)(xian)率最低。這(zhe)是(shi)因為(wei)氧(yang)(yang)(yang)在與大部分(fen)雜質反應的(de)(de)(de)過程中都(dou)起到了(le)清除器(qi)的(de)(de)(de)作用。適度的(de)(de)(de)氧(yang)(yang)(yang)還(huan)有(you)利(li)于去除銅(tong)(tong)液中的(de)(de)(de)氫,生成(cheng)水蒸氣溢出,減少氣孔的(de)(de)(de)形成(cheng)。最佳的(de)(de)(de)氧(yang)(yang)(yang)含(han)量(liang)(liang)為(wei)拉線(xian)(xian)工藝提供了(le)最好的(de)(de)(de)條件。

低氧(yang)銅桿氧(yang)化(hua)(hua)物(wu)的(de)分布(bu):在連續(xu)澆(jiao)鑄(zhu)中凝固的(de)最(zui)初階段,散熱速率和均勻冷(leng)卻(que)是(shi)決定銅桿氧(yang)化(hua)(hua)物(wu)分布(bu)的(de)主要因素。不均勻冷(leng)卻(que)會引起(qi)銅桿內部(bu)結構本質上的(de)差異,但后續(xu)的(de)熱加工,柱狀晶通常會遭到破壞,使氧(yang)化(hua)(hua)亞銅顆粒(li)(li)細微(wei)化(hua)(hua)和均勻分布(bu)。氧(yang)化(hua)(hua)物(wu)顆粒(li)(li)聚(ju)集而產生的(de)典型(xing)情況是(shi)中心(xin)爆(bao)裂(lie)。除氧(yang)化(hua)(hua)物(wu)顆粒(li)(li)分布(bu)的(de)影(ying)響外(wai),具有(you)較小氧(yang)化(hua)(hua)物(wu)顆粒(li)(li)的(de)銅桿顯(xian)示出較好(hao)的(de)拉(la)線特性,較大的(de)Cu2O顆粒(li)(li)容易造成應力集中點(dian)而斷裂(lie)。

無氧(yang)(yang)(yang)(yang)銅(tong)含氧(yang)(yang)(yang)(yang)量超標(biao),銅(tong)桿變脆(cui),延伸率下(xia)降(jiang),拉伸式樣端口顯暗紅色,結(jie)晶組(zu)織疏松。當氧(yang)(yang)(yang)(yang)含量超出8ppm時(shi)(shi),工藝性(xing)能(neng)變差,表現為鑄(zhu)造及(ji)(ji)拉伸過程(cheng)中(zhong)斷(duan)桿及(ji)(ji)斷(duan)線率極具增高(gao)。這是由(you)于氧(yang)(yang)(yang)(yang)能(neng)與銅(tong)生成氧(yang)(yang)(yang)(yang)化亞銅(tong)脆(cui)性(xing)相(xiang),形成銅(tong)-氧(yang)(yang)(yang)(yang)化亞銅(tong)共(gong)晶體(ti),以網(wang)狀(zhuang)組(zu)織分(fen)布在境(jing)界上。這種脆(cui)性(xing)相(xiang)硬度高(gao),在冷變形時(shi)(shi)將會與銅(tong)機體(ti)脫離,導致銅(tong)桿的機械性(xing)能(neng)下(xia)降(jiang),在后續加(jia)工中(zhong)容易造成斷(duan)裂現象。氧(yang)(yang)(yang)(yang)含量高(gao)還能(neng)導致無氧(yang)(yang)(yang)(yang)銅(tong)桿導電率下(xia)降(jiang)。因此,必須嚴格控(kong)制上引(yin)連鑄(zhu)工藝及(ji)(ji)產(chan)品(pin)質量。

4、氫的影響

在(zai)上引連(lian)鑄中,氧含量控(kong)制較(jiao)低(di),氧化物(wu)的副作用(yong)唄**降低(di),但(dan)氫的影響成為較(jiao)顯著(zhu)的問題。吸氣后熔體中存在(zai)平衡(heng)反應:H2O(g)=[O]+2[H];

氣(qi)(qi)體及疏松(song)(song)是在(zai)結晶(jing)(jing)的(de)(de)過程(cheng)中(zhong),氫從過飽和(he)(he)的(de)(de)溶液(ye)中(zhong)析出(chu)(chu)(chu)并聚(ju)集而形成(cheng)的(de)(de)。在(zai)結晶(jing)(jing)前析出(chu)(chu)(chu)的(de)(de)氫又可還(huan)原氧(yang)化亞銅而生(sheng)成(cheng)水(shui)氣(qi)(qi)泡(pao)。由于(yu)上(shang)引鑄造(zao)的(de)(de)特點是銅液(ye)自上(shang)而下的(de)(de)結晶(jing)(jing),形成(cheng)的(de)(de)液(ye)**形狀近似錐型。銅液(ye)結晶(jing)(jing)前析出(chu)(chu)(chu)的(de)(de)氣(qi)(qi)體在(zai)上(shang)浮過程(cheng)中(zhong)被堵(du)在(zai)凝固(gu)組織(zhi)內,結晶(jing)(jing)時在(zai)鑄桿(gan)內形成(cheng)氣(qi)(qi)孔(kong)。上(shang)引的(de)(de)含(han)氣(qi)(qi)量(liang)少時,析出(chu)(chu)(chu)的(de)(de)氫存在(zai)于(yu)晶(jing)(jing)界處(chu),形成(cheng)疏松(song)(song);含(han)氣(qi)(qi)量(liang)多時,則(ze)聚(ju)集成(cheng)氣(qi)(qi)孔(kong),因此,氣(qi)(qi)孔(kong)和(he)(he)疏松(song)(song)是氫氣(qi)(qi)和(he)(he)水(shui)蒸氣(qi)(qi)兩者形成(cheng)的(de)(de)。

氫來源于上(shang)引(yin)生(sheng)產過程中(zhong)的(de)各(ge)個工藝環節,如原料(liao)電解銅(tong)的(de)“銅(tong)綠”、輔料(liao)木炭(tan)**、氣候環境**、石墨結晶器(qi)未干燥等(deng)。因此,熔化爐中(zhong)的(de)銅(tong)液表(biao)面應(ying)覆蓋經烘烤的(de)木炭(tan),電解銅(tong)應(ying)盡量去除“銅(tong)綠”、“銅(tong)豆”“耳(er)朵(duo)”,對(dui)提高無氧銅(tong)桿質(zhi)量非(fei)常重要。

在(zai)連鑄連軋工(gong)藝中,往往采用適度控制氧含量來控制氫。Cu2O+ H2= 2Cu+ H2O

由于銅(tong)液在鑄造過程中是(shi)自下而上結晶,銅(tong)液中的(de)氧和氫(qing)所產(chan)生的(de)水蒸氣(qi)很容易上浮跑出,銅(tong)液中的(de)氫(qing)大部(bu)分能被(bei)有效去除,因(yin)而對銅(tong)桿的(de)影響較小。

二、表面質量

在生產(chan)電磁線等產(chan)品的(de)(de)過程中,對銅(tong)(tong)桿(gan)(gan)的(de)(de)表(biao)面(mian)(mian)質量(liang)也(ye)需提出要(yao)求。需要(yao)拉制后(hou)的(de)(de)銅(tong)(tong)絲表(biao)面(mian)(mian)無毛刺、銅(tong)(tong)粉少(shao)、無油污。并(bing)通過扭轉試驗測量(liang)表(biao)面(mian)(mian)銅(tong)(tong)粉的(de)(de)質量(liang)和扭轉后(hou)觀察銅(tong)(tong)桿(gan)(gan)的(de)(de)復原情況來(lai)判定其好壞。

在連鑄連軋過(guo)程中,從鑄造到軋制前,溫度(du)高,完全暴(bao)露(lu)于(yu)空氣中,使鑄坯(pi)表(biao)(biao)面(mian)形成較厚的氧化(hua)層,在軋制過(guo)程中,隨著軋輥的轉(zhuan)動,氧化(hua)物顆粒軋入(ru)銅線表(biao)(biao)面(mian)。由于(yu)氧化(hua)亞銅是高熔點脆性化(hua)合物,對于(yu)軋入(ru)較深(shen)的氧化(hua)亞銅,當(dang)成條狀的聚集物遇模具拉伸時,就會是銅桿外(wai)表(biao)(biao)面(mian)產生毛刺,給后續的涂漆造成麻煩。

而上引連(lian)鑄工藝制造的(de)無氧銅桿,由于鑄造和冷卻完全(quan)與(yu)氧隔絕,后(hou)續亦無熱(re)軋過程,銅桿表面(mian)無軋入表面(mian)的(de)氧化(hua)物,質(zhi)量較(jiao)好,拉制后(hou)銅粉少,上述(shu)問題較(jiao)少存在。

無氧銅桿(gan)也(ye)分進(jin)口(kou)設(she)(she)備做的(de)(de)和國產(chan)(chan)(chan)設(she)(she)備做的(de)(de),但目前(qian)進(jin)口(kou)產(chan)(chan)(chan)品已無明顯優(you)勢,銅桿(gan)產(chan)(chan)(chan)品出來后(hou)區別不是(shi)很(hen)大(da),只要銅板(ban)選的(de)(de)好,生產(chan)(chan)(chan)控制比較(jiao)穩定,國產(chan)(chan)(chan)設(she)(she)備也(ye)能產(chan)(chan)(chan)出可拉伸0.05的(de)(de)銅桿(gan).進(jin)口(kou)設(she)(she)備一(yi)般是(shi)芬蘭奧托昆普的(de)(de)設(she)(she)備,國產(chan)(chan)(chan)設(she)(she)備最好的(de)(de)應該是(shi)上海的(de)(de)海軍廠的(de)(de)了,生產(chan)(chan)(chan)時間最長,軍工企業,質量(liang)可靠。

低氧銅桿(gan)進口設備(bei)國(guo)(guo)際主(zhu)要有兩種,一種是(shi)美國(guo)(guo)南線設備(bei),英文是(shi)SOUTHWIRE,國(guo)(guo)內(nei)廠(chang)家(jia)是(shi)南京華新(xin),江西銅業,另一種是(shi)德國(guo)(guo)CONTIROD設備(bei),國(guo)(guo)內(nei)廠(chang)家(jia)是(shi)常州金源,天(tian)津大無縫。

無(wu)(wu)氧(yang)及低(di)氧(yang)桿(gan)(gan)(gan)(gan)(gan)從含氧(yang)量上容(rong)易區別,無(wu)(wu)氧(yang)銅(tong)是(shi)含氧(yang)量在(zai)10-20個(ge)PPM以下,但(dan)(dan)目(mu)前有(you)的(de)(de)(de)廠家(jia)只(zhi)能(neng)(neng)(neng)做(zuo)到50個(ge)PPM以下.低(di)氧(yang)銅(tong)桿(gan)(gan)(gan)(gan)(gan)在(zai) 200-400個(ge)PPM,好(hao)(hao)(hao)的(de)(de)(de)桿(gan)(gan)(gan)(gan)(gan)子(zi)(zi)一(yi)般含氧(yang)量控(kong)制在(zai)250個(ge)PPM左右,無(wu)(wu)氧(yang)桿(gan)(gan)(gan)(gan)(gan)一(yi)般采(cai)取的(de)(de)(de)是(shi)上引(yin)法,低(di)氧(yang)桿(gan)(gan)(gan)(gan)(gan)是(shi)連鑄連軋(ya),兩種產品(pin)相對而(er)言低(di)氧(yang)桿(gan)(gan)(gan)(gan)(gan)對漆包線(xian)(xian)性 能(neng)(neng)(neng)更適應些(xie),如柔軟性,回彈角,繞線(xian)(xian)性能(neng)(neng)(neng).但(dan)(dan)低(di)氧(yang)桿(gan)(gan)(gan)(gan)(gan)對拉絲條件相對要苛刻些(xie),同樣拉伸0.2的(de)(de)(de)細絲,如果伸線(xian)(xian)條件不(bu)好(hao)(hao)(hao),普(pu)通的(de)(de)(de)無(wu)(wu)氧(yang)桿(gan)(gan)(gan)(gan)(gan)可拉而(er)好(hao)(hao)(hao)的(de)(de)(de)低(di)氧(yang)桿(gan)(gan)(gan)(gan)(gan)就斷 線(xian)(xian),但(dan)(dan)如果放在(zai)好(hao)(hao)(hao)的(de)(de)(de)伸線(xian)(xian)條件,同樣的(de)(de)(de)桿(gan)(gan)(gan)(gan)(gan)子(zi)(zi),低(di)氧(yang)桿(gan)(gan)(gan)(gan)(gan)說不(bu)定就能(neng)(neng)(neng)拉到雙零五(wu),而(er)普(pu)通無(wu)(wu)氧(yang)桿(gan)(gan)(gan)(gan)(gan)最多只(zhi)能(neng)(neng)(neng)拉伸到0.1而(er)已(yi),當然(ran)做(zuo)的(de)(de)(de)最細的(de)(de)(de)如雙零二卻非得依靠進口的(de)(de)(de) 無(wu)(wu)氧(yang)銅(tong)桿(gan)(gan)(gan)(gan)(gan)了.目(mu)前有(you)企業嘗(chang)試用剝(bo)皮的(de)(de)(de)方(fang)(fang)式來處(chu)理低(di)氧(yang)桿(gan)(gan)(gan)(gan)(gan)來伸0.03線(xian)(xian).但(dan)(dan)有(you)關(guan)這方(fang)(fang)面的(de)(de)(de)內容(rong)我還不(bu)是(shi)很清(qing)楚。

音響線一般反而(er)喜歡(huan)用無氧(yang)桿(gan),這和無氧(yang)桿(gan)是單晶銅,低氧(yang)桿(gan)是多晶銅有(you)關。

氧銅桿(gan)和無氧銅桿(gan)由于(yu)制造方法的不同,致使(shi)存在差別,具(ju)有(you)各自的特點(dian)。

一、關(guan)于氧(yang)的吸入和脫去以及它(ta)的存(cun)在狀態

生產(chan)銅(tong)(tong)(tong)(tong)桿(gan)(gan)的(de)(de)陰(yin)極銅(tong)(tong)(tong)(tong)的(de)(de)含(han)氧(yang)(yang)(yang)(yang)(yang)(yang)量(liang)一般在(zai)10—50ppm,在(zai)常溫下(xia)氧(yang)(yang)(yang)(yang)(yang)(yang)在(zai)銅(tong)(tong)(tong)(tong)中(zhong)的(de)(de)固溶(rong)度約2ppm。低(di)氧(yang)(yang)(yang)(yang)(yang)(yang)銅(tong)(tong)(tong)(tong)桿(gan)(gan)的(de)(de)含(han)氧(yang)(yang)(yang)(yang)(yang)(yang)量(liang)一般在(zai)200(175)—400(450)ppm,因此氧(yang)(yang)(yang)(yang)(yang)(yang)的(de)(de)進入(ru)是(shi)在(zai)銅(tong)(tong)(tong)(tong)的(de)(de)液(ye)態下(xia)吸入(ru)的(de)(de),而上引法無氧(yang)(yang)(yang)(yang)(yang)(yang)銅(tong)(tong)(tong)(tong)桿(gan)(gan)則(ze)相反,氧(yang)(yang)(yang)(yang)(yang)(yang)在(zai)液(ye)態銅(tong)(tong)(tong)(tong)下(xia)保持相當時(shi)間后,被還原而脫去,通常這(zhe)種桿(gan)(gan)的(de)(de)含(han)氧(yang)(yang)(yang)(yang)(yang)(yang)量(liang)都在(zai)10—50ppm以(yi)下(xia),最低(di)可達(da)1-2ppm,從組織(zhi)上看(kan),低(di)氧(yang)(yang)(yang)(yang)(yang)(yang)銅(tong)(tong)(tong)(tong)中(zhong)的(de)(de)氧(yang)(yang)(yang)(yang)(yang)(yang),以(yi)氧(yang)(yang)(yang)(yang)(yang)(yang)化(hua)銅(tong)(tong)(tong)(tong)狀(zhuang)態,存在(zai)于晶(jing)(jing)粒邊界(jie)附(fu)近(jin),這(zhe)對低(di)氧(yang)(yang)(yang)(yang)(yang)(yang)銅(tong)(tong)(tong)(tong)桿(gan)(gan)而言可以(yi)說是(shi)常見(jian)的(de)(de)但(dan)對無氧(yang)(yang)(yang)(yang)(yang)(yang)銅(tong)(tong)(tong)(tong)桿(gan)(gan)則(ze)很少見(jian)。氧(yang)(yang)(yang)(yang)(yang)(yang)化(hua)銅(tong)(tong)(tong)(tong)以(yi)夾雜形式在(zai)晶(jing)(jing)界(jie)出現對材料(liao)的(de)(de)韌性產(chan)生負(fu)面影響(xiang)。而無氧(yang)(yang)(yang)(yang)(yang)(yang)銅(tong)(tong)(tong)(tong)中(zhong)的(de)(de)氧(yang)(yang)(yang)(yang)(yang)(yang)很低(di),所以(yi)這(zhe)種銅(tong)(tong)(tong)(tong)的(de)(de)組織(zhi)是(shi)均勻的(de)(de)單相組織(zhi)對韌性有(you)利。在(zai)無氧(yang)(yang)(yang)(yang)(yang)(yang)銅(tong)(tong)(tong)(tong)桿(gan)(gan)中(zhong)的(de)(de)多孔性是(shi)不常見(jian)的(de)(de),而在(zai)低(di)氧(yang)(yang)(yang)(yang)(yang)(yang)銅(tong)(tong)(tong)(tong)桿(gan)(gan)中(zhong)則(ze)是(shi)常見(jian)的(de)(de)一種缺陷(xian)。

二、熱軋組織(zhi)(zhi)和鑄造組織(zhi)(zhi)的區別

低(di)氧銅(tong)(tong)桿(gan)由(you)于(yu)經(jing)(jing)過(guo)(guo)熱軋(ya),所(suo)(suo)以其(qi)組(zu)織(zhi)屬(shu)熱加工組(zu)織(zhi),原來的(de)(de)鑄造(zao)組(zu)織(zhi)已(yi)經(jing)(jing)破碎,在8mm的(de)(de)桿(gan)時已(yi)有(you)再結晶(jing)(jing)的(de)(de)形式出現,而無氧銅(tong)(tong)桿(gan)屬(shu)鑄造(zao)組(zu)織(zhi),晶(jing)(jing)粒(li)(li)粗(cu)大,這(zhe)是(shi)(shi)為什么,無氧銅(tong)(tong)的(de)(de)再結晶(jing)(jing)溫(wen)度(du)較(jiao)高,需要較(jiao)高退(tui)(tui)火(huo)(huo)溫(wen)度(du)的(de)(de)固有(you)原因。這(zhe)是(shi)(shi)因為,再結晶(jing)(jing)發生在晶(jing)(jing)粒(li)(li)邊界(jie)附近,無氧銅(tong)(tong)桿(gan)組(zu)織(zhi)晶(jing)(jing)粒(li)(li)粗(cu)大,晶(jing)(jing)粒(li)(li)尺寸甚至能達幾個毫米,因而晶(jing)(jing)粒(li)(li)邊界(jie)少(shao),即(ji)使通過(guo)(guo)拉(la)(la)制(zhi)變(bian)形,但晶(jing)(jing)粒(li)(li)邊界(jie)相對低(di)氧銅(tong)(tong)桿(gan)還是(shi)(shi)較(jiao)少(shao),所(suo)(suo)以需要較(jiao)高的(de)(de)退(tui)(tui)火(huo)(huo)功率。對無氧銅(tong)(tong)成(cheng)功的(de)(de)退(tui)(tui)火(huo)(huo)要求(qiu)是(shi)(shi):由(you)桿(gan)經(jing)(jing)拉(la)(la)制(zhi),但尚未鑄造(zao)組(zu)織(zhi)的(de)(de)線時的(de)(de)第(di)一次(ci)退(tui)(tui)火(huo)(huo),其(qi)退(tui)(tui)火(huo)(huo)功率應比同樣情況的(de)(de)低(di)氧銅(tong)(tong)高10——15%。經(jing)(jing)繼續(xu)拉(la)(la)制(zhi),在以后階段(duan)的(de)(de)退(tui)(tui)火(huo)(huo)功率應留(liu)有(you)足夠的(de)(de)余量和(he)對低(di)氧銅(tong)(tong)和(he)無氧銅(tong)(tong)切實(shi)區別執(zhi)行不(bu)同的(de)(de)退(tui)(tui)火(huo)(huo)工藝(yi),以保證在制(zhi)品和(he)成(cheng)品導線的(de)(de)柔軟性。

三、夾雜,氧含(han)量波動,表(biao)面氧化物和(he)可能(neng)存在的(de)熱軋缺陷的(de)差別

無氧(yang)銅(tong)桿(gan)的(de)(de)(de)可(ke)拉(la)(la)性(xing)(xing)在所有(you)線(xian)徑里與(yu)低(di)氧(yang)銅(tong)桿(gan)相比都是(shi)優(you)越的(de)(de)(de),除(chu)上述組織原(yuan)(yuan)因外,無氧(yang)銅(tong)桿(gan)夾雜少,含(han)氧(yang)量(liang)穩定,無熱軋可(ke)能(neng)產生(sheng)的(de)(de)(de)缺陷(xian),桿(gan)表氧(yang)化物厚度可(ke)達≤15A。在連(lian)鑄連(lian)軋生(sheng)產過程(cheng)中如(ru)果工藝不(bu)穩定,對氧(yang)監控不(bu)嚴,含(han)氧(yang)量(liang)不(bu)穩定將(jiang)直接影響桿(gan)的(de)(de)(de)性(xing)(xing)能(neng)。如(ru)果桿(gan)的(de)(de)(de)表面(mian)氧(yang)化物能(neng)在后工序的(de)(de)(de)連(lian)續清洗(xi)中得以彌補外,但比較麻煩的(de)(de)(de)是(shi)有(you)相當(dang)多的(de)(de)(de)氧(yang)化物存在于“皮下(xia)”,對拉(la)(la)線(xian)斷(duan)(duan)線(xian)影響更直接,故而(er)在拉(la)(la)制(zhi)微細(xi)線(xian),超微細(xi)線(xian)時(shi)(shi),為了減少斷(duan)(duan)線(xian),有(you)時(shi)(shi)要(yao)(yao)對銅(tong)桿(gan)采取(qu)不(bu)得已(yi)的(de)(de)(de)辦(ban)法(fa)——剝(bo)皮,甚至二次剝(bo)皮的(de)(de)(de)原(yuan)(yuan)因所在,目(mu)的(de)(de)(de)要(yao)(yao)除(chu)去皮下(xia)氧(yang)化物。

四、低氧(yang)銅桿(gan)和(he)無氧(yang)銅桿(gan)的韌(ren)性有(you)差別

兩者都可以拉到0.015mm,但在低溫超導線(xian)中的低溫級無氧銅,其細絲間的間距只有0.001mm.

五、從制桿的原材料(liao)到制線的經濟性有差別(bie)。

制造無(wu)氧銅(tong)桿要求質量較(jiao)高的原(yuan)材料。一(yi)般,拉(la)制直徑>1mm的銅(tong)線(xian)時,低氧銅(tong)桿的優(you)點(dian)比較(jiao)明顯,而無(wu)氧銅(tong)桿顯得更(geng)為優(you)越的是拉(la)制直徑<0.5mm的銅(tong)線(xian)。

六(liu)、低氧銅(tong)桿的制(zhi)線工藝與無氧銅(tong)桿的有所不同(tong)。

低(di)氧銅桿(gan)(gan)的制線(xian)工(gong)(gong)藝不(bu)(bu)能(neng)照(zhao)搬到無氧銅桿(gan)(gan)的制線(xian)工(gong)(gong)藝上來,至少(shao)兩者的退火工(gong)(gong)藝是不(bu)(bu)同的。因為線(xian)的柔(rou)軟性深受材料(liao)成份和制桿(gan)(gan),制線(xian)和退火工(gong)(gong)藝的影響,不(bu)(bu)能(neng)簡(jian)單地說低(di)氧銅或無氧銅誰軟誰硬。