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來源:行業動態(tai) 閱(yue)讀:109274 發(fa)布(bu)時間(jian):2019-07-05
導讀:由于生(sheng)(sheng)產(chan)銅(tong)(tong)(tong)桿(gan)的(de)(de)兩者的(de)(de)工藝(yi)不(bu)同(tong),所生(sheng)(sheng)產(chan)的(de)(de)銅(tong)(tong)(tong)桿(gan)中的(de)(de)含氧(yang)量及(ji)外觀就不(bu)同(tong)。上引生(sheng)(sheng)產(chan)的(de)(de)銅(tong)(tong)(tong)桿(gan),工藝(yi)得(de)當氧(yang)含量在(zai)10ppm以(yi)下,叫(jiao)無氧(yang)銅(tong)(tong)(tong)桿(gan);連鑄(zhu)連鑄(zhu)生(sheng)(sheng)產(chan)的(de)(de)銅(tong)(tong)(tong)桿(gan) 是在(zai)保護條(tiao)件下的(de)(de)熱軋,氧(yang)含量在(zai)200-500ppm范圍(wei)內,但有時也高達700ppm以(yi)上,一般(ban)情況下,此種(zhong)方法生(sheng)(sheng)產(chan)的(de)(de)銅(tong)(tong)(tong)外表光亮(liang),低氧(yang)銅(tong)(tong)(tong)桿(gan),有時也叫(jiao)光桿(gan)。
銅(tong)桿(gan)是電(dian)纜行業的(de)(de)主要(yao)原(yuan)料,生(sheng)產(chan)的(de)(de)方式(shi)主要(yao)有(you)兩(liang)種——連鑄(zhu)連軋法和上(shang)引(yin)連鑄(zhu)法。連鑄(zhu)連軋低氧銅(tong)桿(gan)的(de)(de)生(sheng)產(chan)方法較多(duo),其特點是金(jin)屬(shu)在(zai)(zai)(zai)豎爐(lu)中融(rong)化后(hou),銅(tong)液通過保(bao)溫(wen)爐(lu)、溜槽(cao)、中間包,從澆(jiao)管進(jin)入封(feng)閉的(de)(de)模腔內(nei),采(cai)用較大(da)的(de)(de)冷(leng)卻強度進(jin)行冷(leng)卻,形成鑄(zhu)坯,然(ran)后(hou)進(jin)行多(duo)道次軋制,生(sheng)產(chan)的(de)(de)低氧銅(tong)桿(gan)為熱加工組(zu)織(zhi),原(yuan)來(lai)的(de)(de)鑄(zhu)造(zao)(zao)組(zu)織(zhi)已(yi)經破碎,含(han)(han)氧量(liang)(liang)一般(ban)為200~400ppm之(zhi)間。無氧銅(tong)桿(gan)國內(nei)基本全部采(cai)用上(shang)引(yin)連鑄(zhu)法生(sheng)產(chan),金(jin)屬(shu)在(zai)(zai)(zai)感應電(dian)爐(lu)中融(rong)化后(hou)通過石墨模進(jin)行上(shang)引(yin)連續鑄(zhu)造(zao)(zao),之(zhi)后(hou)進(jin)行冷(leng)軋或冷(leng)加工,生(sheng)產(chan)的(de)(de)無氧銅(tong)桿(gan)為鑄(zhu)造(zao)(zao)組(zu)織(zhi),含(han)(han)氧量(liang)(liang)一般(ban)在(zai)(zai)(zai)20ppm以下。由于制造(zao)(zao)工藝的(de)(de)不(bu)同(tong),所(suo)以在(zai)(zai)(zai)組(zu)織(zhi)結構、氧含(han)(han)量(liang)(liang)分布(bu)、雜(za)質的(de)(de)形式(shi)及(ji)分布(bu)等諸多(duo)方面有(you)較大(da)差別。
一、拉制性能
銅(tong)(tong)桿的(de)(de)拉制(zhi)性能跟很多(duo)因素(su)有關,如雜(za)質(zhi)的(de)(de)含(han)量(liang)、氧(yang)含(han)量(liang)及分(fen)布、工藝控制(zhi)等。下(xia)面分(fen)別從(cong)以(yi)上幾個方面對(dui)銅(tong)(tong)桿的(de)(de)拉制(zhi)性能進行分(fen)析。
1、熔化(hua)方式(shi)對(dui)S等雜質的影響
連鑄(zhu)連軋生產銅桿主要是通(tong)過氣體(ti)的燃燒使銅桿熔(rong)化(hua)(hua),在(zai)燃燒的過程中,通(tong)過氧(yang)化(hua)(hua)和揮發作用,可一(yi)定程度減少部分雜質進入(ru)銅液,因此(ci)連鑄(zhu)連軋法對原料要求相對低(di)一(yi)些。上引連鑄(zhu)生產無氧(yang)銅桿,由于(yu)是用感(gan)應電(dian)爐熔(rong)化(hua)(hua),電(dian)解銅表面的“銅綠(lv)”“銅豆”基本都熔(rong)入(ru)到銅液中。其中熔(rong)入(ru)的S對無氧(yang)銅桿塑性影響極大,會增(zeng)加拉(la)絲(si)斷(duan)線(xian)率。
2、鑄造過程中雜質的進入
在生(sheng)產過(guo)(guo)程中,連(lian)(lian)(lian)鑄連(lian)(lian)(lian)軋(ya)(ya)(ya)工藝(yi)需通過(guo)(guo)保溫爐(lu)、溜槽、中間包(bao)轉運銅(tong)液,相對容易(yi)造(zao)(zao)成(cheng)耐火材(cai)(cai)料的(de)剝(bo)落,在軋(ya)(ya)(ya)制(zhi)過(guo)(guo)程中需要通過(guo)(guo)軋(ya)(ya)(ya)輥,造(zao)(zao)成(cheng)鐵(tie)質(zhi)(zhi)的(de)脫落,會給銅(tong)桿造(zao)(zao)成(cheng)外部夾雜(za)(za)。而熱軋(ya)(ya)(ya)中皮上和皮下氧化物的(de)軋(ya)(ya)(ya)入,會給低氧桿的(de)拉(la)絲造(zao)(zao)成(cheng)不利的(de)影響。上引連(lian)(lian)(lian)鑄法生(sheng)產工藝(yi)流(liu)程較短,銅(tong)液是通過(guo)(guo)聯體爐(lu)內潛流(liu)式(shi)完成(cheng),對耐火材(cai)(cai)料的(de)沖擊不大(da),結晶是通過(guo)(guo)石墨模內進行,所以過(guo)(guo)程中可能產生(sheng)的(de)污(wu)染源較少(shao),雜(za)(za)質(zhi)(zhi)進入的(de)機會較少(shao)。
O、S、P是與銅(tong)會生產化(hua)合(he)物(wu)的元素。在熔態銅(tong)中(zhong)(zhong),氧(yang)可(ke)以溶(rong)解(jie)一部分,但當銅(tong)冷(leng)凝(ning)時(shi)(shi),氧(yang)幾乎不(bu)溶(rong)解(jie)于銅(tong)中(zhong)(zhong)。熔態時(shi)(shi)所溶(rong)解(jie)的氧(yang),以銅(tong)=氧(yang)化(hua)亞銅(tong)共晶體析出,分布(bu)在晶粒晶界處。銅(tong)-氧(yang)化(hua)亞銅(tong)共晶體的出現,顯(xian)著降(jiang)低了銅(tong)的塑(su)性。
硫(liu)可以溶解在(zai)熔體的銅中,但在(zai)室溫下,其(qi)溶解度幾乎降低(di)到零,它以硫(liu)化亞銅的形式出現(xian)在(zai)晶粒晶界處,會顯著降低(di)銅的塑性。
3、氧在低氧銅桿和無氧銅桿中分布形(xing)式及(ji)其影(ying)響
氧(yang)(yang)含(han)(han)量對低氧(yang)(yang)銅桿的(de)(de)拉線性(xing)能有著明顯的(de)(de)影響。當氧(yang)(yang)含(han)(han)量增(zeng)加到(dao)最佳值時,銅桿的(de)(de)斷線率(lv)最低。這是因為氧(yang)(yang)在與大部分雜質反(fan)應的(de)(de)過程中(zhong)都起(qi)到(dao)了(le)清除(chu)器的(de)(de)作用。適度的(de)(de)氧(yang)(yang)還(huan)有利于(yu)去除(chu)銅液(ye)中(zhong)的(de)(de)氫,生成水蒸氣(qi)溢出,減少氣(qi)孔的(de)(de)形成。最佳的(de)(de)氧(yang)(yang)含(han)(han)量為拉線工(gong)藝提供了(le)最好的(de)(de)條件(jian)。
低氧銅(tong)桿氧化(hua)物(wu)(wu)的(de)(de)分(fen)布:在連續澆鑄中凝固的(de)(de)最(zui)初階段(duan),散熱(re)速率和均(jun)勻(yun)冷卻是決(jue)定銅(tong)桿氧化(hua)物(wu)(wu)分(fen)布的(de)(de)主(zhu)要因素。不均(jun)勻(yun)冷卻會(hui)引起銅(tong)桿內部結構本質上的(de)(de)差異(yi),但后(hou)續的(de)(de)熱(re)加工(gong),柱狀(zhuang)晶(jing)通常會(hui)遭到破壞(huai),使氧化(hua)亞銅(tong)顆(ke)(ke)粒(li)(li)細微化(hua)和均(jun)勻(yun)分(fen)布。氧化(hua)物(wu)(wu)顆(ke)(ke)粒(li)(li)聚(ju)集而產(chan)生(sheng)的(de)(de)典型(xing)情況是中心爆裂。除氧化(hua)物(wu)(wu)顆(ke)(ke)粒(li)(li)分(fen)布的(de)(de)影響外,具有較(jiao)小氧化(hua)物(wu)(wu)顆(ke)(ke)粒(li)(li)的(de)(de)銅(tong)桿顯示(shi)出較(jiao)好的(de)(de)拉線特性(xing),較(jiao)大的(de)(de)Cu2O顆(ke)(ke)粒(li)(li)容(rong)易造成(cheng)應力(li)集中點而斷(duan)裂。
無(wu)氧(yang)(yang)銅(tong)(tong)含氧(yang)(yang)量(liang)超(chao)(chao)標,銅(tong)(tong)桿(gan)(gan)變(bian)(bian)脆(cui),延伸率(lv)下(xia)降(jiang),拉伸式(shi)樣端(duan)口顯暗紅色,結(jie)晶組織疏松。當氧(yang)(yang)含量(liang)超(chao)(chao)出8ppm時,工(gong)藝性能(neng)變(bian)(bian)差,表(biao)現(xian)為鑄(zhu)(zhu)造及(ji)拉伸過程(cheng)中斷桿(gan)(gan)及(ji)斷線(xian)率(lv)極具增高(gao)。這是由于氧(yang)(yang)能(neng)與(yu)銅(tong)(tong)生成(cheng)氧(yang)(yang)化(hua)亞(ya)銅(tong)(tong)脆(cui)性相(xiang),形成(cheng)銅(tong)(tong)-氧(yang)(yang)化(hua)亞(ya)銅(tong)(tong)共(gong)晶體,以網狀組織分布在(zai)(zai)境(jing)界上。這種脆(cui)性相(xiang)硬度(du)高(gao),在(zai)(zai)冷變(bian)(bian)形時將會與(yu)銅(tong)(tong)機體脫離,導致(zhi)銅(tong)(tong)桿(gan)(gan)的機械性能(neng)下(xia)降(jiang),在(zai)(zai)后續加工(gong)中容(rong)易造成(cheng)斷裂現(xian)象。氧(yang)(yang)含量(liang)高(gao)還(huan)能(neng)導致(zhi)無(wu)氧(yang)(yang)銅(tong)(tong)桿(gan)(gan)導電率(lv)下(xia)降(jiang)。因此(ci),必須嚴格(ge)控(kong)制上引連(lian)鑄(zhu)(zhu)工(gong)藝及(ji)產品質量(liang)。
4、氫的影響
在上引連鑄中,氧(yang)含量控(kong)制較(jiao)低,氧(yang)化物的(de)副作用唄**降低,但氫的(de)影響成為較(jiao)顯著的(de)問題(ti)。吸氣后熔體中存(cun)在平衡反(fan)應:H2O(g)=[O]+2[H];
氣(qi)(qi)體及疏(shu)松是在(zai)(zai)結(jie)晶(jing)(jing)的過(guo)(guo)程中(zhong),氫從過(guo)(guo)飽和的溶液中(zhong)析(xi)出(chu)(chu)并聚(ju)集而形(xing)成的。在(zai)(zai)結(jie)晶(jing)(jing)前(qian)析(xi)出(chu)(chu)的氫又可還原(yuan)氧化亞銅而生成水氣(qi)(qi)泡。由于上(shang)引鑄造的特點是銅液自上(shang)而下的結(jie)晶(jing)(jing),形(xing)成的液**形(xing)狀(zhuang)近似錐型(xing)。銅液結(jie)晶(jing)(jing)前(qian)析(xi)出(chu)(chu)的氣(qi)(qi)體在(zai)(zai)上(shang)浮過(guo)(guo)程中(zhong)被堵在(zai)(zai)凝(ning)固組織內(nei)(nei),結(jie)晶(jing)(jing)時在(zai)(zai)鑄桿內(nei)(nei)形(xing)成氣(qi)(qi)孔(kong)。上(shang)引的含氣(qi)(qi)量少時,析(xi)出(chu)(chu)的氫存在(zai)(zai)于晶(jing)(jing)界處,形(xing)成疏(shu)松;含氣(qi)(qi)量多(duo)時,則聚(ju)集成氣(qi)(qi)孔(kong),因此,氣(qi)(qi)孔(kong)和疏(shu)松是氫氣(qi)(qi)和水蒸氣(qi)(qi)兩者(zhe)形(xing)成的。
氫來源于上引(yin)生產過程(cheng)中(zhong)的各(ge)個工藝環節,如原料電(dian)解銅的“銅綠”、輔料木炭**、氣候環境(jing)**、石墨結(jie)晶器未干燥等。因此,熔(rong)化(hua)爐中(zhong)的銅液表面(mian)應(ying)覆蓋經烘(hong)烤的木炭,電(dian)解銅應(ying)盡量去除“銅綠”、“銅豆”“耳朵”,對(dui)提高無氧銅桿質量非常重要(yao)。
在連(lian)鑄連(lian)軋工藝(yi)中(zhong),往(wang)往(wang)采用適度控(kong)制(zhi)(zhi)氧含(han)量來(lai)控(kong)制(zhi)(zhi)氫。Cu2O+ H2= 2Cu+ H2O
由于銅液在鑄造過程中(zhong)(zhong)是自下(xia)而上結(jie)晶,銅液中(zhong)(zhong)的氧和氫所產生的水蒸(zheng)氣很容易上浮跑出(chu),銅液中(zhong)(zhong)的氫大部分(fen)能被(bei)有效(xiao)去除,因(yin)而對銅桿的影響較小。
二、表面質量
在(zai)生產電(dian)磁(ci)線等產品的(de)(de)過(guo)程中,對銅(tong)桿的(de)(de)表(biao)(biao)面質量(liang)也需提出(chu)要(yao)(yao)求。需要(yao)(yao)拉制后(hou)的(de)(de)銅(tong)絲(si)表(biao)(biao)面無毛刺(ci)、銅(tong)粉少、無油污。并通(tong)過(guo)扭轉試(shi)驗測量(liang)表(biao)(biao)面銅(tong)粉的(de)(de)質量(liang)和扭轉后(hou)觀察銅(tong)桿的(de)(de)復原情況來判定其(qi)好壞(huai)。
在(zai)連鑄連軋(ya)過程中(zhong),從鑄造到(dao)軋(ya)制(zhi)(zhi)前,溫度高,完全(quan)暴(bao)露于空氣中(zhong),使鑄坯表(biao)面形成較厚的(de)氧(yang)化層,在(zai)軋(ya)制(zhi)(zhi)過程中(zhong),隨著軋(ya)輥(gun)的(de)轉動,氧(yang)化物(wu)顆粒軋(ya)入銅(tong)線表(biao)面。由于氧(yang)化亞銅(tong)是(shi)高熔點脆性化合物(wu),對(dui)于軋(ya)入較深的(de)氧(yang)化亞銅(tong),當(dang)成條狀的(de)聚集物(wu)遇模具拉(la)伸時,就會(hui)是(shi)銅(tong)桿外表(biao)面產(chan)生(sheng)毛刺,給后續的(de)涂漆造成麻煩。
而上引連(lian)鑄(zhu)工(gong)藝制造的(de)無氧銅桿,由于鑄(zhu)造和冷(leng)卻(que)完全與氧隔(ge)絕,后(hou)續亦無熱軋(ya)過程,銅桿表面(mian)無軋(ya)入表面(mian)的(de)氧化(hua)物,質量較好,拉(la)制后(hou)銅粉少(shao)(shao),上述(shu)問題(ti)較少(shao)(shao)存在。
無氧銅桿也分進口設(she)備做(zuo)的(de)(de)和國產(chan)(chan)設(she)備做(zuo)的(de)(de),但目前進口產(chan)(chan)品已無明顯優(you)勢,銅桿產(chan)(chan)品出(chu)來后區別不是(shi)很大,只要銅板選的(de)(de)好,生產(chan)(chan)控制(zhi)比較穩定,國產(chan)(chan)設(she)備也能產(chan)(chan)出(chu)可拉伸0.05的(de)(de)銅桿.進口設(she)備一般(ban)是(shi)芬蘭奧托昆普(pu)的(de)(de)設(she)備,國產(chan)(chan)設(she)備最(zui)好的(de)(de)應該是(shi)上海的(de)(de)海軍(jun)廠的(de)(de)了(le),生產(chan)(chan)時(shi)間最(zui)長(chang),軍(jun)工(gong)企(qi)業(ye),質量可靠。
低(di)氧銅(tong)桿(gan)進(jin)口設(she)備(bei)國際主要有兩種,一種是(shi)美國南(nan)線設(she)備(bei),英文是(shi)SOUTHWIRE,國內廠(chang)家是(shi)南(nan)京華新,江(jiang)西銅(tong)業,另一種是(shi)德國CONTIROD設(she)備(bei),國內廠(chang)家是(shi)常州金源,天(tian)津大無縫。
無(wu)氧(yang)(yang)(yang)(yang)(yang)(yang)及低(di)氧(yang)(yang)(yang)(yang)(yang)(yang)桿(gan)(gan)從(cong)含(han)氧(yang)(yang)(yang)(yang)(yang)(yang)量(liang)上容易區別,無(wu)氧(yang)(yang)(yang)(yang)(yang)(yang)銅是(shi)含(han)氧(yang)(yang)(yang)(yang)(yang)(yang)量(liang)在(zai)(zai)10-20個(ge)PPM以(yi)下,但目前(qian)有的(de)(de)廠家只能(neng)(neng)做到50個(ge)PPM以(yi)下.低(di)氧(yang)(yang)(yang)(yang)(yang)(yang)銅桿(gan)(gan)在(zai)(zai) 200-400個(ge)PPM,好的(de)(de)桿(gan)(gan)子一般含(han)氧(yang)(yang)(yang)(yang)(yang)(yang)量(liang)控制在(zai)(zai)250個(ge)PPM左右,無(wu)氧(yang)(yang)(yang)(yang)(yang)(yang)桿(gan)(gan)一般采取(qu)的(de)(de)是(shi)上引法(fa),低(di)氧(yang)(yang)(yang)(yang)(yang)(yang)桿(gan)(gan)是(shi)連鑄連軋,兩種產品相(xiang)對(dui)而言低(di)氧(yang)(yang)(yang)(yang)(yang)(yang)桿(gan)(gan)對(dui)漆包線(xian)性 能(neng)(neng)更(geng)適應些,如柔軟性,回(hui)彈角(jiao),繞線(xian)性能(neng)(neng).但低(di)氧(yang)(yang)(yang)(yang)(yang)(yang)桿(gan)(gan)對(dui)拉(la)絲條件相(xiang)對(dui)要苛刻些,同樣拉(la)伸0.2的(de)(de)細(xi)絲,如果(guo)伸線(xian)條件不好,普(pu)通的(de)(de)無(wu)氧(yang)(yang)(yang)(yang)(yang)(yang)桿(gan)(gan)可拉(la)而好的(de)(de)低(di)氧(yang)(yang)(yang)(yang)(yang)(yang)桿(gan)(gan)就(jiu)斷 線(xian),但如果(guo)放在(zai)(zai)好的(de)(de)伸線(xian)條件,同樣的(de)(de)桿(gan)(gan)子,低(di)氧(yang)(yang)(yang)(yang)(yang)(yang)桿(gan)(gan)說(shuo)不定就(jiu)能(neng)(neng)拉(la)到雙零(ling)五(wu),而普(pu)通無(wu)氧(yang)(yang)(yang)(yang)(yang)(yang)桿(gan)(gan)最多只能(neng)(neng)拉(la)伸到0.1而已,當然做的(de)(de)最細(xi)的(de)(de)如雙零(ling)二卻非得(de)依靠(kao)進口(kou)的(de)(de) 無(wu)氧(yang)(yang)(yang)(yang)(yang)(yang)銅桿(gan)(gan)了.目前(qian)有企業嘗試用剝皮的(de)(de)方式來(lai)處理低(di)氧(yang)(yang)(yang)(yang)(yang)(yang)桿(gan)(gan)來(lai)伸0.03線(xian).但有關這方面的(de)(de)內容我還不是(shi)很清(qing)楚。
音(yin)響線一般反而喜歡用無(wu)(wu)氧桿(gan),這和無(wu)(wu)氧桿(gan)是單晶銅,低氧桿(gan)是多晶銅有(you)關。
氧銅(tong)(tong)桿(gan)和(he)無氧銅(tong)(tong)桿(gan)由(you)于制造方法的不同,致使(shi)存在差別,具有(you)各(ge)自的特點。
一、關于氧的吸(xi)入和脫去以及它的存在(zai)狀態
生產銅(tong)(tong)(tong)桿的(de)(de)(de)(de)陰(yin)極(ji)銅(tong)(tong)(tong)的(de)(de)(de)(de)含(han)(han)氧(yang)(yang)(yang)(yang)(yang)量(liang)(liang)一般(ban)在(zai)10—50ppm,在(zai)常(chang)溫下氧(yang)(yang)(yang)(yang)(yang)在(zai)銅(tong)(tong)(tong)中(zhong)的(de)(de)(de)(de)固溶度約2ppm。低(di)(di)(di)氧(yang)(yang)(yang)(yang)(yang)銅(tong)(tong)(tong)桿的(de)(de)(de)(de)含(han)(han)氧(yang)(yang)(yang)(yang)(yang)量(liang)(liang)一般(ban)在(zai)200(175)—400(450)ppm,因此氧(yang)(yang)(yang)(yang)(yang)的(de)(de)(de)(de)進入是在(zai)銅(tong)(tong)(tong)的(de)(de)(de)(de)液(ye)態(tai)下吸入的(de)(de)(de)(de),而上引法無(wu)(wu)氧(yang)(yang)(yang)(yang)(yang)銅(tong)(tong)(tong)桿則相(xiang)反,氧(yang)(yang)(yang)(yang)(yang)在(zai)液(ye)態(tai)銅(tong)(tong)(tong)下保持相(xiang)當時間后,被還原而脫去(qu),通(tong)常(chang)這種(zhong)桿的(de)(de)(de)(de)含(han)(han)氧(yang)(yang)(yang)(yang)(yang)量(liang)(liang)都在(zai)10—50ppm以(yi)下,最(zui)低(di)(di)(di)可達1-2ppm,從(cong)組(zu)(zu)織(zhi)上看,低(di)(di)(di)氧(yang)(yang)(yang)(yang)(yang)銅(tong)(tong)(tong)中(zhong)的(de)(de)(de)(de)氧(yang)(yang)(yang)(yang)(yang),以(yi)氧(yang)(yang)(yang)(yang)(yang)化銅(tong)(tong)(tong)狀態(tai),存在(zai)于晶粒邊(bian)界附(fu)近,這對(dui)(dui)低(di)(di)(di)氧(yang)(yang)(yang)(yang)(yang)銅(tong)(tong)(tong)桿而言可以(yi)說是常(chang)見的(de)(de)(de)(de)但對(dui)(dui)無(wu)(wu)氧(yang)(yang)(yang)(yang)(yang)銅(tong)(tong)(tong)桿則很(hen)少(shao)見。氧(yang)(yang)(yang)(yang)(yang)化銅(tong)(tong)(tong)以(yi)夾雜(za)形(xing)式在(zai)晶界出現對(dui)(dui)材料的(de)(de)(de)(de)韌(ren)性(xing)(xing)產生負面(mian)影響。而無(wu)(wu)氧(yang)(yang)(yang)(yang)(yang)銅(tong)(tong)(tong)中(zhong)的(de)(de)(de)(de)氧(yang)(yang)(yang)(yang)(yang)很(hen)低(di)(di)(di),所以(yi)這種(zhong)銅(tong)(tong)(tong)的(de)(de)(de)(de)組(zu)(zu)織(zhi)是均勻的(de)(de)(de)(de)單相(xiang)組(zu)(zu)織(zhi)對(dui)(dui)韌(ren)性(xing)(xing)有利(li)。在(zai)無(wu)(wu)氧(yang)(yang)(yang)(yang)(yang)銅(tong)(tong)(tong)桿中(zhong)的(de)(de)(de)(de)多孔(kong)性(xing)(xing)是不常(chang)見的(de)(de)(de)(de),而在(zai)低(di)(di)(di)氧(yang)(yang)(yang)(yang)(yang)銅(tong)(tong)(tong)桿中(zhong)則是常(chang)見的(de)(de)(de)(de)一種(zhong)缺陷。
二、熱軋組織和鑄造組織的區別
低(di)氧(yang)(yang)(yang)銅(tong)(tong)(tong)桿(gan)由于(yu)經(jing)過熱軋(ya),所(suo)以(yi)其組(zu)(zu)織(zhi)(zhi)(zhi)屬熱加工組(zu)(zu)織(zhi)(zhi)(zhi),原(yuan)來的(de)(de)鑄造(zao)組(zu)(zu)織(zhi)(zhi)(zhi)已(yi)經(jing)破碎,在(zai)(zai)8mm的(de)(de)桿(gan)時(shi)已(yi)有再結晶(jing)(jing)的(de)(de)形式出現,而(er)無(wu)(wu)氧(yang)(yang)(yang)銅(tong)(tong)(tong)桿(gan)屬鑄造(zao)組(zu)(zu)織(zhi)(zhi)(zhi),晶(jing)(jing)粒(li)粗大,這是為什么,無(wu)(wu)氧(yang)(yang)(yang)銅(tong)(tong)(tong)的(de)(de)再結晶(jing)(jing)溫度(du)較(jiao)高(gao),需要(yao)較(jiao)高(gao)退(tui)火(huo)溫度(du)的(de)(de)固有原(yuan)因(yin)。這是因(yin)為,再結晶(jing)(jing)發生在(zai)(zai)晶(jing)(jing)粒(li)邊界(jie)附近,無(wu)(wu)氧(yang)(yang)(yang)銅(tong)(tong)(tong)桿(gan)組(zu)(zu)織(zhi)(zhi)(zhi)晶(jing)(jing)粒(li)粗大,晶(jing)(jing)粒(li)尺寸甚至能達幾(ji)個毫米,因(yin)而(er)晶(jing)(jing)粒(li)邊界(jie)少,即使(shi)通過拉(la)制(zhi)變形,但晶(jing)(jing)粒(li)邊界(jie)相對(dui)低(di)氧(yang)(yang)(yang)銅(tong)(tong)(tong)桿(gan)還是較(jiao)少,所(suo)以(yi)需要(yao)較(jiao)高(gao)的(de)(de)退(tui)火(huo)功(gong)(gong)率。對(dui)無(wu)(wu)氧(yang)(yang)(yang)銅(tong)(tong)(tong)成功(gong)(gong)的(de)(de)退(tui)火(huo)要(yao)求是:由桿(gan)經(jing)拉(la)制(zhi),但尚未鑄造(zao)組(zu)(zu)織(zhi)(zhi)(zhi)的(de)(de)線時(shi)的(de)(de)第一次退(tui)火(huo),其退(tui)火(huo)功(gong)(gong)率應(ying)(ying)比同(tong)樣情(qing)況的(de)(de)低(di)氧(yang)(yang)(yang)銅(tong)(tong)(tong)高(gao)10——15%。經(jing)繼續拉(la)制(zhi),在(zai)(zai)以(yi)后階(jie)段(duan)的(de)(de)退(tui)火(huo)功(gong)(gong)率應(ying)(ying)留(liu)有足夠的(de)(de)余量和對(dui)低(di)氧(yang)(yang)(yang)銅(tong)(tong)(tong)和無(wu)(wu)氧(yang)(yang)(yang)銅(tong)(tong)(tong)切實區別執行不同(tong)的(de)(de)退(tui)火(huo)工藝(yi),以(yi)保證在(zai)(zai)制(zhi)品和成品導(dao)線的(de)(de)柔軟性。
三、夾雜,氧(yang)含量波動,表面氧(yang)化物和可能存在(zai)的(de)熱軋(ya)缺(que)陷的(de)差別(bie)
無(wu)氧(yang)(yang)銅(tong)桿(gan)(gan)的(de)(de)(de)(de)可拉(la)性在(zai)所(suo)(suo)有(you)(you)線(xian)(xian)徑里與低氧(yang)(yang)銅(tong)桿(gan)(gan)相比都是優越的(de)(de)(de)(de),除(chu)上(shang)述(shu)組織原(yuan)因外,無(wu)氧(yang)(yang)銅(tong)桿(gan)(gan)夾雜少,含氧(yang)(yang)量(liang)穩(wen)定(ding)(ding),無(wu)熱軋(ya)可能產生的(de)(de)(de)(de)缺陷,桿(gan)(gan)表(biao)氧(yang)(yang)化物厚度可達≤15A。在(zai)連(lian)鑄連(lian)軋(ya)生產過程中如果(guo)工(gong)藝不(bu)穩(wen)定(ding)(ding),對氧(yang)(yang)監控(kong)不(bu)嚴,含氧(yang)(yang)量(liang)不(bu)穩(wen)定(ding)(ding)將直接影(ying)響桿(gan)(gan)的(de)(de)(de)(de)性能。如果(guo)桿(gan)(gan)的(de)(de)(de)(de)表(biao)面氧(yang)(yang)化物能在(zai)后工(gong)序的(de)(de)(de)(de)連(lian)續清(qing)洗中得(de)以彌補外,但(dan)比較麻煩(fan)的(de)(de)(de)(de)是有(you)(you)相當多(duo)的(de)(de)(de)(de)氧(yang)(yang)化物存在(zai)于(yu)“皮下(xia)”,對拉(la)線(xian)(xian)斷線(xian)(xian)影(ying)響更直接,故而在(zai)拉(la)制微細線(xian)(xian),超微細線(xian)(xian)時,為(wei)了減少斷線(xian)(xian),有(you)(you)時要對銅(tong)桿(gan)(gan)采取不(bu)得(de)已的(de)(de)(de)(de)辦法——剝(bo)皮,甚至二次(ci)剝(bo)皮的(de)(de)(de)(de)原(yuan)因所(suo)(suo)在(zai),目的(de)(de)(de)(de)要除(chu)去皮下(xia)氧(yang)(yang)化物。
四(si)、低氧銅(tong)(tong)桿和無氧銅(tong)(tong)桿的(de)韌性有(you)差(cha)別
兩者都可以拉到(dao)0.015mm,但在低溫(wen)超導線中的低溫(wen)級無氧銅,其(qi)細絲間的間距只有0.001mm.
五、從(cong)制桿的原材料到制線的經濟性(xing)有(you)差別。
制(zhi)造無氧(yang)銅(tong)桿(gan)要求質量較(jiao)高的原材(cai)料。一般,拉制(zhi)直徑>1mm的銅(tong)線時,低氧(yang)銅(tong)桿(gan)的優(you)點比較(jiao)明顯(xian),而無氧(yang)銅(tong)桿(gan)顯(xian)得更為優(you)越(yue)的是拉制(zhi)直徑<0.5mm的銅(tong)線。
六、低氧(yang)銅桿的制線工(gong)藝與無氧(yang)銅桿的有所不同。
低(di)氧銅(tong)(tong)(tong)桿(gan)的制線(xian)工藝不能照搬到無氧銅(tong)(tong)(tong)桿(gan)的制線(xian)工藝上來,至少兩(liang)者的退(tui)火(huo)工藝是不同的。因為線(xian)的柔軟(ruan)性深受(shou)材料成(cheng)份和(he)制桿(gan),制線(xian)和(he)退(tui)火(huo)工藝的影響,不能簡單地說低(di)氧銅(tong)(tong)(tong)或無氧銅(tong)(tong)(tong)誰軟(ruan)誰硬。
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